Cited by 268Arsenic contamination and mitigationLandfill Environmental Impact StudiesCoal and Its By-products

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Effect of pH on Adsorption of Arsenic and Selenium from Landfill Leachate by Clay Minerals

Frost, R. R., Griffin, R. A.·1977·Soil Science Society of America Journal

DOI 10.2136/sssaj1977.03615995004100010019x

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Abstract

Adsorption of As(V), As(III), and Se(IV) anions from municipal landfill leachate solutions by the clay minerals kaolinite and montmorillonite is strongly dependent upon solution pH. The H 2 AsO 4 ‐ and HSeO ‐ 3 ions are the apparent primary As(V) and Se(IV) species being adsorbed by the clay minerals. Activation of the anion adsorption sites on the clay minerals by H + ions is important in determining the amount of HSeO 3 ‐ ions adsorbed by the clay minerals, but it is apparently not important in determining the amount of H 2 AsO 4 ‐ ions adsorbed. Montmorillonite adsorbed more As(V), As(III), and Se(IV) anions than kaolinite. Although no definite proof is given, the higher adsorption by montmorillonite is attributed to a higher edge surface area. The results of the study suggest that disposal of As and Se wastes in municipal landfills, especially under alkaline conditions, could produce ground water contamination by As and Se.

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Authors: Frost, R. R., & Griffin, R. A.
Venue: Soil Science Society of America Journal
Publisher: Wiley
Published: 1977-01
Volume: 41
Issue: 1
Pages: 53-57
ISSN: 0361-5995 (ISSN-L)
1435-0661
DOI: 10.2136/sssaj1977.03615995004100010019x
OpenAlex: W2809498828
Cited by: 268
References: 0
Citations by year: 2025: 2 · 2024: 6 · 2023: 8 · 2022: 5 · 2021: 4 · 2020: 5 · 2019: 4 · 2018: 5 · 2017: 7 · 2016: 5 · 2015: 10 · 2014: 7 · 2013: 7 · 2012: 2
FWCI: 5.35
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor)
Locations: Soil Science Society of America Journal (publishedVersion)
Topics: Physical Sciences › Environmental Science › Environmental Chemistry › Arsenic contamination and mitigation
Physical Sciences › Environmental Science › Waste Management and Disposal › Landfill Environmental Impact Studies
Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Coal and Its By-products
Keywords: arsenic adsorption, selenium adsorption, landfill leachate, clay minerals, kaolinite, montmorillonite, pH dependence, arsenate, arsenite, selenite, groundwater contamination

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Effect of pH on Adsorption of Arsenic and Selenium from Landfill Leachate by Clay Minerals

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