Sorption of As (V) by some oxyhydroxides and clay minerals. Application to its immobilization in two polluted mining soils
Abstract
Abstract Among the arsenic species in the environment, arsenate predominates under oxidizing conditions in soils and waters. The adsorption of As(V) by some natural Fe oxyhydroxides and clay minerals and synthetic Al(OH)3and FeOOH has been studied. The results show a very high As(V) adsorption capacity on both synthetic Al hydroxide (122 mg/g at pH: 5) and Fe oxyhydroxide (76 mg/g at pH 5). This adsorption capacity is pH dependent and shows maximum values at ∼pH 4. The application of these adsorbents to arsenic immobilization in the remediation process of two polluted mining soils with some differences in their physicochemical characteristics has also been studied. The best results were obtained when synthetic Al(OH)3and FeOOH were used; these materials decreased the water-extractable fraction of As by 55–79% for one soil and by nearly 100% for the other soil, the latter with higher pH and Eh values.
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Synthetic Al(OH)3 was effective at immobilizing soil As.
“Despite the natural Al oxides having immobilizing effects, Garcia-Sanchez et al. (2002) reported that synthetic Al(OH) 3 was effective at immobilizing soil As.”
From Soil amendments for immobilization of potentially toxic elements in contaminated soils: A critical review (2020) · cites this paper as Garcia-Sanchez et al., 2002
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- Authors
- García- Sanchez, A., Alvarez-Ayuso, E., & Rodriguez-Martin, F.
- Affiliations
- Consejo Superior de Investigaciones Científicas (ES)
- Venue
- Clay Minerals
- Publisher
- Mineralogical Society
- Published
- 2002-03
- Volume
- 37
- Issue
- 1
- Pages
- 187-194
- ISSN
- 0009-8558 (ISSN-L)
- 1471-8030
- OpenAlex
- W2314934704
- Cited by
- 118
- References
- 39
- Citations by year
- 2025: 3 · 2024: 1 · 2023: 2 · 2022: 5 · 2020: 4 · 2019: 9 · 2018: 5 · 2017: 3 · 2016: 5 · 2015: 9 · 2014: 5 · 2013: 6 · 2012: 6
- FWCI
- 4.69
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Clay Minerals (publishedVersion)
- Topics
- Physical Sciences › Environmental Science › Environmental Chemistry › Arsenic contamination and mitigation
- Physical Sciences › Environmental Science › Pollution › Heavy metals in environment
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Keywords
- arsenate adsorption, As(V) adsorption, iron oxyhydroxide, aluminum hydroxide, pH dependence, arsenic immobilization, mine soils, soil remediation, redox potential
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