Cited by 1,699Advanced Battery Materials and TechnologiesAdvancements in Battery MaterialsBattery Modeling and Management

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Fluoroethylene Carbonate Additives to Render Uniform Li Deposits in Lithium Metal Batteries

Zhang, Xue‐Qiang, Cheng, Xin‐Bing, Chen, Xiang, Yan, Chong, Zhang, Qiang·2017·Advanced Functional Materials

DOI 10.1002/adfm.201605989

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Abstract

Lithium (Li) metal has been considered as an important substitute for the graphite anode to further boost the energy density of Li‐ion batteries. However, Li dendrite growth during Li plating/stripping causes safety concern and poor lifespan of Li metal batteries (LMB). Herein, fluoroethylene carbonate (FEC) additives are used to form a LiF‐rich solid electrolyte interphase (SEI). The FEC‐induced SEI layer is compact and stable, and thus beneficial to obtain a uniform morphology of Li deposits. This uniform and dendrite‐free morphology renders a significantly improved Coulombic efficiency of 98% within 100 cycles in a Li | Cu half‐cell. When the FEC‐protected Li metal anode matches a high‐loading LiNi 0.5 Co 0.2 Mn 0.3 O 2 (NMC) cathode (12 mg cm −2 ), a high initial capacity of 154 mAh g −1 (1.9 mAh cm −2 ) at 180.0 mA g −1 is obtained. This LMB with conversion‐type Li metal anode and intercalation‐type NMC cathode affords an emerging energy storage system to probe the energy chemistry of Li metal protection and demonstrates the material engineering of batteries with very high energy density.

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Influential
Controlled Lithium Deposition
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“However, LMB has several severe problems, such as poor cycle performance and safety issues related to dendrite formation during the electrochemical lithium plating process.(1-8) Many attempts to apply lithium metal as an anode have been conducted.”
Background
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Authors: Zhang, X., Cheng, X., Chen, X., Yan, C., & Zhang, Q.
Affiliations: Tsinghua University (CN)
Corresponding author: Zhang, Qiang
ORCID: Zhang, Xue‐Qiang
Cheng, Xin‐Bing
Chen, Xiang
Yan, Chong
Zhang, Qiang
Venue: Advanced Functional Materials
Publisher: Wiley
Published: 2017-01-20
Volume: 27
Issue: 10
ISSN: 1616-301X (ISSN-L)
1616-3028
DOI: 10.1002/adfm.201605989
OpenAlex: W2579562509
Cited by: 1,699
References: 0
Citations by year: 2026: 81 · 2025: 135 · 2024: 161 · 2023: 203 · 2022: 230 · 2021: 228 · 2020: 242 · 2019: 231 · 2018: 130 · 2017: 58
FWCI: 75.16
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor)
Locations: Advanced Functional Materials (publishedVersion)
Funders: National Key Research and Development Program (2016YFA0202500)
Natural Scientific Foundation of China (21422604, 21676160, 21561130151)
Topics: Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
Physical Sciences › Engineering › Automotive Engineering › Battery Modeling and Management
Keywords: lithium metal batteries, fluoroethylene carbonate, electrolyte additives, lithium dendrite suppression, solid electrolyte interphase, LiF-rich SEI, lithium deposition uniformity, lithium metal anode, NCM cathode, Coulombic efficiency, high energy density

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Fluoroethylene Carbonate Additives to Render Uniform Li Deposits in Lithium Metal Batteries

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