Monolayer MoS2 Films Supported by 3D Nanoporous Metals for High‐Efficiency Electrocatalytic Hydrogen Production
Abstract
The "edge-free" monolayer MoS2 films supported by 3D nanoporous gold show high catalytic activities towards hydrogen evolution reaction (HER), originating from large out-of-plane strains that are geometrically required to manage the 3D curvature of bicontinuous nanoporosity. The large lattice bending leads to local semiconductor-to-metal transition of 2H MoS2 and the formation of catalytically active sites for HER.
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Hybridization of TMDs with other nanomaterials (e.g., noble metals, conductive materials) can provide a greater number of active sites and guarantee fast electron transfer between the external circuit and electrode to improve electrocatalytic HER activity.
“In electrocatalytic HERs, the hybridization of TMDs with other nanomaterials (e.g., noble metals, conductive materials) could provide a greater number of active sites and guarantee fast electron transfer between the external circuit and electrode to improve the electrocatalytic HER activity. [ 41-43 ]”
From 2D Transition‐Metal‐Dichalcogenide‐Nanosheet‐Based Composites for Photocatalytic and Electrocatalytic Hydrogen Evolution Reactions (2016) · cites this paper as [41]
The electrocatalytic HER activity of MoS2 can be improved by the introduced out-of-plane strain from the porous Au substrate.
“It was proved that the electrocatalytic HER activity of MoS 2 could be improved by the introduced outof-plane strain from the porous Au substrate.”
From 2D Transition‐Metal‐Dichalcogenide‐Nanosheet‐Based Composites for Photocatalytic and Electrocatalytic Hydrogen Evolution Reactions (2016) · cites this paper as [41]
Transition metal dichalcogenides (TMD) materials, such as MoS2, WS2, MoSe2, WSe2, and VSe2, are developed as potential alternatives to Pt-group electrocatalysts for HER due to their constrained electrons within two-dimensional layers.
“Transition metal dichalcogenides (TMD) materials, for instance, MoS2, WS2, MoSe2, WSe2, and VSe2, are developed as potential alternatives of Pt-group electrocatalysts for HER due to their constrained electrons within two-dimensional (2D) layers.2,15−21”
From In-Situ Growth of Few-Layered MoS<sub>2</sub> Nanosheets on Highly Porous Carbon Aerogel as Advanced Electrocatalysts for Hydrogen Evolution Reaction (2015) · cites this paper as [15]
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- Authors
- Tan, Y., Liu, P., Chen, L., Cong, W., Ito, Y., Han, J., Guo, X., Tang, Z., Fujita, T., Hirata, A., & Chen, M. W.
- Affiliations
- Tohoku University (JP)
- East China Normal University (CN)
- Shanghai Jiao Tong University (CN)
- Corresponding author
- Chen, Mingwei W.
- ORCID
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2014-10-31
- Volume
- 26
- Issue
- 47
- Pages
- 8023-8028
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2030873181
- Cited by
- 329
- References
- 9
- Citations by year
- 2026: 4 · 2025: 11 · 2024: 13 · 2023: 15 · 2022: 28 · 2021: 41 · 2020: 39 · 2019: 36 · 2018: 38 · 2017: 51 · 2016: 32 · 2015: 21
- FWCI
- 11.42
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Advanced Materials (publishedVersion)
- PubMed (publishedVersion)
- Funders
- National Science Foundation
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Materials Science › Materials Chemistry › 2D Materials and Applications
- Physical Sciences › Materials Science › Materials Chemistry › Hydrogen Storage and Materials
- Keywords
- monolayer MoS2, hydrogen evolution reaction, electrocatalysis, out-of-plane strain, lattice bending, semiconductor-metal transition, supported catalysts
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