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Accelerated Hydrogen Evolution Kinetics on NiFe‐Layered Double Hydroxide Electrocatalysts by Tailoring Water Dissociation Active Sites
Abstract
Owing to its earth abundance, low kinetic overpotential, and superior stability, NiFe‐layered double hydroxide (NiFe‐LDH) has emerged as a promising electrocatalyst for catalyzing water splitting, especially oxygen evolution reaction (OER), in alkaline solutions. Unfortunately, as a result of extremely sluggish water dissociation kinetics (Volmer step), hydrogen evolution reaction (HER) activity of the NiFe‐LDH is rather poor in alkaline environment. Here a novel strategy is demonstrated for substantially accelerating the hydrogen evolution kinetics of the NiFe‐LDH by partially substituting Fe atoms with Ru. In a 1 m KOH solution, the as‐synthesized Ru‐doped NiFe‐LDH nanosheets (NiFeRu‐LDH) exhibit excellent HER performance with an overpotential of 29 mV at 10 mA cm−2, which is much lower than those of noble metal Pt/C and reported electrocatalysts. Both experimental and theoretical results reveal that the introduction of Ru atoms into NiFe‐LDH can efficiently reduce energy barrier of the Volmer step, eventually accelerating its HER kinetics. Benefitting from its outstanding HER activity and remained excellent OER activity, the NiFeRu‐LDH steadily drives an alkaline electrolyzer with a current density of 10 mA cm−2 at a cell voltage of 1.52 V, which is much lower than the values for Pt/C–Ir/C couple and state‐of‐the‐art overall water‐splitting electrocatalysts.
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Cites
Combining theory and experiment in electrocatalysis: Insights into materials design
Seh, Z. W., Kibsgaard, J., Dickens, C. F., Chorkendorff, I., Nørskov, J. K., & Jaramillo, T. F. (2017) · Science · doi:10.1126/science.aad4998 · Cited by 12,114
Noble metal-free hydrogen evolution catalysts for water splitting
Zou, X., & Zhang, Y. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00448e · Cited by 5,955
Computational high-throughput screening of electrocatalytic materials for hydrogen evolution
Greeley, J., Jaramillo, T. F., Bonde, J., Chorkendorff, I., & Nørskov, J. K. (2006) · Nature Materials · doi:10.1038/nmat1752 · Cited by 4,097
Earth-abundant catalysts for electrochemical and photoelectrochemical water splitting
Roger, I., Shipman, M. A., & Symes, M. D. (2017) · Nature Reviews Chemistry · doi:10.1038/s41570-016-0003 · Cited by 3,503
Enhancing Hydrogen Evolution Activity in Water Splitting by Tailoring Li + -Ni(OH) 2 -Pt Interfaces
Subbaraman, R., Tripkovic, D., Strmcnik, D., Chang, K.-C., Uchimura, M., Paulikas, A. P., Stamenkovic, V., & Markovic, N. M. (2011) · Science · doi:10.1126/science.1211934 · Cited by 3,135
Hosseini, S. E., & Wahid, M. A. (2016) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2015.12.112 · Cited by 2,567
Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts
Luo, J., Im, J.-H., Mayer, M. T., Schreier, M., Nazeeruddin, M. K., Park, N.-G., Tilley, S. D., Fan, H. J., & Grätzel, M. (2014) · Science · doi:10.1126/science.1258307 · Cited by 2,509
Wu, H. B., Xia, B. Y., Yu, L., Yu, X.-Y., & Lou, X. W. (2015) · Nature Communications · doi:10.1038/ncomms7512 · Cited by 1,434
High-Performance Water Electrolysis System with Double Nanostructured Superaerophobic Electrodes
Xu, W., Lu, Z., Wan, P., Kuang, Y., & Sun, X. (2016) · Small · doi:10.1002/smll.201600189 · Cited by 156
Research works printed but not linked: 30
- 10.1126/science.1103197 · DOI · Paper page
- 10.1016/j.pecs.2009.11.002 · DOI · Paper page
- 10.1039/C6EE01786J · DOI · Paper page
- 10.1021/cr1002326 · DOI · Paper page
- 10.1126/science.1212858 · DOI · Paper page
- 10.1002/adma.201502696 · DOI · Paper page
- 10.1126/science.1185372 · DOI · Paper page
- 10.1021/acs.chemrev.6b00398 · DOI · Paper page
- 10.1002/aenm.201700518 · DOI · Paper page
- 10.1002/anie.201602237 · DOI · Paper page
- 10.1021/ja4027715 · DOI · Paper page
- 10.1039/C4CC01625D · DOI · Paper page
- 10.1038/ncomms7616 · DOI · Paper page
- 10.1016/j.ijhydene.2014.10.109 · DOI · Paper page
- 10.1038/ncomms15437 · DOI · Paper page
- 10.1038/nmat3313 · DOI · Paper page
- 10.1021/cr200434v · DOI · Paper page
- 10.1002/smll.201401464 · DOI · Paper page
- 10.1039/C4CS00160E · DOI · Paper page
- 10.1021/ja4027715 · DOI · Paper page
- 10.1016/j.nanoen.2017.06.027 · DOI · Paper page
- 10.1038/ncomms14969 · DOI · Paper page
- 10.1038/nmat4410 · DOI · Paper page
- 10.1038/ncomms11204 · DOI · Paper page
- 10.1002/adma.201605502 · DOI · Paper page
- 10.1038/ncomms5695 · DOI · Paper page
- 10.1038/nmat4481 · DOI · Paper page
- 10.1038/ncomms15341 · DOI · Paper page
- 10.1002/anie.201503407 · DOI · Paper page
- 10.1021/jacs.7b03507 · DOI · Paper page
Cited by
Support and Interface Effects in Water‐Splitting Electrocatalysts
Zhang, J., Zhang, Q., & Feng, X. (2019) · Advanced Materials · doi:10.1002/adma.201808167 · Cited by 916
Self-citationYu, L., Wu, L., McElhenny, B., Song, S., Luo, D., Zhang, F., Yu, Y., Chen, S., & Ren, Z. (2020) · Energy & Environmental Science · doi:10.1039/d0ee00921k · Cited by 877
Recent Advances and Prospective in Ruthenium-Based Materials for Electrochemical Water Splitting
Yu, J., He, Q., Yang, G., Zhou, W., Shao, Z., & Ni, M. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b02457 · Cited by 789
Zhou, K. L., Wang, Z., Han, C. B., Ke, X., Wang, C., Jin, Y., Zhang, Q., Liu, J., Wang, H., & Yan, H. (2021) · Nature Communications · doi:10.1038/s41467-021-24079-8 · Cited by 765
Hydrogen Evolution and Oxidation: Mechanistic Studies and Material Advances
Tian, X., Zhao, P., & Sheng, W. (2019) · Advanced Materials · doi:10.1002/adma.201808066 · Cited by 751
Metadata
- Authors
- Chen, G., Wang, T., Zhang, J., Liu, P., Sun, H., Zhuang, X., Chen, M., & Feng, X.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2018-01-19
- Volume
- 30
- Issue
- 10
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2789809168
- Cited by
- 934
- References
- 9
- FWCI
- 23.02
- Type
- journal article
- Language
- en
- Open access
- closed
- Funders
- European Research Council (2DMATER)
- European Commission (CNECT‐ICT‐604391)
- National Natural Science Foundation of China (21720102002)
- China Scholarship Council
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- Chen, G., Wang, T., Zhang, J., Liu, P., Sun, H., Zhuang, X., Chen, M., & Feng, X. (2018). Accelerated Hydrogen Evolution Kinetics on NiFe‐Layered Double Hydroxide Electrocatalysts by Tailoring Water Dissociation Active Sites. Advanced Materials. https://doi.org/10.1002/adma.201706279
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