The DOI matches its Crossref record; 12 of the 12 references it cites were found in a registry or an index.
Toward Stimuli‐Responsive Dynamic Thermosets through Continuous Development and Improvements in Covalent Adaptable Networks (CANs)
Abstract
Covalent adaptable networks (CANs), unlike typical thermosets or other covalently crosslinked networks, possess a unique, often dormant ability to activate one or more forms of stimuli‐responsive, dynamic covalent chemistries as a means to transition their behavior from that of a viscoelastic solid to a material with fluid‐like plastic flow. Upon application of a stimulus, such as light or other irradiation, temperature, or even a distinct chemical signal, the CAN responds by transforming to a state of temporal plasticity through activation of either reversible addition or reversible bond exchange, either of which allows the material to essentially re‐equilibrate to an altered set of conditions that are distinct from those in which the original covalently crosslinked network is formed, often simultaneously enabling a new and distinct shape, function, and characteristics. As such, CANs span the divide between thermosets and thermoplastics, thus offering unprecedented possibilities for innovation in polymer and materials science. Without attempting to comprehensively review the literature, recent developments in CANs are discussed here with an emphasis on the most effective dynamic chemistries that render these materials to be stimuli responsive, enabling features that make CANs more broadly applicable.
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Cites
Silica-Like Malleable Materials from Permanent Organic Networks
Montarnal, D., Capelot, M., Tournilhac, F., & Leibler, L. (2011) · Science · doi:10.1126/science.1212648 · Cited by 3,625
Hydrogels with tunable stress relaxation regulate stem cell fate and activity
Chaudhuri, O., Gu, L., Klumpers, D., Darnell, M., Bencherif, S. A., Weaver, J. C., Huebsch, N., Lee, H.-P., Lippens, E., Duda, G. N., et al. (2016) · Nature Materials · doi:10.1038/nmat4489 · Cited by 2,443
Covalent Adaptable Networks (CANs): A Unique Paradigm in Cross-Linked Polymers
Kloxin, C. J., Scott, T. F., Adzima, B. J., & Bowman, C. N. (2010) · Macromolecules · doi:10.1021/ma902596s · Cited by 1,175
Self-citationMechanically Activated, Catalyst-Free Polyhydroxyurethane Vitrimers
Fortman, D. J., Brutman, J. P., Cramer, C. J., Hillmyer, M. A., & Dichtel, W. R. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08084 · Cited by 811
Closed-loop recycling of plastics enabled by dynamic covalent diketoenamine bonds
Christensen, P. R., Scheuermann, A. M., Loeffler, K. E., & Helms, B. A. (2019) · Nature Chemistry · doi:10.1038/s41557-019-0249-2 · Cited by 676
Making Insoluble Polymer Networks Malleable via Olefin Metathesis
Lu, Y.-X., Tournilhac, F., Leibler, L., & Guan, Z. (2012) · Journal of the American Chemical Society · doi:10.1021/ja303356z · Cited by 568
Shape memory polymer network with thermally distinct elasticity and plasticity
Zhao, Q., Zou, W., Luo, Y., & Xie, T. (2016) · Science Advances · doi:10.1126/sciadv.1501297 · Cited by 514
Jin, B., Song, H., Jiang, R., Song, J., Zhao, Q., & Xie, T. (2018) · Science Advances · doi:10.1126/sciadv.aao3865 · Cited by 497
Reprocessable thermosets for sustainable three-dimensional printing
Zhang, B., Kowsari, K., Serjouei, A., Dunn, M. L., & Ge, Q. (2018) · Nature Communications · doi:10.1038/s41467-018-04292-8 · Cited by 398
Chen, M., Tian, J., Liu, Y., Cao, H., Li, R., Wang, J., Wu, J., & Zhang, Q. (2019) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.05.043 · Cited by 281
Cited by
Payne, J., & Jones, M. D. (2021) · ChemSusChem · doi:10.1002/cssc.202100400 · Cited by 426
Upcycling and catalytic degradation of plastic wastes
Hou, Q., Zhen, M., Qian, H., Nie, Y., Bai, X., Xia, T., Laiq Ur Rehman, M., Li, Q., & Ju, M. (2021) · Cell Reports Physical Science · doi:10.1016/j.xcrp.2021.100514 · Cited by 335
Balu, R., Dutta, N. K., & Roy Choudhury, N. (2022) · Polymers · doi:10.3390/polym14224788 · Cited by 121
Metadata
- Authors
- Podgórski, M., Fairbanks, B. D., Kirkpatrick, B. E., McBride, M., Martinez, A., Dobson, A., Bongiardina, N. J., & Bowman, C. N.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2020-02-14
- Volume
- 32
- Issue
- 20
- Pages
- e1906876-e1906876
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W3006011555
- Cited by
- 524
- References
- 12
- FWCI
- 24.93
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Podgórski, M., Fairbanks, B. D., Kirkpatrick, B. E., McBride, M., Martinez, A., Dobson, A., Bongiardina, N. J., & Bowman, C. N. (2020). Toward Stimuli‐Responsive Dynamic Thermosets through Continuous Development and Improvements in Covalent Adaptable Networks (CANs). Advanced Materials. https://doi.org/10.1002/adma.201906876
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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