The DOI matches its Crossref record; 31 of the 31 references it cites were found in a registry or an index.
Bidirectional Catalysts for Liquid–Solid Redox Conversion in Lithium–Sulfur Batteries
Abstract
Accelerated conversion by catalysis is a promising way to inhibit shuttling of soluble polysulfides in lithium–sulfur (Li–S) batteries, but most of the reported catalysts work only for one direction sulfur reaction (reduction or oxidation), which is still not a root solution since fast cycled use of sulfur species is not finally realized. A bidirectional catalyst design, oxide–sulfide heterostructure, is proposed to accelerate both reduction of soluble polysulfides and oxidation of insoluble discharge products (e.g., Li 2 S), indicating a fundamental way for improving both the cycling stability and sulfur utilization. Typically, a TiO 2–Ni 3 S 2 heterostructure is prepared by in situ growing TiO 2 nanoparticles on Ni 3 S 2 surface and the intimately bonded interfaces are the key for bidirectional catalysis. For reduction, TiO 2 traps while Ni 3 S 2 catalytically converts polysulfides. For oxidation, TiO 2 and Ni 3 S 2 both show catalytic activity for Li 2 S dissolution, refreshing the catalyst surface. The produced sulfur cathode with TiO 2–Ni 3 S 2 delivers a low capacity decay of 0.038% per cycle for 900 cycles at 0.5C and specially, with a sulfur loading of 3.9 mg cm−2, achieves a high capacity retention of 65% over 500 cycles at 0.3C. This work unlocks how a bidirectional catalyst works for boosting Li–S batteries approaching practical uses.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Henkelman, G., & Jónsson, H. (2000) · The Journal of Chemical Physics · doi:10.1063/1.1323224 · Cited by 9,523
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
Rechargeable Lithium–Sulfur Batteries
Manthiram, A., Fu, Y., Chung, S.-H., Zu, C., & Su, Y.-S. (2014) · Chemical Reviews · doi:10.1021/cr500062v · Cited by 4,665
Biesinger, M. C., Lau, L. W. M., Gerson, A. R., & Smart, R. S. C. (2010) · Applied Surface Science · doi:10.1016/j.apsusc.2010.07.086 · Cited by 4,592
Lithium–Sulfur Batteries: Electrochemistry, Materials, and Prospects
Yin, Y., Xin, S., Guo, Y., & Wan, L. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201304762 · Cited by 2,707
Advances in lithium–sulfur batteries based on multifunctional cathodes and electrolytes
Pang, Q., Liang, X., Kwok, C. Y., & Nazar, L. F. (2016) · Nature Energy · doi:10.1038/nenergy.2016.132 · Cited by 2,167
Wei Seh, Z., Li, W., Cha, J. J., Zheng, G., Yang, Y., McDowell, M. T., Hsu, P.-C., & Cui, Y. (2013) · Nature Communications · doi:10.1038/ncomms2327 · Cited by 2,107
Lithium–Sulfur Batteries: Progress and Prospects
Manthiram, A., Chung, S., & Zu, C. (2015) · Advanced Materials · doi:10.1002/adma.201405115 · Cited by 1,620
Zhang, J., Wang, T., Pohl, D., Rellinghaus, B., Dong, R., Liu, S., Zhuang, X., & Feng, X. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201602237 · Cited by 1,412
Self-citationTao, X., Wang, J., Liu, C., Wang, H., Yao, H., Zheng, G., Seh, Z. W., Cai, Q., Li, W., Zhou, G., et al. (2016) · Nature Communications · doi:10.1038/ncomms11203 · Cited by 1,391
Self-citation
Cited by
Interface engineering toward stable lithium–sulfur batteries
Guo, Y., Niu, Q., Pei, F., Wang, Q., Zhang, Y., Du, L., Zhang, Y., Zhang, Y., Zhang, Y., Fan, L., et al. (2024) · Energy & Environmental Science · doi:10.1039/d3ee04183b · Cited by 322
Self-citationLiu, W., Luo, C., Zhang, S., Zhang, B., Ma, J., Wang, X., Liu, W., Li, Z., Yang, Q.-H., & Lv, W. (2021) · ACS Nano · doi:10.1021/acsnano.1c00896 · Cited by 269
Self-citationDefect Engineering for Expediting Li–S Chemistry: Strategies, Mechanisms, and Perspectives
Shi, Z., Li, M., Sun, J., & Chen, Z. (2021) · Advanced Energy Materials · doi:10.1002/aenm.202100332 · Cited by 269
Metadata
- Authors
- Wang, R., Luo, C., Wang, T., Zhou, G., Deng, Y., He, Y., Zhang, Q., Kang, F., Lv, W., & Yang, Q.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2020-07-06
- Volume
- 32
- Issue
- 32
- Pages
- e2000315-e2000315
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W3039186878
- Cited by
- 423
- References
- 31
- FWCI
- 24.56
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Bidirectional Catalysts for Liquid–Solid Redox Conversion in Lithium–Sulfur Batteries. https://app.cochat.ai/papers/10.1002/adma.202000315
- The paper
- Wang, R., Luo, C., Wang, T., Zhou, G., Deng, Y., He, Y., Zhang, Q., Kang, F., Lv, W., & Yang, Q. (2020). Bidirectional Catalysts for Liquid–Solid Redox Conversion in Lithium–Sulfur Batteries. Advanced Materials. https://doi.org/10.1002/adma.202000315
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
