The DOI matches its Crossref record; 10 of the 10 references it cites were found in a registry or an index.
Sequential Phase Conversion‐Induced Phosphides Heteronanorod Arrays for Superior Hydrogen Evolution Performance to Pt in Wide pH Media
Abstract
Developing an efficient and non‐precious pH‐universal hydrogen evolution reaction electrocatalyst is highly desirable for hydrogen production by electrochemical water splitting but remains a significant challenge. Herein, a hierarchical structure composed of heterostructured Ni 2 P‐Ni 12 P 5 nanorod arrays rooted on Ni 3 S 2 film (Ni 2 P‐Ni 12 P 5@Ni 3 S 2) via a simultaneous corrosion and sulfidation is built followed by a phosphidation treatment toward the metallic nickel foam. The combination of theoretical calculations with in/ex situ characterizations unveils that such a unique sequential phase conversion strategy ensures the strong interfacial coupling between Ni 2 P and Ni 12 P 5 as well as the robust stabilization of 1D heteronanorod arrays by Ni 3 S 2 film, resulting in the promoted water adsorption/dissociation energy, the optimized hydrogen adsorption energy, and the enhanced electron/proton transfer ability accompanied with an excellent stability. Consequently, Ni 2 P‐Ni 12 P 5@Ni 3 S 2/NF requires only 32, 46, and 34 mV overpotentials to drive 10 mA cm−2 in 1.0 m KOH, 0.5 m H 2 SO 4, and 1.0 m phosphate‐buffered saline electrolytes, respectively, exceeding almost all the previously reported non‐noble metal‐based electrocatalysts. This work may pave a new avenue for the rational design of non‐precious electrocatalysts toward pH‐universal hydrogen evolution catalysis.
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Cites
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Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
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Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
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Cited by
Sun, H., Xu, X., Kim, H., Jung, W., Zhou, W., & Shao, Z. (2023) · ENERGY & ENVIRONMENTAL MATERIALS · doi:10.1002/eem2.12441 · Cited by 601
Xing, M., Zhu, S., Zeng, X., Wang, S., Liu, Z., & Cao, D. (2023) · Advanced Energy Materials · doi:10.1002/aenm.202302376 · Cited by 105
Li, C., Wang, N., Wang, S., Li, C., Fan, W., Liu, T., Chen, S., & Zhang, F. (2025) · Advanced Functional Materials · doi:10.1002/adfm.202423856 · Cited by 32
Xu, Y., Liu, T., Shi, K., Yu, H., Deng, K., Wang, X., Wang, Z., Wang, L., & Wang, H. (2022) · Journal of Materials Chemistry A · doi:10.1039/d2ta05151f · Cited by 31
Noble Metal Phosphides: Robust Electrocatalysts toward Hydrogen Evolution Reaction
Guo, B., Wen, X., Xu, L., Ren, X., Niu, S., YangCheng, R., Ma, G., Zhang, J., Guo, Y., Xu, P., et al. (2023) · Small Methods · doi:10.1002/smtd.202301469 · Cited by 29
Metadata
- Authors
- Yang, H., Guo, P., Wang, R., Chen, Z., Xu, H., Pan, H., Sun, D., Fang, F., & Wu, R.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2022-04-11
- Volume
- 34
- Issue
- 20
- Pages
- e2107548-e2107548
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W4220806205
- Cited by
- 224
- References
- 10
- FWCI
- 7.49
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Sequential Phase Conversion‐Induced Phosphides Heteronanorod Arrays for Superior Hydrogen Evolution Performance to Pt in Wide pH Media. https://app.cochat.ai/papers/10.1002/adma.202107548
- The paper
- Yang, H., Guo, P., Wang, R., Chen, Z., Xu, H., Pan, H., Sun, D., Fang, F., & Wu, R. (2022). Sequential Phase Conversion‐Induced Phosphides Heteronanorod Arrays for Superior Hydrogen Evolution Performance to Pt in Wide pH Media. Advanced Materials. https://doi.org/10.1002/adma.202107548
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