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Cited by 268

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Confined Growth of Silver–Copper Janus Nanostructures with {100} Facets for Highly Selective Tandem Electrocatalytic Carbon Dioxide Reduction

Open access
Ma, Yangbo, Yu, Jinli, Sun, Mingzi, Chen, Bo, Zhou, Xichen, Ye, Chenliang, Guan, Zhiqiang, Guo, Weihua, Wang, Gang, Lu, Shiyao, Xia, Dongsheng, Wang, Yunhao, He, Zhen, Zheng, Long, Yun, Qinbai, Wang, Liqiang, Zhou, Jingwen, Lu, Pengyi, Yin, Jinwen, Zhao, Yifei, Luo, Zhongbin, Zhai, Li, Liao, Lingwen, Zhu, Zonglong, Ye, Ruquan, Chen, Ye, Lu, Yang, Xi, Shibo, Huang, Bolong, Lee, Chun‐Sing, Fan, Zhanxi·2022·Advanced Materials

Abstract

Electrocatalytic carbon dioxide reduction reaction (CO 2 RR) holds significant potential to promote carbon neutrality. However, the selectivity toward multicarbon products in CO 2 RR is still too low to meet practical applications. Here the authors report the delicate synthesis of three kinds of Ag–Cu Janus nanostructures with {100} facets (JNS‐100) for highly selective tandem electrocatalytic reduction of CO 2 to multicarbon products. By controlling the surfactant and reduction kinetics of Cu precursor, the confined growth of Cu with {100} facets on one of the six equal faces of Ag nanocubes is realized. Compared with Cu nanocubes, Ag 65–Cu 35 JNS‐100 demonstrates much superior selectivity for both ethylene and multicarbon products in CO 2 RR at less negative potentials. Density functional theory calculations reveal that the compensating electronic structure and carbon monoxide spillover in Ag 65–Cu 35 JNS‐100 contribute to the enhanced CO 2 RR performance. This study provides an effective strategy to design advanced tandem catalysts toward the extensive application of CO 2 RR.

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Metadata

Authors
Ma, Y., Yu, J., Sun, M., Chen, B., Zhou, X., Ye, C., Guan, Z., Guo, W., Wang, G., Lu, S., Xia, D., Wang, Y., He, Z., Zheng, L., Yun, Q., Wang, L., Zhou, J., Lu, P., Yin, J., Zhao, Y., Luo, Z., Zhai, L., Liao, L., Zhu, Z., Ye, R., Chen, Y., Lu, Y., Xi, S., Huang, B., Lee, C., & Fan, Z.
Venue
Advanced Materials
Publisher
Wiley
Published
2022-04-05
Volume
34
Issue
19
Pages
e2110607-e2110607
ISSN
  • 0935-9648 (ISSN-L)
  • 1521-4095
OpenAlex
W4220723415
Cited by
268
References
7
FWCI
9.60
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Confined Growth of Silver–Copper Janus Nanostructures with {100} Facets for Highly Selective Tandem Electrocatalytic Carbon Dioxide Reduction. https://app.cochat.ai/papers/10.1002/adma.202110607
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Ma, Y., Yu, J., Sun, M., Chen, B., Zhou, X., Ye, C., Guan, Z., Guo, W., Wang, G., Lu, S., Xia, D., Wang, Y., He, Z., Zheng, L., Yun, Q., Wang, L., Zhou, J., Lu, P., Yin, J., . . . Fan, Z. (2022). Confined Growth of Silver–Copper Janus Nanostructures with {100} Facets for Highly Selective Tandem Electrocatalytic Carbon Dioxide Reduction. Advanced Materials. https://doi.org/10.1002/adma.202110607

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.