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Transition Metal‐Promoted V2CO2 (MXenes): A New and Highly Active Catalyst for Hydrogen Evolution Reaction
Open accessAbstract
Developing alternatives to precious Pt for hydrogen production from water splitting is central to the area of renewable energy. This work predicts extremely high catalytic activity of transition metal (Fe, Co, and Ni) promoted two‐dimensional MXenes, fully oxidized vanadium carbides (V 2 CO 2), for hydrogen evolution reaction (HER). The first‐principle calculations show that the introduction of transition metal can greatly weaken the strong binding between hydrogen and oxygen and engineer the hydrogen adsorption free energy to the optimal value ≈0 eV by choosing the suitable type and coverage of the promoters as well as the active sites. Strain engineering on the performance of transition metal promoted V 2 CO 2 further reveals that the excellent HER activities can maintain well while those poor ones can be modulated to be highly active. This study provides new possibilities for cost‐effective alternatives to Pt in HER and for the application of 2D MXenes.
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Cites
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
Kresse, G., & Furthmüller, J. (1996) · Physical Review B · doi:10.1103/physrevb.54.11169 · Cited by 123,652
Projector augmented-wave method
Blöchl, P. E. (1994) · Physical Review B · doi:10.1103/physrevb.50.17953 · Cited by 92,732
From ultrasoft pseudopotentials to the projector augmented-wave method
Kresse, G., & Joubert, D. (1999) · Physical Review B · doi:10.1103/physrevb.59.1758 · Cited by 85,307
Accurate and simple analytic representation of the electron-gas correlation energy
Perdew, J. P., & Wang, Y. (1992) · Physical Review B · doi:10.1103/physrevb.45.13244 · Cited by 25,089
Perdew, J. P., Chevary, J. A., Vosko, S. H., Jackson, K. A., Pederson, M. R., Singh, D. J., & Fiolhais, C. (1992) · Physical Review B · doi:10.1103/physrevb.46.6671 · Cited by 22,269
Perdew, J. P., Chevary, J. A., Vosko, S. H., Jackson, K. A., Pederson, M. R., Singh, D. J., & Fiolhais, C. (1993) · Physical Review B · doi:10.1103/physrevb.48.4978.2 · Cited by 17,144
Two‐Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2
Naguib, M., Kurtoglu, M., Presser, V., Lu, J., Niu, J., Heon, M., Hultman, L., Gogotsi, Y., & Barsoum, M. W. (2011) · Advanced Materials · doi:10.1002/adma.201102306 · Cited by 11,855
Sustainable Hydrogen Production
Turner, J. A. (2004) · Science · doi:10.1126/science.1103197 · Cited by 6,602
25th Anniversary Article: MXenes: A New Family of Two‐Dimensional Materials
Naguib, M., Mochalin, V. N., Barsoum, M. W., & Gogotsi, Y. (2014) · Advanced Materials · doi:10.1002/adma.201304138 · Cited by 6,414
Trends in the exchange current for hydrogen evolution
Nørskov, J. K., Bligaard, T., Logadottir, A., Kitchin, J. R., Chen, J. G., Pandelov, S., & Stimming, U. (2005) · Journal of The Electrochemical Society · doi:10.1149/1.1856988 · Cited by 6,121
Noble metal-free hydrogen evolution catalysts for water splitting
Zou, X., & Zhang, Y. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00448e · Cited by 5,955
MoS 2 Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction
Li, Y., Wang, H., Xie, L., Liang, Y., Hong, G., & Dai, H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201269b · Cited by 5,001
Alternative energy technologies
Dresselhaus, M. S., & Thomas, I. L. (2001) · Nature · doi:10.1038/35104599 · Cited by 4,894
Two-Dimensional Transition Metal Carbides
Naguib, M., Mashtalir, O., Carle, J., Presser, V., Lu, J., Hultman, L., Gogotsi, Y., & Barsoum, M. W. (2012) · ACS Nano · doi:10.1021/nn204153h · Cited by 4,769
Computational high-throughput screening of electrocatalytic materials for hydrogen evolution
Greeley, J., Jaramillo, T. F., Bonde, J., Chorkendorff, I., & Nørskov, J. K. (2006) · Nature Materials · doi:10.1038/nmat1752 · Cited by 4,097
Biomimetic Hydrogen Evolution: MoS 2 Nanoparticles as Catalyst for Hydrogen Evolution
Hinnemann, B., Moses, P. G., Bonde, J., Jørgensen, K. P., Nielsen, J. H., Horch, S., Chorkendorff, I., & Nørskov, J. K. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0504690 · Cited by 4,065
Tang, Q., Zhou, Z., & Shen, P. (2012) · Journal of the American Chemical Society · doi:10.1021/ja308463r · Cited by 2,254
New Two-Dimensional Niobium and Vanadium Carbides as Promising Materials for Li-Ion Batteries
Naguib, M., Halim, J., Lu, J., Cook, K. M., Hultman, L., Gogotsi, Y., & Barsoum, M. W. (2013) · Journal of the American Chemical Society · doi:10.1021/ja405735d · Cited by 2,150
Zheng, Y., Jiao, Y., Jaroniec, M., & Qiao, S. Z. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201407031 · Cited by 2,046
Novel Electronic and Magnetic Properties of Two‐Dimensional Transition Metal Carbides and Nitrides
Khazaei, M., Arai, M., Sasaki, T., Chung, C., Venkataramanan, N. S., Estili, M., Sakka, Y., & Kawazoe, Y. (2013) · Advanced Functional Materials · doi:10.1002/adfm.201202502 · Cited by 1,998
MXene: a promising transition metal carbide anode for lithium-ion batteries
Naguib, M., Come, J., Dyatkin, B., Presser, V., Taberna, P.-L., Simon, P., Barsoum, M. W., & Gogotsi, Y. (2012) · Electrochemistry Communications · doi:10.1016/j.elecom.2012.01.002 · Cited by 1,596
Xie, Y., Naguib, M., Mochalin, V. N., Barsoum, M. W., Gogotsi, Y., Yu, X., Nam, K.-W., Yang, X.-Q., Kolesnikov, A. I., & Kent, P. R. C. (2014) · Journal of the American Chemical Society · doi:10.1021/ja501520b · Cited by 1,537
Lu, Q., Yu, Y., Ma, Q., Chen, B., & Zhang, H. (2016) · Advanced Materials · doi:10.1002/adma.201503270 · Cited by 1,447
Prediction and Characterization of MXene Nanosheet Anodes for Non-Lithium-Ion Batteries
Xie, Y., Dall’Agnese, Y., Naguib, M., Gogotsi, Y., Barsoum, M. W., Zhuang, H. L., & Kent, P. R. C. (2014) · ACS Nano · doi:10.1021/nn503921j · Cited by 1,046
Rakhi, R. B., Ahmed, B., Hedhili, M. N., Anjum, D. H., & Alshareef, H. N. (2015) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b01623 · Cited by 981
Support nanostructure boosts oxygen transfer to catalytically active platinum nanoparticles
Vayssilov, G. N., Lykhach, Y., Migani, A., Staudt, T., Petrova, G. P., Tsud, N., Skála, T., Bruix, A., Illas, F., Prince, K. C., et al. (2011) · Nature Materials · doi:10.1038/nmat2976 · Cited by 889
A Review of Phosphide‐Based Materials for Electrocatalytic Hydrogen Evolution
Xiao, P., Chen, W., & Wang, X. (2015) · Advanced Energy Materials · doi:10.1002/aenm.201500985 · Cited by 844
Graphene-analogous low-dimensional materials
Tang, Q., & Zhou, Z. (2013) · Progress in Materials Science · doi:10.1016/j.pmatsci.2013.04.003 · Cited by 762
Tuning the MoS 2 Edge-Site Activity for Hydrogen Evolution via Support Interactions
Tsai, C., Abild-Pedersen, F., & Nørskov, J. K. (2014) · Nano Letters · doi:10.1021/nl404444k · Cited by 760
Eames, C., & Islam, M. S. (2014) · Journal of the American Chemical Society · doi:10.1021/ja508154e · Cited by 688
Hot Electron of Au Nanorods Activates the Electrocatalysis of Hydrogen Evolution on MoS2 Nanosheets
Shi, Y., Wang, J., Wang, C., Zhai, T.-T., Bao, W.-J., Xu, J.-J., Xia, X.-H., & Chen, H.-Y. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b01732 · Cited by 643
Self-citationMXene: A New Family of Promising Hydrogen Storage Medium
Hu, Q., Sun, D., Wu, Q., Wang, H., Wang, L., Liu, B., Zhou, A., & He, J. (2013) · The Journal of Physical Chemistry A · doi:10.1021/jp409585v · Cited by 518
Lu, P., Wu, X., Guo, W., & Zeng, X. C. (2012) · Physical Chemistry Chemical Physics · doi:10.1039/c2cp42181j · Cited by 486
Graphene, inorganic graphene analogs and their composites for lithium ion batteries
Jing, Y., Zhou, Z., Cabrera, C. R., & Chen, Z. (2014) · Journal of Materials Chemistry A · doi:10.1039/c4ta01033g · Cited by 282
Study of the Kinetics of Hydrogen Evolution Reaction on Nickel‐Zinc Alloy Electrodes
Chen, L., & Lasia, A. (1991) · Journal of The Electrochemical Society · doi:10.1149/1.2085409 · Cited by 276
Hu, Q., Wang, H., Wu, Q., Ye, X., Zhou, A., Sun, D., Wang, L., Liu, B., & He, J. (2014) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2014.05.037 · Cited by 233
Zhao, S., Kang, W., & Xue, J. (2014) · Applied Physics Letters · doi:10.1063/1.4870515 · Cited by 184
Molybdenum Sulfide Supported on Crumpled Graphene Balls for Electrocatalytic Hydrogen Production
Smith, A. J., Chang, Y., Raidongia, K., Chen, T., Li, L., & Huang, J. (2014) · Advanced Energy Materials · doi:10.1002/aenm.201400398 · Cited by 109
Noble metal-based composite nanomaterials fabricated via solution-based approaches
Liu, H., Yan, F., Chen, D., Li, C., Cui, P., & Yang, J. (2014) · Journal of Materials Chemistry A · doi:10.1039/c4ta05801a · Cited by 106
Noncovalent assembly of carbon nanotube-inorganic hybrids
Li, X., Qin, Y., Picraux, S. T., et al. (2011) · Journal of Materials Chemistry · doi:10.1039/c1jm10516g · Cited by 80
Cited by
Two-Dimensional Molybdenum Carbide (MXene) as an Efficient Electrocatalyst for Hydrogen Evolution
Seh, Z. W., Fredrickson, K. D., Anasori, B., Kibsgaard, J., Strickler, A. L., Lukatskaya, M. R., Gogotsi, Y., Jaramillo, T. F., & Vojvodic, A. (2016) · ACS Energy Letters · doi:10.1021/acsenergylett.6b00247 · Cited by 1,482
2D MXenes: A New Family of Promising Catalysts for the Hydrogen Evolution Reaction
Gao, G., O’Mullane, A. P., & Du, A. (2017) · ACS Catalysis · doi:10.1021/acscatal.6b02754 · Cited by 1,153
Pang, S.-Y., Wong, Y.-T., Yuan, S., Liu, Y., Tsang, M.-K., Yang, Z., Huang, H., Wong, W.-T., & Hao, J. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b02578 · Cited by 835
Peng, J., Chen, X., Ong, W.-J., Zhao, X., & Li, N. (2019) · Chem · doi:10.1016/j.chempr.2018.08.037 · Cited by 829
Hong Ng, V. M., Huang, H., Zhou, K., Lee, P. S., Que, W., Xu, J. Z., & Kong, L. B. (2017) · Journal of Materials Chemistry A · doi:10.1039/c6ta06772g · Cited by 784
Metadata
- Authors
- Ling, C., Shi, L., Ouyang, Y., Chen, Q., & Wang, J.
- Venue
- Advanced Science
- Publisher
- Wiley
- Published
- 2016-06-28
- Volume
- 3
- Issue
- 11
- Pages
- 1600180-1600180
- ISSN
- 2198-3844 (ISSN-L)
- OpenAlex
- W2467389410
- Cited by
- 367
- References
- 40
- FWCI
- 8.22
- Type
- journal article
- Language
- en
- Open access
- gold
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