The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Promotion of Overall Water Splitting Activity Over a Wide pH Range by Interfacial Electrical Effects of Metallic NiCo‐nitrides Nanoparticle/NiCo2O4 Nanoflake/graphite Fibers
Open accessAbstract
Many efforts have been made to develop bifunctional electrocatalysts to facilitate overall water splitting. Here, a fibrous bifunctional 3D electrocatalyst is reported for both the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER) with high performance. The remarkable electrochemical performance is attributed of the catalysts to a number of factors: the metallic character of the three components (i.e., Ni 3 N, CoN, and NiCo 2 O 4); the electronic structure, nanoflake‐nanosphere network with abundant electroactive sites, and the electric field effect at the interfaces between different components. The oxide–nitride/graphite fibers have the lowest overpotential requirements of 71 and 183 mV at 10 mA cm−2 for HER and OER in alkaline medium, respectively. These values are comparable to those of commercial Pt/C (20 wt%) and RuO 2. The electrodes also show a response to HER and OER in both neutral and acid media. Furthermore, the 3D structure can be highlighted by all‐round electrodes for overall water splitting. The calculations on the changes in electrons transfer and the Femi level from oxides to oxides/nitrides reveal that the observed superb electrocatalytic performance can be attributed to the presence of Ni 3 N and CoN derived from the in situ nitridation of NiCo 2 O 4.
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Cites
Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions
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Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
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Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis
Hong, W. T., Risch, M., Stoerzinger, K. A., Grimaud, A., Suntivich, J., & Shao-Horn, Y. (2015) · Energy & Environmental Science · doi:10.1039/c4ee03869j · Cited by 2,089
Metallic Nickel Nitride Nanosheets Realizing Enhanced Electrochemical Water Oxidation
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Cited by
Water Splitting: From Electrode to Green Energy System
Li, X., Zhao, L., Yu, J., Liu, X., Zhang, X., Liu, H., & Zhou, W. (2020) · Nano-Micro Letters · doi:10.1007/s40820-020-00469-3 · Cited by 619
Self-citationSun, H., Xu, X., Kim, H., Jung, W., Zhou, W., & Shao, Z. (2023) · ENERGY & ENVIRONMENTAL MATERIALS · doi:10.1002/eem2.12441 · Cited by 601
Precious Metal Free Hydrogen Evolution Catalyst Design and Application
Feidenhans’l, A. A., Regmi, Y. N., Wei, C., Xia, D., Kibsgaard, J., & King, L. A. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00712 · Cited by 499
Self-supported electrocatalysts for practical water electrolysis
Yang, H., Driess, M., & Menezes, P. W. (2021) · Advanced Energy Materials · doi:10.1002/aenm.202102074 · Cited by 489
Rational Design of Better Hydrogen Evolution Electrocatalysts for Water Splitting: A Review
Liu, F., Shi, C., Guo, X., He, Z., Pan, L., Huang, Z., Zhang, X., & Zou, J. (2022) · Advanced Science · doi:10.1002/advs.202200307 · Cited by 455
Metadata
- Authors
- Liu, Z., Tan, H., Liu, D., Liu, X., Xin, J., Xie, J., Zhao, M., Song, L., Dai, L., & Liu, H.
- Venue
- Advanced Science
- Publisher
- Wiley
- Published
- 2019-01-15
- Volume
- 6
- Issue
- 5
- Pages
- 1801829-1801829
- ISSN
- 2198-3844 (ISSN-L)
- OpenAlex
- W2910857927
- Cited by
- 182
- References
- 8
- FWCI
- 5.46
- Type
- journal article
- Language
- en
- Open access
- gold
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- Liu, Z., Tan, H., Liu, D., Liu, X., Xin, J., Xie, J., Zhao, M., Song, L., Dai, L., & Liu, H. (2019). Promotion of Overall Water Splitting Activity Over a Wide pH Range by Interfacial Electrical Effects of Metallic NiCo‐nitrides Nanoparticle/NiCo2O4 Nanoflake/graphite Fibers. Advanced Science. https://doi.org/10.1002/advs.201801829
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