The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
Superb Alkaline Hydrogen Evolution and Simultaneous Electricity Generation by Pt‐Decorated Ni3N Nanosheets
Abstract
The development of efficient hydrogen evolution reaction electrocatalysts is critical to the realization of clean hydrogen fuel production, while the sluggish kinetics of the Volmer‐step substantially restricts the catalyst performances in alkali electrolyzers, even for noble metal catalysts such as Pt. Here, a Pt‐decorated Ni 3 N nanosheet electrocatalyst is developed to achieve a top performance of hydrogen evolution in alkaline conditions. Possessing a high metallic conductivity and an atomic‐thin semiconducting hydroxide surface, the Ni 3 N nanosheets serve as not only an efficient electron pathway without the hindrance of Schottky barriers, but also provide abundant active sites for water dissociation and generation of hydrogen intermediates, which are further adsorbed on the Pt surface to recombine to H 2. The Pt‐decorated Ni 3 N nanosheet catalyst exhibits a hydrogen evolution current density of 200 mA cm−2 at an overpotential of 160 mV versus reversible hydrogen electrode, a Tafel slope of ≈36.5 mV dec−1, and excellent stability of 82.5% current retention after 24 h of operation. Moreover, a hybrid cell consisting of a Pt‐decorated Ni 3 N nanosheet cathode and a Li‐metal anode is assembled to achieve simultaneous hydrogen evolution and electricity generation, exhibiting >60 h long‐term hydrogen evolution reaction stability and an output voltage ranging from 1.3 to 2.2 V.
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Cites
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Enhancing Hydrogen Evolution Activity in Water Splitting by Tailoring Li + -Ni(OH) 2 -Pt Interfaces
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Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts
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Recent advances in transition metal-based electrocatalysts for alkaline hydrogen evolution
Chen, Z., Duan, X., Wei, W., Wang, S., & Ni, B.-J. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta03220g · Cited by 753
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In Situ Grown Epitaxial Heterojunction Exhibits High‐Performance Electrocatalytic Water Splitting
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Metadata
- Authors
- Wang, Y., Chen, L., Yu, X., Wang, Y., & Zheng, G.
- Venue
- Advanced Energy Materials
- Publisher
- Wiley
- Published
- 2016-09-26
- Volume
- 7
- Issue
- 2
- ISSN
- 1614-6832 (ISSN-L)
- 1614-6840
- OpenAlex
- W2525270132
- Cited by
- 259
- References
- 7
- FWCI
- 7.96
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, Y., Chen, L., Yu, X., Wang, Y., & Zheng, G. (2017). Superb Alkaline Hydrogen Evolution and Simultaneous Electricity Generation by Pt‐Decorated Ni3N Nanosheets. Advanced Energy Materials. https://doi.org/10.1002/aenm.201601390
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