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Applications of Phosphorene and Black Phosphorus in Energy Conversion and Storage Devices
Abstract
The successful isolation of phosphorene (atomic layer thick black phosphorus) in 2014 has currently aroused the interest of 2D material researchers. In this review, first, the fundamentals of phosphorus allotropes, phosphorene, and black phosphorus, are briefly introduced, along with their structures, properties, and synthesis methods. Second, the readers are presented with an overview of their energy applications. Particularly in electrochemical energy storage, the large interlayer spacing (0.53 nm) in phosphorene allows the intercalation/deintercalation of larger ions as compared to its graphene counterpart. Therefore, phosphorene may possess greater potential for high electrochemical performance. In addition, the status of lithium ion batteries as well as secondary sodium ion batteries is reviewed. Next, each application for energy generation, conversion, and storage is described in detail with milestones as well as the challenges. These emerging applications include supercapacitors, photovoltaic devices, water splitting, photocatalytic hydrogenation, oxygen evolution, and thermoelectric generators. Finally the fast‐growing dynamic field of phosphorene research is summarized and perspectives on future possibilities are presented calling on the efforts of chemists, physicists, and material scientists
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“Various piezoelectric, thermoelectric, and triboelectric energy harvesters have been developed based on the emerging 2D materials, such as MoS 2 , 119-123 graphene, 41,[124][125][126][127][128] and black phosphorus.129”
From From flexible electronics technology in the era of IoT and artificial intelligence toward future implanted body sensor networks (2019) · cites this paper as [129]
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Metadata
- Authors
- Pang, J., Bachmatiuk, A., Yin, Y., Trzebicka, B., Zhao, L., Fu, L., Mendes, R. G., Gemming, T., Liu, Z., & Rummeli, M. H.
- Affiliations
- Leibniz Institute for Solid State and Materials Research (DE)
- Centre of Polymer and Carbon Materials (PL)
- Soochow University (CN)
- Wuhan University (CN)
- Peking University (CN)
- The Leibniz Institute for Solid State and Materials Research Dresden (IFW Dresden) Helmholtzstr. 20 Dresden D‐01069 Germany
- ORCID
- Venue
- Advanced Energy Materials
- Publisher
- Wiley
- Published
- 2017-12
- Volume
- 8
- Issue
- 8
- ISSN
- 1614-6832 (ISSN-L)
- 1614-6840
- OpenAlex
- W2775596045
- Cited by
- 518
- References
- 1,133
- Citations by year
- 2026: 32 · 2025: 28 · 2024: 64 · 2023: 61 · 2022: 63 · 2021: 69 · 2020: 81 · 2019: 75 · 2018: 44 · 2017: 1
- FWCI
- 23.21
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Advanced Energy Materials (publishedVersion)
- Funders
- National Natural Science Foundation of China (51672181)
- Narodowym Centrum Nauki
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › 2D Materials and Applications
- Physical Sciences › Materials Science › Materials Chemistry › Graphene research and applications
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Keywords
- phosphorene, black phosphorus, phosphorus allotropes, two-dimensional materials, energy storage, energy conversion, lithium-ion batteries, sodium-ion batteries, intercalation, supercapacitors, photovoltaic devices, water splitting, photocatalytic hydrogenation, oxygen evolution reaction, thermoelectric generators
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