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A Process for the Synthesis of Formic Acid by CO2 Hydrogenation: Thermodynamic Aspects and the Role of CO
Abstract
Alcohol and CO: A new process for hydrogenating CO2 to formic acid has been developed. Calorimetric studies were carried out to clarify the role of the alcohol solvent in the catalytic cycle. CO2 hydrogenation is only thermodynamically feasible in the presence of hydrogen-bonding solvents. NMR spectroscopy indicates that catalytically active monocarbonyl complexes are formed when highly basic alkyl phosphine complexes are used as catalysts.
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Cited by
Carbon capture and storage (CCS): the way forward
Bui, M., Adjiman, C. S., Bardow, A., Anthony, E. J., Boston, A., Brown, S., Fennell, P. S., Fuss, S., Galindo, A., Hackett, L. A., et al. (2018) · Energy & Environmental Science · doi:10.1039/c7ee02342a · Cited by 4,374
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
Appel, A. M., Bercaw, J. E., Bocarsly, A. B., Dobbek, H., DuBois, D. L., Dupuis, M., Ferry, J. G., Fujita, E., Hille, R., Kenis, P. J. A., et al. (2013) · Chemical Reviews · doi:10.1021/cr300463y · Cited by 2,193
Large-scale storage of hydrogen
Andersson, J., & Grönkvist, S. (2019) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2019.03.063 · Cited by 1,356
Centi, G., Quadrelli, E. A., & Perathoner, S. (2013) · Energy & Environmental Science · doi:10.1039/c3ee00056g · Cited by 1,257
Mellmann, D., Sponholz, P., Junge, H., & Beller, M. (2016) · Chemical Society Reviews · doi:10.1039/c5cs00618j · Cited by 872
Metadata
- Authors
- Schaub, T., & Paciello, R. A.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2011-06-24
- Volume
- 50
- Issue
- 32
- Pages
- 7278-7282
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W1964370294
- Cited by
- 317
- References
- 0
- FWCI
- 12.32
- Type
- journal article
- Language
- en
- Open access
- closed
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- Schaub, T., & Paciello, R. A. (2011). A Process for the Synthesis of Formic Acid by CO2 Hydrogenation: Thermodynamic Aspects and the Role of CO. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201101292
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
