Cited by 1,378Ionic liquids properties and applicationsPhase Equilibria and ThermodynamicsLubricants and Their Additives

The DOI matches its Crossref record; 71 of the 71 references it cites were found in a registry or an index.

Low-transition-temperature mixtures (LTTMs): A new generation of designer solvents

Francisco, María, van den Bruinhorst, Adriaan, Kroon, Maaike C.·2013·Angewandte Chemie International Edition

DOI 10.1002/anie.201207548

Open this paper in CoChat — free account

Abstract

A new generation of designer solvents emerged in the last decade as promising green media for multiple applications, including separation processes: the low‐transition‐temperature mixtures (LTTMs). They can be prepared by mixing natural high‐melting‐point starting materials, which form a liquid by hydrogen‐bond interactions. Among them, deep‐eutectic solvents (DESs) were presented as promising alternatives to conventional ionic liquids (ILs). Some limitations of ILs are overcome by LTTMs, which are cheap and easy to prepare from natural and readily available starting materials, biodegradable, and renewable.

Integrity signals

Registry

Crossref · 10.1002/anie.201207548

Cites

71 of 71 references verified0 citation errors · 0 not checkable

Statistics

Recomputing p-values needs the paper’s full text.

Claims the paper makes

This paper’s full text isn’t openly available, so its claims and self-check weren’t run. The registry and citation checks still apply.

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

Novel solvent properties of choline chloride/urea mixturesElectronic supplementary information (ESI) available: spectroscopic data. See http://www.rsc.org/suppdata/cc/b2/b210714g/
Abbott, A. P., Capper, G., Davies, D. L., Rasheed, R. K., & Tambyrajah, V. (2003) · Chemical Communications · doi:10.1039/b210714g · Cited by 5,738
Deep eutectic solvents: syntheses, properties and applications
Zhang, Q., De Oliveira Vigier, K., Royer, S., & Jérôme, F. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35178a · Cited by 4,899
Deep eutectic solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids
Abbott, A. P., Boothby, D., Capper, G., Davies, D. L., & Rasheed, R. K. (2004) · Journal of the American Chemical Society · doi:10.1021/ja048266j · Cited by 4,340
ANALYSIS OF RECENT MEASUREMENTS OF THE VISCOSITY OF GLASSES
Fulcher, G. S. (1925) · Journal of the American Ceramic Society · doi:10.1111/j.1151-2916.1925.tb16731.x · Cited by 4,199
Ionic liquids. Green solvents for the future
Earle, M. J., & Seddon, K. R. (2000) · Pure and Applied Chemistry · doi:10.1351/pac200072071391 · Cited by 2,813
Origins, Current Status, and Future Challenges of Green Chemistry
Anastas, P. T., & Kirchhoff, M. M. (2002) · Accounts of Chemical Research · doi:10.1021/ar010065m · Cited by 2,221
What is a green solvent? A comprehensive framework for the environmental assessment of solvents
Capello, C., Fischer, U., & Hungerbühler, K. (2007) · Green Chemistry · doi:10.1039/b617536h · Cited by 1,917
The properties of organic liquids that are relevant to their use as solvating solvents
Marcus, Y. (1993) · Chemical Society Reviews · doi:10.1039/cs9932200409 · Cited by 1,637
Are Natural Deep Eutectic Solvents the Missing Link in Understanding Cellular Metabolism and Physiology?
Choi, Y. H., van Spronsen, J., Dai, Y., Verberne, M., Hollmann, F., Arends, I. W. C. E., Witkamp, G.-J., & Verpoorte, R. (2011) · Plant Physiology · doi:10.1104/pp.111.178426 · Cited by 1,368
Organic chemistry in water
LI, C. ‐., & Chen, L. (2005) · Chemical Society Reviews · doi:10.1039/b507207g · Cited by 1,335

Flagged first, then by citations

Show all 71 references

Research works printed but not linked: 3

Savchenko P. S., 1959, Russ. J. Inorg. Chem., 4, 186
R. C. Harris Physical Properties of Alcohol‐Based Deep‐Eutectic Solvents Ph.d. Thesis University of Leicester 2009.
Feynman R. P., 1960, Eng. Sci., 23, 22

Sorted by citations

Items 401–500 of 1,000

A new era of chitin synthesis and dissolution using deep eutectic solvents- comparison with ionic liquids
Sulthan, R., Reghunadhan, A., & Sambhudevan, S. (2023) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2023.121794 · Cited by 68
Deep eutectic solvents in countercurrent and centrifugal partition chromatography
Roehrer, S., Bezold, F., García, E. M., & Minceva, M. (2016) · Journal of Chromatography A · doi:10.1016/j.chroma.2016.01.024 · Cited by 66
CO2 solubility in and physical properties for ionic liquid mixtures of 1-butyl-3-methylimidazolium acetate and 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide
Kanakubo, M., Makino, T., & Umecky, T. (2016) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2016.02.018 · Cited by 64
Superbase‐Added Choline Chloride‐Based Deep Eutectic Solvents for CO 2 Capture and Sequestration
Bhawna, B., Pandey, A., & Pandey, S. (2017) · ChemistrySelect · doi:10.1002/slct.201702259 · Cited by 64
Evidence of Molecular Heterogeneities in Amide-Based Deep Eutectic Solvents
Cui, Y., & Kuroda, D. G. (2018) · The Journal of Physical Chemistry A · doi:10.1021/acs.jpca.7b10264 · Cited by 64
A novel aqueous biphasic system formed by deep eutectic solvent and ionic liquid for DNA partitioning
Xu, P., Wang, Y., Chen, J., Wei, X., Xu, W. J., Ni, R., Meng, J., & Zhou, Y. (2018) · Talanta · doi:10.1016/j.talanta.2018.07.035 · Cited by 64
Ternary hydrophobic deep eutectic solvents for carbon dioxide absorption
Haider, M. B., Jha, D., Kumar, R., & Sivagnanam, B. M. (2019) · International journal of greenhouse gas control · doi:10.1016/j.ijggc.2019.102839 · Cited by 64
Tuning thin-film composite reverse osmosis membranes using deep eutectic solvents and ionic liquids toward enhanced water permeation
Shahabi, S. S., Azizi, N., & Vatanpour, V. (2020) · Journal of Membrane Science · doi:10.1016/j.memsci.2020.118267 · Cited by 64
Molecular imprinting with deep eutectic solvents: Synthesis, applications, their significance, and benefits
Madikizela, L. M., Ncube, S., Nomngongo, P. N., & Pakade, V. E. (2022) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2022.119696 · Cited by 63
Deep eutectic solvents – Ideal solution for clean air or hidden danger?
Janjhi, F. A., Castro-Muñoz, R., & Boczkaj, G. (2023) · Separation and Purification Technology · doi:10.1016/j.seppur.2023.123590 · Cited by 63
Variation of Density, Viscosity, and Electrical Conductivity of the Deep Eutectic Solvent Reline, Composed of Choline Chloride and Urea at a Molar Ratio of 1:2, Mixed with Dimethylsulfoxide as a Cosolvent
Agieienko, V. N., & Buchner, R. (2020) · Journal of Chemical & Engineering Data · doi:10.1021/acs.jced.9b01105 · Cited by 62
Smart Nanosystems for Biomedicine, Optoelectronics and Catalysis
Shabatina, T. I., & Bochenkov, V. E. (2019) · IntechOpen eBooks · doi:10.5772/intechopen.83226 · Cited by 62
Advances in the application of deep eutectic solvents based aqueous biphasic systems: An up-to-date review
Oke, E. A., & Ijardar, S. P. (2021) · Biochemical Engineering Journal · doi:10.1016/j.bej.2021.108211 · Cited by 64
Deep eutectic solvent catalyzed Friedel–Crafts alkylation of electron-rich arenes with aldehydes
Wang, A., Xing, P., Zheng, X., Cao, H., Yang, G., & Zheng, X. (2015) · RSC Advances · doi:10.1039/c5ra08950f · Cited by 62
Molecularly Heterogeneous Structure of a Nonionic Deep Eutectic Solvent Composed of N-Methylacetamide and Lauric Acid
Cui, Y., Rushing, J. C., Seifert, S., Bedford, N. M., & Kuroda, D. G. (2019) · The Journal of Physical Chemistry B · doi:10.1021/acs.jpcb.8b11732 · Cited by 63
Natural deep eutectic solvents as an efficient and reusable active system for the Nazarov cyclization
Nejrotti, S., Iannicelli, M., Jamil, S. S., Arnodo, D., Blangetti, M., & Prandi, C. (2019) · Green Chemistry · doi:10.1039/c9gc03465j · Cited by 62
Carbon Dioxide Capture and Utilization by Alkanolamines in Deep Eutectic Solvent Medium
Maheswari, A. U., & Palanivelu, K. (2015) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.5b01818 · Cited by 61
Natural Deep Eutectic Solvents in Extraction Process
Owczarek, K., Szczepańska, N., Płotka‐Wasylka, J., Rutkowska, M., Shyshchak, O., Bratychak, M., & Namieśnik, J. (2016) · Chemistry & Chemical Technology · doi:10.23939/chcht10.04si.601 · Cited by 61
Controllable green synthesis of crassula peforata-like TiO2 with high photocatalytic activity based on deep eutectic solvent (DES)
Wang, Q. H., Dong, B., Zhao, Y., Huang, F., Xie, J., Cui, G., & Tang, B. (2018) · Chemical Engineering Journal · doi:10.1016/j.cej.2018.05.020 · Cited by 61
Thermoplastic starch with deep eutectic solvents and montmorillonite as a base for composite materials
Adamus, J., Spychaj, T., Zdanowicz, M., & Jędrzejewski, R. (2018) · Industrial Crops and Products · doi:10.1016/j.indcrop.2018.06.069 · Cited by 61
Synthesis and characterization of green menthol-based low transition temperature mixture with tunable thermophysical properties as hydrophobic low viscosity solvent
Mat Hussin, S. A., Varanusupakul, P., Shahabuddin, S., Yih Hui, B., & Mohamad, S. (2020) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2020.113015 · Cited by 60
Protic guanidine isothiocyanate plus acetamide deep eutectic solvents with low viscosity for efficient NH3 capture and NH3/CO2 separation
Deng, D., Deng, X., Duan, X., & Gong, L. (2020) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2020.114719 · Cited by 60
Chemoselective synthesis of xanthenes and tetraketones in a choline chloride-based deep eutectic solvent
Azizi, N., Dezfooli, S., & Hashemi, M. M. (2013) · Comptes Rendus Chimie · doi:10.1016/j.crci.2013.05.002 · Cited by 60
A hydrophobic deep eutectic solvent mediated sol-gel coating of solid phase microextraction fiber for determination of toluene, ethylbenzene and o-xylene in water coupled with GC-FID
Li, T., Song, Y., Xu, J., & Fan, J. (2019) · Talanta · doi:10.1016/j.talanta.2018.11.085 · Cited by 59
A novel ternary deep eutectic solvent for efficient recovery of critical metals from spent lithium-ion batteries under mild conditions
Liao, Y., Gong, S., Wang, G., Wu, T. H., Meng, X., Huang, Q., Su, Y., Wu, F., & Kelly, R. (2022) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2022.108627 · Cited by 59
Choline Chloride- and Organic Acids-Based Deep Eutectic Solvents: Exploring Chemical and Thermophysical Properties
dos Santos, M. R. M., Lima, Á. S., Oliveira, G. D. A. R., Lião, L. M., Franceschi, E., da Silva, R., & Cardozo‐Filho, L. (2024) · Journal of Chemical & Engineering Data · doi:10.1021/acs.jced.3c00706 · Cited by 60
Free-radical polymerization of itaconic acid in the presence of choline salts: Mechanism of persulfate decomposition
Bednarz, S., Błaszczyk, A., Błażejewska, D., & Bogdał, D. (2014) · Catalysis Today · doi:10.1016/j.cattod.2014.07.021 · Cited by 59
Novel Acidic Deep Eutectic Solvent-Based Aqueous Biphasic Systems for Efficient Extraction of Pepsin
Marchel, M., Coroadinha, A. S., & Marrucho, I. M. (2020) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.0c02673 · Cited by 60
Deep eutectic solvents for the preparation and post-synthetic modification of metal- and covalent organic frameworks
Maia, R. A., Louis, B., & Baudron, S. A. (2021) · CrystEngComm · doi:10.1039/d1ce00714a · Cited by 58
Isopropanol dehydration via extractive distillation using low transition temperature mixtures as entrainers
Rodriguez, N. R., & Kroon, M. C. (2015) · The Journal of Chemical Thermodynamics · doi:10.1016/j.jct.2015.02.003 · Cited by 58
Self-citation
An Expeditious and Greener Synthesis of 2-Aminoimidazoles in Deep Eutectic Solvents
Capua, M., Perrone, S., Perna, F. M., Vitale, P., Troisi, L., Salomone, A., & Capriati, V. (2016) · Molecules · doi:10.3390/molecules21070924 · Cited by 58
Solute Rotation and Translation Dynamics in an Ionic Deep Eutectic Solvent Based on Choline Chloride
Hossain, S. S., & Samanta, A. (2017) · The Journal of Physical Chemistry B · doi:10.1021/acs.jpcb.7b08472 · Cited by 60
Oil desulfurization using deep eutectic solvents as sustainable and economical extractants via liquid-liquid extraction: Experimental and PC-SAFT predictions
Warrag, S. E. E., Pototzki, C., Rodriguez, N. R., Annaland, M. V. S., Kroon, M. C., Held, C., Sadowski, G., & Peters, C. J. (2018) · Fluid Phase Equilibria · doi:10.1016/j.fluid.2018.03.018 · Cited by 58
Self-citation
Designing Eco‐Sustainable Dye‐Sensitized Solar Cells by the Use of a Menthol‐Based Hydrophobic Eutectic Solvent as an Effective Electrolyte Medium
Boldrini, C. L., Manfredi, N., Perna, F. M., Capriati, V., & Abbotto, A. (2018) · Chemistry – A European Journal · doi:10.1002/chem.201803668 · Cited by 58
Modelling and simulation of CO2 removal from shale gas using deep eutectic solvents
Haider, M. B., Jha, D., Sivagnanam, B. M., & Kumar, R. (2018) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2018.10.061 · Cited by 59
Optimization of the extraction process of flavonoids from Trollius ledebouri with natural deep eutectic solvents
Zuo, J., Ma, P., Geng, S., Kong, Y., Li, X., Fan, Z., Zhang, Y., Dong, A., & Zhou, Q. (2021) · Journal of Separation Science · doi:10.1002/jssc.202100802 · Cited by 57
An Efficient Four Component Domino Synthesis of Pyrazolopyranopyrimidines using Recyclable Choline Chloride:Urea Deep Eutectic Solvent
Tipale, M. R., Khillare, L. D., Deshmukh, A. R., & Bhosle, M. R. (2018) · Journal of Heterocyclic Chemistry · doi:10.1002/jhet.3095 · Cited by 57
New deep eutectic solvents composed of crown ether, hydroxide and polyethylene glycol for extraction of non-basic N-compounds
Ali, M. C., Liu, R., Chen, J., Cai, T., Zhang, H., Li, Z., Zhai, H., & Qiu, H. (2019) · Chinese Chemical Letters · doi:10.1016/j.cclet.2019.02.025 · Cited by 57
Deep eutectic solvents consisting of 1-ethyl-3-methylimidazolium chloride and glycerol derivatives for highly efficient and reversible SO2 capture
Long, G., Yang, C., Yang, X., Zhao, T., & Xu, M. (2020) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2020.112538 · Cited by 57
Extraction of pyridine from n-alkane mixtures using methyltriphenylphosphonium bromide-based deep eutectic solvents as extractive denitrogenation agents
Warrag, S. E. E., Darwish, A. S., Adeyemi, I., Hadj-Kali, M. K., Kroon, M. C., & AlNashef, I. M. (2020) · Fluid Phase Equilibria · doi:10.1016/j.fluid.2020.112622 · Cited by 57
Self-citation
Combined Extractive Dearomatization, Desulfurization, and Denitrogenation of Oil Fuels Using Deep Eutectic Solvents: A Parametric Study
Warrag, S. E. E., Darwish, A. S., Hatab, F. A., Adeyemi, I., Kroon, M. C., & AlNashef, I. M. (2020) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.0c01360 · Cited by 57
Self-citation
Structure–properties relationships of deep eutectic solvents formed between choline chloride and carboxylic acids: Experimental and computational study
Zhang, M., Zhao, X., Tang, S., Wu, K., Wang, B., Liu, Y., Zhu, Y., Lu, H., & Liang, B. (2022) · Journal of Molecular Structure · doi:10.1016/j.molstruc.2022.134283 · Cited by 57
A comprehensive review on recent developments and future perspectives of switchable solvents and their applications in sample preparation techniques
Ullah, N., & Tüzen, M. (2023) · Green Chemistry · doi:10.1039/d3gc00020f · Cited by 57
Towards a better understanding of how to improve lipase‐catalyzed reactions using deep eutectic solvents based on choline chloride
Durand, E., Lecomte, J., Baréa, B., & Villeneuve, P. (2013) · European Journal of Lipid Science and Technology · doi:10.1002/ejlt.201300246 · Cited by 59
A Sustainable Route towards Imidazolium Building Blocks Based on Biomass Molecules
Esposito, D., Kirchhecker, S., & Antonietti, M. (2013) · Chemistry - A European Journal · doi:10.1002/chem.201302806 · Cited by 56
How do we drive deep eutectic systems towards an industrial reality?
Paiva, A., Matias, A. A., & Duarte, A. R. C. (2018) · Current Opinion in Green and Sustainable Chemistry · doi:10.1016/j.cogsc.2018.05.010 · Cited by 56
Green aerobic oxidative desulfurization of diesel by constructing an Fe-Anderson type polyoxometalate and benzene sulfonic acid-based deep eutectic solvent biomimetic cycle
Xu, J., Zhu, Z., Su, T., Liao, W., Deng, C., Hao, D., Zhao, Y., Ren, W., & Lü, H. (2020) · CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION) · doi:10.1016/s1872-2067(19)63500-x · Cited by 56
Synthesis of low-viscosity hydrophobic magnetic deep eutectic solvent: Selective extraction of DNA
Peng, F., Liu, M., Wang, X., & Ding, X. (2021) · Analytica Chimica Acta · doi:10.1016/j.aca.2021.338899 · Cited by 56
High-performance of deep eutectic solvent based aqueous bi-phasic systems for the extraction of DNA
Li, N., Wang, Y., Xu, K., Wen, Q., Ding, X., Zhang, H., & Yang, Q. M. (2016) · RSC Advances · doi:10.1039/c6ra17689e · Cited by 55
Microwave-assisted deep eutectic-solvothermal preparation of iron oxide nanoparticles for photoelectrochemical solar water splitting
Hammond, O. S., Eslava, S., Smith, A. J. A., Zhang, J., & Edler, K. J. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta02078c · Cited by 56
Glycerol as a source of designer solvents: physicochemical properties of low melting mixtures containing glycerol ethers and ammonium salts
Leal‐Duaso, A., Pérez, P., Mayoral, J. A., Pires, E., & García, J. I. (2017) · Physical Chemistry Chemical Physics · doi:10.1039/c7cp04987k · Cited by 56
Aqueous biphasic systems formed by deep eutectic solvent and new-type salts for the high-performance extraction of pigments
Zhang, H., Wang, Y., Zhou, Y., Chen, J., Wei, X., & Xu, P. (2018) · Talanta · doi:10.1016/j.talanta.2018.01.014 · Cited by 56
One-pot synthesis of hydrophilic and hydrophobic fluorescent carbon dots using deep eutectic solvents as designer reaction media
Çalhan, S. D., Alaş, M. Ö., Aşık, M., Kaya, F. N. D., & Genç, R. (2018) · Journal of Materials Science · doi:10.1007/s10853-018-2723-4 · Cited by 55
Tailor-Made Deep Eutectic Solvents for Simultaneous Extraction of Five Aromatic Acids from Ginkgo biloba Leaves
Cao, J., Wang, H., Zhang, W., Cao, F., Ge-li, M., & Su, E. (2018) · Molecules · doi:10.3390/molecules23123214 · Cited by 55
Comparing a deep eutectic solvent (DES) to a hydrotrope for their ability to enhance the fractionation and enzymatic hydrolysis of willow and corn stover
Song, Y., Chandra, R. P., Zhang, X., Tan, T., & Saddler, J. N. (2019) · Sustainable Energy & Fuels · doi:10.1039/c8se00617b · Cited by 55
Process analysis of extractive distillation for the separation of ethanol–water using deep eutectic solvent as entrainer
Shang, X., Ma, S., Pan, Q., Li, J., Sun, Y., Ji, K., & Sun, L. (2019) · Process Safety and Environmental Protection · doi:10.1016/j.cherd.2019.06.014 · Cited by 55
Effect of Ternary Deep Eutectic Solvents on Bagasse Cellulose and Lignin Structure in Low-Temperature Pretreatment
Yang, Y., Zhao, L., Ren, J., & He, B. (2022) · Processes · doi:10.3390/pr10040778 · Cited by 54
Evaluation of deep eutectic solvents as co‐solvent for steroids 1‐en‐dehydrogenation biotransformation by Arthrobacter simplex
Mao, S., Yu, L., Ji, S., Liu, X., & Lu, F. (2015) · Journal of Chemical Technology & Biotechnology · doi:10.1002/jctb.4691 · Cited by 54
Green effervescence assisted dispersive liquid–liquid microextraction based on a hydrophobic deep eutectic solvent for determination of Sunset Yellow and Brilliant Blue FCF in food samples
Ravandi, M. G., & Fat’hi, M. R. (2018) · New Journal of Chemistry · doi:10.1039/c8nj00782a · Cited by 54
Catalytic conversion of herbal residue carbohydrates to furanic derivatives in a deep eutectic solvent accompanied by dissolution and recrystallisation of choline chloride
Yu, Q., Song, Z., Zhuang, X., Liu, L., Qiu, W., Shi, J., Wang, W., Li, Y., Wang, Z., & Yuan, Z. (2019) · Cellulose · doi:10.1007/s10570-019-02372-6 · Cited by 54
DESs: Green solvents for transition metal catalyzed organic reactions
Peng, L., Hu, Z., Lu, Q., Tang, Z., Jiao, Y., & Xu, X. (2019) · Chinese Chemical Letters · doi:10.1016/j.cclet.2019.05.063 · Cited by 54
Comparison of hydrophilic and hydrophobic deep eutectic solvents for pretreatment determination of sulfonamides from aqueous environments
Ma, Y., Wang, Q., & Zhu, T. (2019) · Analytical Methods · doi:10.1039/c9ay02244a · Cited by 54
Efficient Absorption of Low Partial Pressure SO2 by 1-Ethyl-3-methylimidazolium Chloride Plus N-Formylmorpholine Deep Eutectic Solvents
Deng, D., Zhang, C., Deng, X., & Gong, L. (2019) · Energy & Fuels · doi:10.1021/acs.energyfuels.9b03235 · Cited by 54
Study on the Desulfurization and Regeneration Performance of Functional Deep Eutectic Solvents
Wang, B., Cheng, J. B., Wang, D., Li, X., Meng, Q., Zhang, Z., An, J., Liu, X., & Li, M. (2020) · ACS Omega · doi:10.1021/acsomega.0c01467 · Cited by 54
Novel Nonanol-Based deep eutectic solvents: Thermophysical properties and their applications in Liquid-Liquid extraction and amino acid detection
Omar, K. A., & Sadeghi, R. (2021) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2021.116359 · Cited by 56
Deep Eutectic Solvent Formulations and Alginate-Based Hydrogels as a New Partnership for the Transdermal Administration of Anti-Inflammatory Drugs
Pedro, S. N., Mendes, M. S. M., Neves, B. M., Almeida, I. F., Costa, P. C., Correia‐Sá, I., Vilela, C., Freire, M. G., Silvestre, A. J. D., & Freire, C. S. R. (2022) · Pharmaceutics · doi:10.3390/pharmaceutics14040827 · Cited by 53
A comprehensive review: Evaluating emerging green leaching technologies for recycling spent lithium-ion batteries
Shi, H., Zhang, J., & Ou, L. (2025) · Chemical Engineering Journal · doi:10.1016/j.cej.2025.160006 · Cited by 53
Aliphatic+ethanol separation via liquid–liquid extraction using low transition temperature mixtures as extracting agents
Rodriguez, N. R., Molina, B. S., & Kroon, M. C. (2015) · Fluid Phase Equilibria · doi:10.1016/j.fluid.2015.03.017 · Cited by 53
Self-citation
Experimental determination of the LLE data of systems consisting of {hexane + benzene + deep eutectic solvent} and prediction using the Conductor-like Screening Model for Real Solvents
Rodriguez, N. R., Gerlach, T. H., Scheepers, D., Kroon, M. C., & Smirnova, I. V. (2016) · The Journal of Chemical Thermodynamics · doi:10.1016/j.jct.2016.09.021 · Cited by 54
Self-citation
Synthesis of cyclic carbonates from CO 2 and propylene oxide (PO) with deep eutectic solvents (DESs) based on amino acids (AAs) and dicarboxylic acids
Lü, H., Wu, K., Zhao, Y., Hao, L., Liao, W., Deng, C., & Ren, W. (2017) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2017.10.024 · Cited by 53
Sustainable Water Reclamation from Different Feed Streams by Forward Osmosis Process Using Deep Eutectic Solvents as Reusable Draw Solution
Mahto, A., Mondal, D., Polisetti, V., Bhatt, J., Nidhi Maalige, R., Prasad, K., & Nataraj, S. K. (2017) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.7b03046 · Cited by 55
How do the hydrocarbon chain length and hydroxyl group position influence the solute dynamics in alcohol-based deep eutectic solvents?
Hossain, S. S., & Samanta, A. (2018) · Physical Chemistry Chemical Physics · doi:10.1039/c8cp04859b · Cited by 54
Novel low viscous hydrophobic deep eutectic solvents liquid-liquid microextraction combined with acid base induction for the determination of phthalate esters in the packed milk samples
Wang, X., Lu, Y., Shi, L., Yang, D., & Yang, Y. (2020) · Microchemical Journal · doi:10.1016/j.microc.2020.105332 · Cited by 55
Ultrasound-assisted emulsification liquid phase microextraction method based on deep eutectic solvent as extraction solvent for determination of five pesticides in traditional Chinese medicine
Li, X., Wang, M., Zhao, J., Guo, H., Gao, X., Xiong, Z., & Zhao, L. (2019) · Journal of Pharmaceutical and Biomedical Analysis · doi:10.1016/j.jpba.2019.01.018 · Cited by 52
Efficient fractionation of woody biomass hemicelluloses using cholinium amino acids-based deep eutectic solvents and their aqueous mixtures
Wang, Y., Zhang, W., Yang, J., Li, M., Peng, F., & Bian, J. (2022) · Bioresource Technology · doi:10.1016/j.biortech.2022.127139 · Cited by 52
Green and Economical Bet-Based Natural Deep Eutectic Solvents: A Novel High-Performance Lubricant
Li, Y., Li, H., Fan, X., Cai, M., Xu, X., & Zhu, M. (2022) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.2c00300 · Cited by 52
Deep eutectic solvents as entrainers in extractive distillation – A review
Neubauer, M., Wallek, T., & Lux, S. (2022) · Process Safety and Environmental Protection · doi:10.1016/j.cherd.2022.06.019 · Cited by 52
Separation of Thiophene from Aliphatic Hydrocarbons Using Tetrahexylammonium-Based Deep Eutectic Solvents as Extracting Agents
Warrag, S. E. E., Rodriguez, N. R., AlNashef, I. M., Annaland, M. V. S., Siepmann, J. I., Kroon, M. C., & Peters, C. J. (2017) · Journal of Chemical & Engineering Data · doi:10.1021/acs.jced.7b00168 · Cited by 52
Self-citation
The effect of deep eutectic solvent on the pharmacokinetics of salvianolic acid B in rats and its acute toxicity test
Chen, J., Wang, Q., Liu, M., & Zhang, L. (2017) · Journal of Chromatography B · doi:10.1016/j.jchromb.2017.08.016 · Cited by 52
Synergy of high permeability, selectivity and good stability properties of silver-decorated deep eutectic solvent based facilitated transport membranes for efficient ethylene/ethane separation
Dou, H., Jiang, B., Zhang, L., Xu, M., & Sun, Y. (2018) · Journal of Membrane Science · doi:10.1016/j.memsci.2018.09.027 · Cited by 52
Eutectic Mixtures Based on Polyalcohols as Sustainable Solvents: Screening and Characterization
Silva, L. P., Martins, M. A. R., Conceição, J. H. F., Pinho, S. P., & Coutinho, J. A. P. (2020) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.0c05518 · Cited by 52
Machine learning in absorption-based post-combustion carbon capture systems: A state-of-the-art review
Hosseinpour, M., Shojaei, M. J., Salimi, M., & Amidpour, M. (2023) · Fuel · doi:10.1016/j.fuel.2023.129265 · Cited by 51
Novel manganese(II)-based deep eutectic solvents: Synthesis and physical properties analysis
Kow, K.-K., & Sirat, K. (2015) · Chinese Chemical Letters · doi:10.1016/j.cclet.2015.05.049 · Cited by 51
Liquid–liquid equilibrium data for the systems {LTTM+benzene+hexane} and {LTTM+ethyl acetate+hexane} at different temperatures and atmospheric pressure
Gonzalez, A. S. B., Francisco, M., Jimeno, G., Lago, S., & Kroon, M. C. (2013) · Fluid Phase Equilibria · doi:10.1016/j.fluid.2013.09.010 · Cited by 51
Self-citation
Sustainable green pretreatment approach to biomass-to-energy conversion using natural hydro-low-transition-temperature mixtures
Yiin, C. L., Quitain, A. T., Yusup, S. B., Uemura, Y., Sasaki, M., & Kida, T. (2018) · Bioresource Technology · doi:10.1016/j.biortech.2018.04.039 · Cited by 53
Environmentally benign non-fluoro deep eutectic solvent and free-standing rice husk-derived bio-carbon based high-temperature supercapacitors
Sathyamoorthi, S., Phattharasupakun, N., & Sawangphruk, M. (2018) · Electrochimica Acta · doi:10.1016/j.electacta.2018.08.027 · Cited by 51
Deep eutectic solvents for Cu-catalysed ARGET ATRP under an air atmosphere: a sustainable and efficient route to poly(methyl methacrylate) using a recyclable Cu( ii ) metal–organic framework
Quirós-Montes, L., Carriedo, G. A., García‐Álvarez, J., & Soto, A. P. (2019) · Green Chemistry · doi:10.1039/c9gc02624j · Cited by 51
CO2 capture from flue gas using phosphonium based deep eutectic solvents: Modeling and simulation approach
Haider, M. B., Maheshwari, P., & Kumar, R. (2021) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2021.106727 · Cited by 52
Biodegradable betaine-based aprotic task-specific ionic liquids and their application in efficient SO 2 absorption
Yang, B., Zhang, Q., Fei, Y., Zhou, F., Wang, P., & Deng, Y. (2015) · Green Chemistry · doi:10.1039/c5gc00691k · Cited by 52
Synthesis and Properties
Vigier, K. D. O., & Jérôme, F. (2019) · Wiley eBooks · doi:10.1002/9783527818488.ch1 · Cited by 53
Rhodium catalyzed hydroformylation of 1-decene in low melting mixtures based on various cyclodextrins and N,N′-dimethylurea
Ferreira, M., Jérôme, F., Bricout, H., Menuel, S., Landy, D., Fourmentin, S., Tilloy, S., & Monflier, É. (2014) · Catalysis Communications · doi:10.1016/j.catcom.2014.11.001 · Cited by 50
Recent advances in modeling green solvents
Das, S. K., Mondal, A., & Balasubramanian, S. (2017) · Current Opinion in Green and Sustainable Chemistry · doi:10.1016/j.cogsc.2017.03.006 · Cited by 50
SO2absorption/desorption performance of renewable phenol-based deep eutectic solvents
Liu, X., Gao, B., & Deng, D. (2018) · Separation Science and Technology · doi:10.1080/01496395.2018.1446026 · Cited by 50
Whole-Cell Biocatalyst for Chemoenzymatic Total Synthesis of Rivastigmine
Vitale, P., Perna, F. M., Agrimi, G., Pisano, I., Mirizzi, F., Capobianco, R., & Capriati, V. (2018) · Catalysts · doi:10.3390/catal8020055 · Cited by 50
A low transition temperature mixture for the dispersive liquid-liquid microextraction of pesticides from surface waters
Tomai, P., Lippiello, A., D’Angelo, P., Persson, I., Martinelli, A., Lisio, V. D., Curini, R., Fanali, C., & Gentili, A. (2019) · Journal of Chromatography A · doi:10.1016/j.chroma.2019.06.050 · Cited by 50
Computation of gas solubilities in choline chloride urea and choline chloride ethylene glycol deep eutectic solvents using Monte Carlo simulations
Salehi, H. S., Hens, R., Moultos, O. A., & Vlugt, T. J. H. (2020) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2020.113729 · Cited by 52
Deep Eutectic Solvents as Novel and Effective Extraction Media for Quantitative Determination of Ochratoxin A in Wheat and Derived Products
Piemontese, L., Perna, F., Logrieco, A., Capriati, V., & Solfrizzo, M. (2017) · Molecules · doi:10.3390/molecules22010121 · Cited by 49
Towards the development of continuous, organocatalytic, and stereoselective reactions in deep eutectic solvents
Brenna, D., Massolo, E., Puglisi, A., Rossi, S., Celentano, G., Benaglia, M., & Capriati, V. (2016) · Beilstein Journal of Organic Chemistry · doi:10.3762/bjoc.12.258 · Cited by 49
Density and refractive index measurements of transition-temperature mixture (deep eutectic analogues) based on potassium carbonate with dual hydrogen bond donors for CO2 capture
Ghaedi, H., Ayoub, M., Sufian, S. B., Shariff, A. M., Lal, B., & Wilfred, C. D. (2017) · The Journal of Chemical Thermodynamics · doi:10.1016/j.jct.2017.11.008 · Cited by 51
Organolithium‐Initiated Polymerization of Olefins in Deep Eutectic Solvents under Aerobic Conditions
Sánchez‐Condado, A., Carriedo, G. A., Soto, A. P., Rodríguez‐Álvarez, M. J., García‐Álvarez, J., & Hevia, E. (2019) · ChemSusChem · doi:10.1002/cssc.201900533 · Cited by 50

Authors: Francisco, M., van den Bruinhorst, A., & Kroon, M. C.
Affiliations: Eindhoven University of Technology (NL)
Corresponding author: Kroon, Maaike C.
ORCID: Francisco, María
Kroon, Maaike C.
Venue: Angewandte Chemie International Edition
Publisher: Wiley
Published: 2013-02-10
Volume: 52
Issue: 11
Pages: 3074-3085
ISSN: 1433-7851 (ISSN-L)
1521-3773
DOI: 10.1002/anie.201207548
OpenAlex: W2133982938
Cited by: 1,378
References: 71
Citations by year: 2026: 97 · 2025: 101 · 2024: 106 · 2023: 115 · 2022: 123 · 2021: 121 · 2020: 144 · 2019: 140 · 2018: 105 · 2017: 116 · 2016: 74 · 2015: 73 · 2014: 47 · 2013: 15
FWCI: 27.61
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor)
Locations: Angewandte Chemie International Edition (publishedVersion)
PubMed (publishedVersion)
TU/e Research Portal (submittedVersion)
Topics: Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Ionic liquids properties and applications
Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Phase Equilibria and Thermodynamics
Physical Sciences › Engineering › Mechanical Engineering › Lubricants and Their Additives
Keywords: low transition temperature mixtures, deep eutectic solvents, ionic liquids, hydrogen bonding, green solvents, separation processes, biodegradable solvents, renewable solvents

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

Low-transition-temperature mixtures (LTTMs): A new generation of designer solvents

Abstract

Overview

Integrity signals

Verification

Claims the paper makes

Claims other papers make about this one

Citations

Cites

Cited by

Related

Metadata

Record

About these checks