Cited by 1,378Ionic liquids properties and applicationsPhase Equilibria and ThermodynamicsLubricants and Their Additives

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Low-transition-temperature mixtures (LTTMs): A new generation of designer solvents

Francisco, María, van den Bruinhorst, Adriaan, Kroon, Maaike C.·2013·Angewandte Chemie International Edition

DOI 10.1002/anie.201207548

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Abstract

A new generation of designer solvents emerged in the last decade as promising green media for multiple applications, including separation processes: the low‐transition‐temperature mixtures (LTTMs). They can be prepared by mixing natural high‐melting‐point starting materials, which form a liquid by hydrogen‐bond interactions. Among them, deep‐eutectic solvents (DESs) were presented as promising alternatives to conventional ionic liquids (ILs). Some limitations of ILs are overcome by LTTMs, which are cheap and easy to prepare from natural and readily available starting materials, biodegradable, and renewable.

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Authors: Francisco, M., van den Bruinhorst, A., & Kroon, M. C.
Affiliations: Eindhoven University of Technology (NL)
Corresponding author: Kroon, Maaike C.
ORCID: Francisco, María
Kroon, Maaike C.
Venue: Angewandte Chemie International Edition
Publisher: Wiley
Published: 2013-02-10
Volume: 52
Issue: 11
Pages: 3074-3085
ISSN: 1433-7851 (ISSN-L)
1521-3773
DOI: 10.1002/anie.201207548
OpenAlex: W2133982938
Cited by: 1,378
References: 71
Citations by year: 2026: 97 · 2025: 101 · 2024: 106 · 2023: 115 · 2022: 123 · 2021: 121 · 2020: 144 · 2019: 140 · 2018: 105 · 2017: 116 · 2016: 74 · 2015: 73 · 2014: 47 · 2013: 15
FWCI: 27.61
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor)
Locations: Angewandte Chemie International Edition (publishedVersion)
PubMed (publishedVersion)
TU/e Research Portal (submittedVersion)
Topics: Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Ionic liquids properties and applications
Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Phase Equilibria and Thermodynamics
Physical Sciences › Engineering › Mechanical Engineering › Lubricants and Their Additives
Keywords: low transition temperature mixtures, deep eutectic solvents, ionic liquids, hydrogen bonding, green solvents, separation processes, biodegradable solvents, renewable solvents

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Low-transition-temperature mixtures (LTTMs): A new generation of designer solvents

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