Cited by 1,378Ionic liquids properties and applicationsPhase Equilibria and ThermodynamicsLubricants and Their Additives

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Low-transition-temperature mixtures (LTTMs): A new generation of designer solvents

Francisco, María, van den Bruinhorst, Adriaan, Kroon, Maaike C.·2013·Angewandte Chemie International Edition

DOI 10.1002/anie.201207548

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Abstract

A new generation of designer solvents emerged in the last decade as promising green media for multiple applications, including separation processes: the low‐transition‐temperature mixtures (LTTMs). They can be prepared by mixing natural high‐melting‐point starting materials, which form a liquid by hydrogen‐bond interactions. Among them, deep‐eutectic solvents (DESs) were presented as promising alternatives to conventional ionic liquids (ILs). Some limitations of ILs are overcome by LTTMs, which are cheap and easy to prepare from natural and readily available starting materials, biodegradable, and renewable.

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Novel solvent properties of choline chloride/urea mixturesElectronic supplementary information (ESI) available: spectroscopic data. See http://www.rsc.org/suppdata/cc/b2/b210714g/
Abbott, A. P., Capper, G., Davies, D. L., Rasheed, R. K., & Tambyrajah, V. (2003) · Chemical Communications · doi:10.1039/b210714g · Cited by 5,738
Deep eutectic solvents: syntheses, properties and applications
Zhang, Q., De Oliveira Vigier, K., Royer, S., & Jérôme, F. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35178a · Cited by 4,899
Deep eutectic solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids
Abbott, A. P., Boothby, D., Capper, G., Davies, D. L., & Rasheed, R. K. (2004) · Journal of the American Chemical Society · doi:10.1021/ja048266j · Cited by 4,340
ANALYSIS OF RECENT MEASUREMENTS OF THE VISCOSITY OF GLASSES
Fulcher, G. S. (1925) · Journal of the American Ceramic Society · doi:10.1111/j.1151-2916.1925.tb16731.x · Cited by 4,199
Ionic liquids. Green solvents for the future
Earle, M. J., & Seddon, K. R. (2000) · Pure and Applied Chemistry · doi:10.1351/pac200072071391 · Cited by 2,813
Origins, Current Status, and Future Challenges of Green Chemistry
Anastas, P. T., & Kirchhoff, M. M. (2002) · Accounts of Chemical Research · doi:10.1021/ar010065m · Cited by 2,221
What is a green solvent? A comprehensive framework for the environmental assessment of solvents
Capello, C., Fischer, U., & Hungerbühler, K. (2007) · Green Chemistry · doi:10.1039/b617536h · Cited by 1,917
The properties of organic liquids that are relevant to their use as solvating solvents
Marcus, Y. (1993) · Chemical Society Reviews · doi:10.1039/cs9932200409 · Cited by 1,637
Are Natural Deep Eutectic Solvents the Missing Link in Understanding Cellular Metabolism and Physiology?
Choi, Y. H., van Spronsen, J., Dai, Y., Verberne, M., Hollmann, F., Arends, I. W. C. E., Witkamp, G.-J., & Verpoorte, R. (2011) · Plant Physiology · doi:10.1104/pp.111.178426 · Cited by 1,368
Organic chemistry in water
LI, C. ‐., & Chen, L. (2005) · Chemical Society Reviews · doi:10.1039/b507207g · Cited by 1,335

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Savchenko P. S., 1959, Russ. J. Inorg. Chem., 4, 186
R. C. Harris Physical Properties of Alcohol‐Based Deep‐Eutectic Solvents Ph.d. Thesis University of Leicester 2009.
Feynman R. P., 1960, Eng. Sci., 23, 22

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Authors: Francisco, M., van den Bruinhorst, A., & Kroon, M. C.
Affiliations: Eindhoven University of Technology (NL)
Corresponding author: Kroon, Maaike C.
ORCID: Francisco, María
Kroon, Maaike C.
Venue: Angewandte Chemie International Edition
Publisher: Wiley
Published: 2013-02-10
Volume: 52
Issue: 11
Pages: 3074-3085
ISSN: 1433-7851 (ISSN-L)
1521-3773
DOI: 10.1002/anie.201207548
OpenAlex: W2133982938
Cited by: 1,378
References: 71
Citations by year: 2026: 97 · 2025: 101 · 2024: 106 · 2023: 115 · 2022: 123 · 2021: 121 · 2020: 144 · 2019: 140 · 2018: 105 · 2017: 116 · 2016: 74 · 2015: 73 · 2014: 47 · 2013: 15
FWCI: 27.61
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor)
Locations: Angewandte Chemie International Edition (publishedVersion)
PubMed (publishedVersion)
TU/e Research Portal (submittedVersion)
Topics: Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Ionic liquids properties and applications
Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Phase Equilibria and Thermodynamics
Physical Sciences › Engineering › Mechanical Engineering › Lubricants and Their Additives
Keywords: low transition temperature mixtures, deep eutectic solvents, ionic liquids, hydrogen bonding, green solvents, separation processes, biodegradable solvents, renewable solvents

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Low-transition-temperature mixtures (LTTMs): A new generation of designer solvents

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