Cited by 1,378Ionic liquids properties and applicationsPhase Equilibria and ThermodynamicsLubricants and Their Additives

The DOI matches its Crossref record; 71 of the 71 references it cites were found in a registry or an index.

Low-transition-temperature mixtures (LTTMs): A new generation of designer solvents

Francisco, María, van den Bruinhorst, Adriaan, Kroon, Maaike C.·2013·Angewandte Chemie International Edition

DOI 10.1002/anie.201207548

Open this paper in CoChat — free account

Abstract

A new generation of designer solvents emerged in the last decade as promising green media for multiple applications, including separation processes: the low‐transition‐temperature mixtures (LTTMs). They can be prepared by mixing natural high‐melting‐point starting materials, which form a liquid by hydrogen‐bond interactions. Among them, deep‐eutectic solvents (DESs) were presented as promising alternatives to conventional ionic liquids (ILs). Some limitations of ILs are overcome by LTTMs, which are cheap and easy to prepare from natural and readily available starting materials, biodegradable, and renewable.

Integrity signals

Registry

Crossref · 10.1002/anie.201207548

Cites

71 of 71 references verified0 citation errors · 0 not checkable

Statistics

Recomputing p-values needs the paper’s full text.

Claims the paper makes

This paper’s full text isn’t openly available, so its claims and self-check weren’t run. The registry and citation checks still apply.

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

Novel solvent properties of choline chloride/urea mixturesElectronic supplementary information (ESI) available: spectroscopic data. See http://www.rsc.org/suppdata/cc/b2/b210714g/
Abbott, A. P., Capper, G., Davies, D. L., Rasheed, R. K., & Tambyrajah, V. (2003) · Chemical Communications · doi:10.1039/b210714g · Cited by 5,738
Deep eutectic solvents: syntheses, properties and applications
Zhang, Q., De Oliveira Vigier, K., Royer, S., & Jérôme, F. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35178a · Cited by 4,899
Deep eutectic solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids
Abbott, A. P., Boothby, D., Capper, G., Davies, D. L., & Rasheed, R. K. (2004) · Journal of the American Chemical Society · doi:10.1021/ja048266j · Cited by 4,340
ANALYSIS OF RECENT MEASUREMENTS OF THE VISCOSITY OF GLASSES
Fulcher, G. S. (1925) · Journal of the American Ceramic Society · doi:10.1111/j.1151-2916.1925.tb16731.x · Cited by 4,199
Ionic liquids. Green solvents for the future
Earle, M. J., & Seddon, K. R. (2000) · Pure and Applied Chemistry · doi:10.1351/pac200072071391 · Cited by 2,813
Origins, Current Status, and Future Challenges of Green Chemistry
Anastas, P. T., & Kirchhoff, M. M. (2002) · Accounts of Chemical Research · doi:10.1021/ar010065m · Cited by 2,221
What is a green solvent? A comprehensive framework for the environmental assessment of solvents
Capello, C., Fischer, U., & Hungerbühler, K. (2007) · Green Chemistry · doi:10.1039/b617536h · Cited by 1,917
The properties of organic liquids that are relevant to their use as solvating solvents
Marcus, Y. (1993) · Chemical Society Reviews · doi:10.1039/cs9932200409 · Cited by 1,637
Are Natural Deep Eutectic Solvents the Missing Link in Understanding Cellular Metabolism and Physiology?
Choi, Y. H., van Spronsen, J., Dai, Y., Verberne, M., Hollmann, F., Arends, I. W. C. E., Witkamp, G.-J., & Verpoorte, R. (2011) · Plant Physiology · doi:10.1104/pp.111.178426 · Cited by 1,368
Organic chemistry in water
LI, C. ‐., & Chen, L. (2005) · Chemical Society Reviews · doi:10.1039/b507207g · Cited by 1,335

Flagged first, then by citations

Show all 71 references

Research works printed but not linked: 3

Savchenko P. S., 1959, Russ. J. Inorg. Chem., 4, 186
R. C. Harris Physical Properties of Alcohol‐Based Deep‐Eutectic Solvents Ph.d. Thesis University of Leicester 2009.
Feynman R. P., 1960, Eng. Sci., 23, 22

Sorted by citations

Items 201–300 of 1,000

Second generation biorefining in Ecuador: Circular bioeconomy, zero waste technology, environment and sustainable development: The nexus
Orejuela-Escobar, L. M., Landázuri, A. C., & Goodell, B. S. (2021) · Journal of Bioresources and Bioproducts · doi:10.1016/j.jobab.2021.01.004 · Cited by 127
Synthesis strategies of covalent organic frameworks: An overview from nonconventional heating methods and reaction media
Xiao, J., Chen, J., Liu, J., Ihara, H., & Qiu, H. (2022) · Green Energy & Environment · doi:10.1016/j.gee.2022.05.003 · Cited by 128
Reactivity of Polar Organometallic Compounds in Unconventional Reaction Media: Challenges and Opportunities
García‐Álvarez, J., Hevia, E., & Capriati, V. (2015) · European Journal of Organic Chemistry · doi:10.1002/ejoc.201500757 · Cited by 124
Low Transition Temperature Mixtures as Innovative and Sustainable CO 2 Capture Solvents
Zubeir, L. F., Lacroix, M. H. M., & Kroon, M. C. (2014) · The Journal of Physical Chemistry B · doi:10.1021/jp5089004 · Cited by 124
Self-citation
Charge Spreading in Deep Eutectic Solvents
Zahn, S., Kirchner, B., & Mollenhauer, D. (2016) · ChemPhysChem · doi:10.1002/cphc.201600348 · Cited by 125
Deep eutectic solvents for highly efficient separations in oil and gas industries
Warrag, S. E. E., Peters, C. J., & Kroon, M. C. (2017) · Current Opinion in Green and Sustainable Chemistry · doi:10.1016/j.cogsc.2017.03.013 · Cited by 124
Self-citation
Deep Eutectic Solvents for the Valorisation of Lignocellulosic Biomasses towards Fine Chemicals
Scelsi, E., Angelini, A., & Pastore, C. (2021) · Biomass · doi:10.3390/biomass1010003 · Cited by 130
Air-assisted dispersive liquid–liquid microextraction based on a new hydrophobic deep eutectic solvent for the preconcentration of benzophenone-type UV filters from aqueous samples
Ge, D., Zhang, Y., Dai, Y., & Yang, S. (2018) · Journal of Separation Science · doi:10.1002/jssc.201701282 · Cited by 121
In situ PM-IRRAS of a glassy carbon electrode/deep eutectic solvent interface
Vieira, L., Schennach, R., & Gollas, B. R. (2015) · Physical Chemistry Chemical Physics · doi:10.1039/c5cp00070j · Cited by 121
Water opens the door to organolithiums and Grignard reagents: exploring and comparing the reactivity of highly polar organometallic compounds in unconventional reaction media towards the synthesis of tetrahydrofurans
Cicco, L., Sblendorio, S., Mansueto, R., Perna, F. M., Salomone, A., Florio, S., & Capriati, V. (2015) · Chemical Science · doi:10.1039/c5sc03436a · Cited by 124
Designed porous carbon materials for efficient CO2 adsorption and separation
Zhang, X.-Q., Li, W., & Lu, A. (2015) · New Carbon Materials · doi:10.1016/s1872-5805(15)60203-7 · Cited by 123
Bulk and interfacial structures of reline deep eutectic solvent: A molecular dynamics study
Kaur, S., Sharma, S., & Kashyap, H. K. (2017) · The Journal of Chemical Physics · doi:10.1063/1.4996644 · Cited by 121
Separation Performance of BioRenewable Deep Eutectic Solvents
Verevkin, S. P., Sazonova, A. Y., Frolkova, A. K., Zaitsau, D. H., Prikhodko, I. V., & Held, C. (2015) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.5b00357 · Cited by 123
Aliphatic–Aromatic Separation Using Deep Eutectic Solvents as Extracting Agents
Rodriguez, N. R., Requejo, P. F., & Kroon, M. C. (2015) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.5b02611 · Cited by 121
Self-citation
How Do Animals Survive Extreme Temperature Amplitudes? The Role of Natural Deep Eutectic Solvents
Gertrudes, A., Craveiro, R., Eltayari, Z. S. F., Reis, R. L., Paiva, A., & Duarte, A. R. C. (2017) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.7b01707 · Cited by 123
Composition and antioxidant activity of anthocyanins from Aronia melanocarpa extracted using an ultrasonic-microwave-assisted natural deep eutectic solvent extraction method
Lin, S., Meng, X., Tan, C., Tong, Y., Wan, M., Wang, M., Zhao, Y., Deng, H., Kong, Y., & Ma, Y. (2022) · Ultrasonics Sonochemistry · doi:10.1016/j.ultsonch.2022.106102 · Cited by 125
Estimation of Normal Boiling Temperatures, Critical Properties, and Acentric Factors of Deep Eutectic Solvents
Mirza, N. R., Nicholas, N. J., Wu, Y., Kentish, S. E., & Stevens, G. W. (2015) · Journal of Chemical & Engineering Data · doi:10.1021/acs.jced.5b00046 · Cited by 121
Selectivity of deproteinization and demineralization using natural deep eutectic solvents for production of insect chitin (Hermetia illucens)
Zhou, P., Li, J., Yan, T., Wang, X., Huang, J., Kuang, Z., Ye, M., & Pan, M. (2019) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2019.115255 · Cited by 122
Imidazole-based deep eutectic solvents for starch dissolution and plasticization
Zdanowicz, M., Spychaj, T., & Mąka, H. (2015) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2015.12.036 · Cited by 115
The role of pretreatment in the catalytic valorization of cellulose
Liao, Y., de Beeck, B. O., Thielemans, K., Ennaert, T., Snelders, J., Dusselier, M., Courtin, C. M., & Sels, B. F. (2020) · Molecular Catalysis · doi:10.1016/j.mcat.2020.110883 · Cited by 119
Natural Deep Eutectic Solvent as Extraction Media for the Main Phenolic Compounds from Olive Oil Processing Wastes
Bonacci, S., Gioia, M. L. D., Costanzo, P., Maiuolo, L., Tallarico, S., & Nardi, M. (2020) · Antioxidants · doi:10.3390/antiox9060513 · Cited by 117
Stereoselective organocatalysed reactions in deep eutectic solvents: highly tunable and biorenewable reaction media for sustainable organic synthesis
Massolo, E., Palmieri, S., Benaglia, M., Capriati, V., & Perna, F. M. (2015) · Green Chemistry · doi:10.1039/c5gc01855b · Cited by 114
Physicochemical Properties and Investigation of Azole-Based Deep Eutectic Solvents as Efficient and Reversible SO2 Absorbents
Deng, D., Liu, X., & Gao, B. (2017) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.7b02478 · Cited by 114
Choline Chloride-Based DES as Solvents/Catalysts/Chemical Donors in Pharmaceutical Synthesis
Amoroso, R., Hollmann, F., & Maccallini, C. (2021) · Molecules · doi:10.3390/molecules26206286 · Cited by 117
Choline chloride-based deep eutectic solvents for efficient cycloaddition of CO 2 with propylene oxide
Wu, K., Su, T., Hao, D., Liao, W., Zhao, Y., Ren, W., Deng, C., & Lü, H. (2018) · Chemical Communications · doi:10.1039/c8cc04412k · Cited by 112
Transforming nature into the next generation of bio-based flexible devices: New avenues using deep eutectic systems
Mota-Morales, J. D., & Morales‐Narváez, E. (2021) · Matter · doi:10.1016/j.matt.2021.05.009 · Cited by 113
Predicting the Surface Tension of Deep Eutectic Solvents Using Artificial Neural Networks
Lemaoui, T., Boublia, A., Darwish, A. S., Alam, M., Park, S., Jeon, B., BANAT, F. A., Benguerba, Y., & AlNashef, I. M. (2022) · ACS Omega · doi:10.1021/acsomega.2c03458 · Cited by 112
Critical Assessment of the Sustainability of Deep Eutectic Solvents: A Case Study on Six Choline Chloride-Based Mixtures
Nejrotti, S., Antenucci, A., Pontremoli, C., Gontrani, L., Barbero, N., Carbone, M., & Bonomo, M. (2022) · ACS Omega · doi:10.1021/acsomega.2c06140 · Cited by 111
Deep eutectics and analogues as electrolytes in batteries
Pietro, M. E. D., & Mele, A. (2021) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2021.116597 · Cited by 115
Development of deep eutectic solvents for sustainable chemistry
Liu, J., Li, X., & Row, K. H. (2022) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2022.119654 · Cited by 112
Physicochemical and thermal characteristics of choline chloride-based deep eutectic solvents
Sazali, A. L., AlMasoud, N., Amran, S. K., Alomar, T. S., Pa’ee, K. F., El-Bahy, Z. M., Len, K. Y. T., Dailin, D. J., & Chuah, L. F. (2023) · Chemosphere · doi:10.1016/j.chemosphere.2023.139485 · Cited by 117
Understanding the peculiar effect of water on the physicochemical properties of choline chloride based deep eutectic solvents theoretically and experimentally
Kuddushi, M., Nangala, G. S., Rajput, S. M., Ijardar, S. P., & Malek, N. I. (2019) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2019.01.053 · Cited by 112
Evaluation of pretreatment effect on lignin extraction from wheat straw by deep eutectic solvent
Lou, R., & Zhang, X. (2021) · Bioresource Technology · doi:10.1016/j.biortech.2021.126174 · Cited by 110
Selective recovery of rare earth elements from e-waste via ionic liquid extraction: A review
Kaim, V., Rintala, J. A., & He, C. H. (2022) · Separation and Purification Technology · doi:10.1016/j.seppur.2022.122699 · Cited by 114
Fast environment-friendly ball mill-assisted deep eutectic solvent-based extraction of natural products
Wang, M., Wang, J., Zhang, Y., Xia, Q., Bi, W., Yang, X., & Chen, D. D. Y. (2016) · Journal of Chromatography A · doi:10.1016/j.chroma.2016.03.061 · Cited by 108
Ionic liquids and deep eutectics as a transformative platform for the synthesis of nanomaterials
Hammond, O. S., & Mudring, A. (2022) · Chemical Communications · doi:10.1039/d1cc06543b · Cited by 111
Ecofriendly Mechanochemical Extraction of Bioactive Compounds from Plants with Deep Eutectic Solvents
Wang, M., Wang, J., Zhou, Y., Zhang, M., Xia, Q., Bi, W., & Chen, D. D. Y. (2017) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.7b01378 · Cited by 107
Development and challenges of deep eutectic solvents for cathode recycling of end-of-life lithium-ion batteries
Fan, Y., Kong, Y., Jiang, P., Zhang, G., Cong, J., Shi, X., Liu, Y., Zhang, R., Zhang, R., & Huang, Y. (2023) · Chemical Engineering Journal · doi:10.1016/j.cej.2023.142278 · Cited by 110
Choline hydroxide based deep eutectic solvent for dissolving cellulose
Zhong, Y., Wu, J., Kang, H., & Liu, R. (2022) · Green Chemistry · doi:10.1039/d1gc04130d · Cited by 110
Determination of the Total Vapor Pressure of Hydrophobic Deep Eutectic Solvents: Experiments and Perturbed-Chain Statistical Associating Fluid Theory Modeling
Dietz, C. H. J. T., Creemers, J. T., Meuleman, M. A., Held, C., Sadowski, G., van Sint Annaland, M., Gallucci, F., & Kroon, M. C. (2019) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.8b05449 · Cited by 105
Self-citation
Dye‐Sensitized Solar Cells that use an Aqueous Choline Chloride‐Based Deep Eutectic Solvent as Effective Electrolyte Solution
Boldrini, C. L., Manfredi, N., Perna, F. M., Trifiletti, V., Capriati, V., & Abbotto, A. (2016) · Energy Technology · doi:10.1002/ente.201600420 · Cited by 107
Investigation of solubilities of carbon dioxide in five levulinic acid-based deep eutectic solvents and their thermodynamic properties
Deng, D., Jiang, Y., Liu, X., Zhang, Z., & Ai, N. (2016) · The Journal of Chemical Thermodynamics · doi:10.1016/j.jct.2016.08.015 · Cited by 107
Investigation of a deep eutectic solvent formed by levulinic acid with quaternary ammonium salt as an efficient SO 2 absorbent
Deng, D., Han, G., & Jiang, Y. (2015) · New Journal of Chemistry · doi:10.1039/c5nj01629k · Cited by 104
Solvent extraction of lithium ions using benzoyltrifluoroacetone in new solvents
Masmoudi, A., Zante, G., Trébouet, D., Barillon, R., & Boltoeva, M. (2020) · Separation and Purification Technology · doi:10.1016/j.seppur.2020.117653 · Cited by 104
Integration of hydrogen bonding interaction and Schiff-base chemistry toward self-healing, anti-freezing, and conductive elastomer
Lu, C., Wang, C., Wang, J., Yong, Q., & Chu, F. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.130652 · Cited by 104
Density relaxation and particle motion characteristics in a non-ionic deep eutectic solvent (acetamide + urea): Time-resolved fluorescence measurements and all-atom molecular dynamics simulations
Das, A., Das, S., & Biswas, R. (2015) · The Journal of Chemical Physics · doi:10.1063/1.4906119 · Cited by 104
Novel supported liquid membranes based on deep eutectic solvents for olefin-paraffin separation via facilitated transport
Jiang, B., Dou, H., Zhang, L., Wang, B., Sun, Y., Yang, H., Huang, Z., & Bi, H. (2017) · Journal of Membrane Science · doi:10.1016/j.memsci.2017.05.004 · Cited by 104
Novel acidic eutectic mixture as peroxidase mimetics for oxidative desulfurization of model diesel
Sun, L., Zhu, Z., Su, T., Liao, W., Hao, D., Chen, Y., Zhao, Y., Ren, W., Ge, H., & Lü, H. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.117747 · Cited by 103
New ternary deep eutectic solvents for effective wheat straw deconstruction into its high-value utilization under near-neutral conditions
Ci, Y., Yu, F., Zhou, C., Mo, H., Li, Z., Ma, Y., & Zang, L. (2020) · Green Chemistry · doi:10.1039/d0gc03240a · Cited by 103
Deep eutectic solvents as sustainable extraction media for plants and food samples: A review
Kaoui, S., Chebli, B., Zaidouni, S., Basaid, K., & Mir, Y. (2022) · Sustainable Chemistry and Pharmacy · doi:10.1016/j.scp.2022.100937 · Cited by 105
Dispelling some myths about the CO 2 solubility in ionic liquids
Carvalho, P. J., Kurnia, K. A., & Coutinho, J. A. P. (2016) · Physical Chemistry Chemical Physics · doi:10.1039/c6cp01896c · Cited by 105
Deep Eutectic Solvent Aqueous Solutions as Efficient Media for the Solubilization of Hardwood Xylans
Morais, E. S., Mendonça, P. V., Coelho, J. F. J., Freire, M. G., Freire, C. S. R., Coutinho, J. A. P., & Silvestre, A. J. D. (2018) · ChemSusChem · doi:10.1002/cssc.201702007 · Cited by 106
A perspective on bioethanol production from biomass as alternative fuel for spark ignition engine
Sebayang, A. H., Masjuki, H. H., Ong, H. C., Dharma, S. H., Silitonga, A. S., Mahlia, T. M. I., & Aditiya, H. B. (2016) · RSC Advances · doi:10.1039/c5ra24983j · Cited by 102
Thermophysical properties of glycerol and polyethylene glycol (PEG 600) based DES
Singh, A., Walvekar, R., Khalid, M., Wong, W. Y., & Gupta, T. C. S. M. (2017) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2017.10.030 · Cited by 103
Low transition temperature mixtures (LTTMs) as novel entrainers in extractive distillation
Rodriguez, N. R., González, A. S. B., Tijssen, P. M. A., & Kroon, M. C. (2014) · Fluid Phase Equilibria · doi:10.1016/j.fluid.2014.10.044 · Cited by 101
Self-citation
Deep eutectic solvent formation: a structural view using molecular dynamics simulations with classical force fields
Mainberger, S., Kindlein, M., Bezold, F., Elts, E., Minceva, M., & Briesen, H. (2017) · Molecular Physics · doi:10.1080/00268976.2017.1288936 · Cited by 101
Deep eutectic solvents as green absorbents of volatile organic pollutants
Moura, L. M., Moufawad, T., Ferreira, M., Bricout, H., Tilloy, S., Monflier, É., Gomes, M. C., Landy, D., & Fourmentin, S. (2017) · Environmental Chemistry Letters · doi:10.1007/s10311-017-0654-y · Cited by 100
Ternary Deep Eutectic Solvent Behavior of Water and Urea–Choline Chloride Mixtures
Smith, P. J., Arroyo, C. B., Hernandez, F. L., & Goeltz, J. C. (2019) · The Journal of Physical Chemistry B · doi:10.1021/acs.jpcb.8b12322 · Cited by 104
Intensification of biotransformations using deep eutectic solvents: Overview and outlook
Juneidi, I., Hayyan, M., & Hashim, M. A. (2017) · Process Biochemistry · doi:10.1016/j.procbio.2017.12.003 · Cited by 100
Innovative Approaches for Recovery of Phytoconstituents from Medicinal/Aromatic Plants and Biotechnological Production
Fierăscu, R. C., Fierăscu, I., Orțan, A., Georgiev, M. I., & Sieniawska, E. (2020) · Molecules · doi:10.3390/molecules25020309 · Cited by 102
Deep eutectic solvents: A structural point of view on the role of the cation
Migliorati, V., Sessa, F., & D’Angelo, P. (2018) · Chemical Physics Letters · doi:10.1016/j.cpletx.2018.100001 · Cited by 105
Solubilities and Thermodynamic Properties of Carbon Dioxide in Guaiacol-Based Deep Eutectic Solvents
Liu, X., Gao, B., Jiang, Y., Ai, N., & Deng, D. (2017) · Journal of Chemical & Engineering Data · doi:10.1021/acs.jced.6b01013 · Cited by 98
PC-SAFT modeling of CO 2 solubilities in hydrophobic deep eutectic solvents
Dietz, C. H. J. T., van Osch, D. J. G. P., Kroon, M. C., Sadowski, G., van Sint Annaland, M., Gallucci, F., Zubeir, L. F., & Held, C. (2017) · Fluid Phase Equilibria · doi:10.1016/j.fluid.2017.03.028 · Cited by 97
Self-citation
Multiple Hydrogen-Bonding Interactions Enhance the Solubility of Starch in Natural Deep Eutectic Solvents: Molecule and Macroscopic Scale Insights
Cao, C., Nian, B., Li, Y., Wu, S., & Liu, Y. (2019) · Journal of Agricultural and Food Chemistry · doi:10.1021/acs.jafc.9b04503 · Cited by 97
Biomimetic oxygen activation and electron transfer mechanism for oxidative desulfurization
Chi, M., Su, T., Sun, L., Zhu, Z., Liao, W., Ren, W., Zhao, Y., & Lü, H. (2020) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2020.119134 · Cited by 97
A simple and green deep eutectic solvent based air assisted liquid phase microextraction for separation, preconcentration and determination of lead in water and food samples by graphite furnace atomic absorption spectrometry
Zounr, R. A., Tuzen, M., & Khuhawar, M. Y. (2018) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2018.03.034 · Cited by 96
Indirect assessment of the fusion properties of choline chloride from solid-liquid equilibria data
Fernández, L., Silva, L. P., Martins, M. A. R., Ferreira, O., Ortega, J., Pinho, S. P., & Coutinho, J. A. P. (2017) · Fluid Phase Equilibria · doi:10.1016/j.fluid.2017.03.015 · Cited by 99
Characterization of natural low transition temperature mixtures (LTTMs): Green solvents for biomass delignification
Yiin, C. L., Quitain, A. T., Yusup, S. B., Sasaki, M., Uemura, Y., & Kida, T. (2015) · Bioresource Technology · doi:10.1016/j.biortech.2015.07.103 · Cited by 101
Glycerol: a biorenewable solvent for base-free Cu(i)-catalyzed 1,3-dipolar cycloaddition of azides with terminal and 1-iodoalkynes. Highly efficient transformations and catalyst recycling
Vidal, C., & García‐Álvarez, J. (2014) · Green Chemistry · doi:10.1039/c4gc00451e · Cited by 97
Differential Microscopic Mobility of Components within a Deep Eutectic Solvent
Wagle, D. V., Baker, G. A., & Mamontov, E. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b01192 · Cited by 99
Catalytic deep eutectic solvents for highly efficient conversion of cellulose to gluconic acid with gluconic acid self-precipitation separation
Liu, F., Xue, Z., Zhao, X., Mou, H., He, J., & Mu, T. (2018) · Chemical Communications · doi:10.1039/c8cc03798a · Cited by 95
Low-melting mixtures based on choline ionic liquids
Rengstl, D., Fischer, V., & Kunz, W. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c4cp02860k · Cited by 95
Ionic conductivity of deep eutectic solvents: the role of orientational dynamics and glassy freezing
Reuter, D., Binder, C., Lunkenheimer, P., & Loidl, A. (2019) · Physical Chemistry Chemical Physics · doi:10.1039/c9cp00742c · Cited by 99
Aqueous two‐phase systems based on deep eutectic solvents and their application in green separation processes
Zhao, R., Pei, D., Yu, P., Wei, J., Wang, N., Di, D., & Liu, Y. (2019) · Journal of Separation Science · doi:10.1002/jssc.201900991 · Cited by 96
Deep eutectic systems: An overview of fundamental aspects, current understanding and drug delivery applications
Chakraborty, S., Chormale, J. H., & Bansal, A. K. (2021) · International Journal of Pharmaceutics · doi:10.1016/j.ijpharm.2021.121203 · Cited by 101
Unexpectedly efficient SO 2 capture and conversion to sulfur in novel imidazole-based deep eutectic solvents
Zhao, T., Liang, J. P., Zhang, Y., Wu, Y., & Hu, X. (2018) · Chemical Communications · doi:10.1039/c8cc04349c · Cited by 93
Eutectogels: The Multifaceted Soft Ionic Materials of Tomorrow
Mercadal, P. A., González, A., Beloqui, A., Tomé, L. C., Mecerreyes, D., Calderón, M., & Picchio, M. L. (2024) · JACS Au · doi:10.1021/jacsau.4c00677 · Cited by 94
Dynamic Solvent Control of a Reaction in Ionic Deep Eutectic Solvents: Time-Resolved Fluorescence Measurements of Reactive and Nonreactive Dynamics in (Choline Chloride + Urea) Melts
Das, A., & Biswas, R. (2015) · The Journal of Physical Chemistry B · doi:10.1021/acs.jpcb.5b04936 · Cited by 94
Efficient separation of phenolic compounds from model oil by the formation of choline derivative-based deep eutectic solvents
Zhang, Y., Li, Z., Wang, H., Xuan, X., & Wang, J. (2016) · Separation and Purification Technology · doi:10.1016/j.seppur.2016.03.014 · Cited by 95
Natural Deep Eutectic Solvents Based on Choline Chloride and Phenolic Compounds as Efficient Bioadhesives and Corrosion Protectors
Picchio, M. L., Minudri, D., Mantione, D., Criado‐Gonzalez, M., Guzmán‐González, G., Schmarsow, R. N., Müller, A. J., Tomé, L. C., Minari, R. J., & Mecerreyes, D. (2022) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.2c01976 · Cited by 95
Deep eutectic solvents composed of tetrabutylammonium bromide and PEG: Density, speed of sound and viscosity as a function of temperature
Ijardar, S. P. (2019) · The Journal of Chemical Thermodynamics · doi:10.1016/j.jct.2019.105897 · Cited by 95
Revealing the role of hydrogen bonding interactions and supramolecular complexes in lignin dissolution by deep eutectic solvents
Li, Q., Dong, Y., Hammond, K. D., & Wan, C. (2021) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2021.117779 · Cited by 91
Dielectric Relaxations of (Acetamide + Electrolyte) Deep Eutectic Solvents in the Frequency Window, 0.2 ≤ ν/GHz ≤ 50: Anion and Cation Dependence
Mukherjee, K., Das, A., Choudhury, S., Barman, A., & Biswas, R. (2015) · The Journal of Physical Chemistry B · doi:10.1021/acs.jpcb.5b01502 · Cited by 91
Establishment of an Aqueous PEG 200-Based Deep Eutectic Solvent Extraction and Enrichment Method for Pumpkin (Cucurbita moschata) Seed Protein
Liu, R., Yu, P., Ge, X.-L., Xiu-feng, B., Li, X.-Q., & Fu, Q. (2016) · Food Analytical Methods · doi:10.1007/s12161-016-0732-y · Cited by 91
SO 2 absorption in EmimCl–TEG deep eutectic solvents
Yang, D., Zhang, S., Jiang, D., & Dai, S. (2018) · Physical Chemistry Chemical Physics · doi:10.1039/c8cp02250j · Cited by 90
Regioselective desymmetrization of diaryltetrahydrofurans via directed ortho-lithiation: an unexpected help from green chemistry
Mallardo, V., Rizzi, R., Sassone, F. C., Mansueto, R., Perna, F. M., Salomone, A., & Capriati, V. (2014) · Chemical Communications · doi:10.1039/c4cc03149k · Cited by 91
Surfactant–Solvent Interaction Effects on the Micellization of Cationic Surfactants in a Carboxylic Acid-Based Deep Eutectic Solvent
Sanchez-Fernandez, A., Hammond, O. S., Jackson, A., Arnold, T., Doutch, J., & Edler, K. J. (2017) · Langmuir · doi:10.1021/acs.langmuir.7b03254 · Cited by 90
NaDES Application in Cosmetic and Pharmaceutical Fields: An Overview
Villa, C., Caviglia, D., della Cuna, F. S. R., Zuccari, G., & Russo, E. (2024) · Gels · doi:10.3390/gels10020107 · Cited by 93
Ternary and binary deep eutectic solvents as a novel extraction medium for protein partitioning
Zhang, H., Wang, Y., Xu, K., Li, N., Wen, Q., Yang, Q., & Zhou, Y. (2016) · Analytical Methods · doi:10.1039/c6ay01860b · Cited by 91
Hydrophobic deep eutectic solvents in the food sector: Focus on their use for the extraction of bioactive compounds
Sportiello, L., Favati, F., Condelli, N., Di Cairano, M., Caruso, M. C., Simonato, B., Tolve, R., & Galgano, F. (2023) · Food Chemistry · doi:10.1016/j.foodchem.2022.134703 · Cited by 87
Unveiling the Hidden Performance of Whole Cells in the Asymmetric Bioreduction of Aryl‐containing Ketones in Aqueous Deep Eutectic Solvents
Vitale, P., Abbinante, V. M., Perna, F. M., Salomone, A., Cardellicchio, C., & Capriati, V. (2016) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.201601064 · Cited by 87
Nanostructure of the deep eutectic solvent/platinum electrode interface as a function of potential and water content
Hammond, O. S., Li, H., Westermann, C., Al-Murshedi, A. Y. M., Endres, F., Abbott, A. P., Warr, G. G., Edler, K. J., & Atkin, R. (2018) · Nanoscale Horizons · doi:10.1039/c8nh00272j · Cited by 88
Tailor-made solvents for pharmaceutical use? Experimental and computational approach for determining solubility in deep eutectic solvents (DES)
Palmelund, H., Andersson, M., Asgreen, C. J., Boyd, B. J., Rantanen, J., & Löbmann, K. (2019) · International Journal of Pharmaceutics X · doi:10.1016/j.ijpx.2019.100034 · Cited by 92
Natural acidic deep eutectic solvent to obtain cellulose nanocrystals using the design of experience approach
Douard, L., Bras, J., Encinas, T., & Belgacem, M. N. (2020) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2020.117136 · Cited by 89
An overview about the extraction of heavy metals and other critical pollutants from contaminated water via hydrophobic deep eutectic solvents
Wazeer, I., Hizaddin, H. F., Hashim, M. A., & Hadj-Kali, M. K. (2022) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2022.108574 · Cited by 88
Aqueous Two-Phase Systems Based on Ionic Liquids and Deep Eutectic Solvents as a Tool for the Recovery of Non-Protein Bioactive Compounds—A Review
Buarque, F. S., Gautério, G. V., Coelho, M. A. Z., Lemes, A. C., & Ribeiro, B. D. (2022) · Processes · doi:10.3390/pr11010031 · Cited by 88
Sample preparation procedure using extraction and derivatization of carboxylic acids from aqueous samples by means of deep eutectic solvents for gas chromatographic-mass spectrometric analysis
Makoś‐Chełstowska, P., Fernandes, A., Przyjazny, A., & Boczkaj, G. (2018) · Journal of Chromatography A · doi:10.1016/j.chroma.2018.04.054 · Cited by 87
Hydrophobic eutectic mixtures as volatile fatty acid extractants
van den Bruinhorst, A., Raes, S. M. T., Maesara, S. A., Kroon, M. C., Esteves, A. C. C., & Meuldijk, J. (2019) · Separation and Purification Technology · doi:10.1016/j.seppur.2018.12.087 · Cited by 87
Self-citation
The impact of charges in force field parameterization for molecular dynamics simulations of deep eutectic solvents
García, G., Atilhan, M., & Aparício, S. (2015) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2015.07.070 · Cited by 88
Aqueous biphasic systems containing PEG-based deep eutectic solvents for high-performance partitioning of RNA
Zhang, H., Wang, Y., Zhou, Y., Xu, K., Li, N., Wen, Q., & Yang, Q. (2017) · Talanta · doi:10.1016/j.talanta.2017.04.018 · Cited by 87

Authors: Francisco, M., van den Bruinhorst, A., & Kroon, M. C.
Affiliations: Eindhoven University of Technology (NL)
Corresponding author: Kroon, Maaike C.
ORCID: Francisco, María
Kroon, Maaike C.
Venue: Angewandte Chemie International Edition
Publisher: Wiley
Published: 2013-02-10
Volume: 52
Issue: 11
Pages: 3074-3085
ISSN: 1433-7851 (ISSN-L)
1521-3773
DOI: 10.1002/anie.201207548
OpenAlex: W2133982938
Cited by: 1,378
References: 71
Citations by year: 2026: 97 · 2025: 101 · 2024: 106 · 2023: 115 · 2022: 123 · 2021: 121 · 2020: 144 · 2019: 140 · 2018: 105 · 2017: 116 · 2016: 74 · 2015: 73 · 2014: 47 · 2013: 15
FWCI: 27.61
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor)
Locations: Angewandte Chemie International Edition (publishedVersion)
PubMed (publishedVersion)
TU/e Research Portal (submittedVersion)
Topics: Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Ionic liquids properties and applications
Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Phase Equilibria and Thermodynamics
Physical Sciences › Engineering › Mechanical Engineering › Lubricants and Their Additives
Keywords: low transition temperature mixtures, deep eutectic solvents, ionic liquids, hydrogen bonding, green solvents, separation processes, biodegradable solvents, renewable solvents

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

Low-transition-temperature mixtures (LTTMs): A new generation of designer solvents

Abstract

Overview

Integrity signals

Verification

Claims the paper makes

Claims other papers make about this one

Citations

Cites

Cited by

Related

Metadata

Record

About these checks