Stereocomplexed Poly(Limonene Carbonate): A Unique Example of the Cocrystallization of Amorphous Enantiomeric Polymers
Abstract
We report the cocrystallization of the regio‐ and stereoregular chiral copolymer poly(limonene carbonate). To the best of our knowledge, this marks the first example of an amorphous, enantiomerically pure polymer that becomes crystalline upon stereocomplexation with its complementary enantiomer. By analyzing X‐ray powder diffraction data, we propose a packing model in which sheets of enantiopure chains interdigitate with layers of the opposite enantiomer, forming a “steric zipper”.
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Some epoxides and anhydrides can be prepared from biomass such as limonene oxide (from terpene) and maleic anhydride (from furfuraldehyde), which are attractive monomers for fully renewable aliphatic polyesters and polycarbonates.
“Some epoxides and anhydrides can be prepared from biomass (Figure 7) such as limonene oxide (from terpene) 365,366 and maleic anhydride (from furfuraldehyde) 138 , which are attractive monomers for fully renewable aliphatic polyesters and polycarbonates.”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [366]
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- Authors
- Auriemma, F., De Rosa, C., Di Caprio, M. R., Di Girolamo, R., Ellis, W. C., & Coates, G. W.
- Affiliations
- Cornell University (US)
- Corresponding author
- Auriemma, Finizia
- Coates, Geoffrey W.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2014-11-24
- Volume
- 54
- Issue
- 4
- Pages
- 1215-1218
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2114863424
- Cited by
- 164
- References
- 33
- Citations by year
- 2026: 3 · 2025: 7 · 2024: 12 · 2023: 17 · 2022: 14 · 2021: 13 · 2020: 17 · 2019: 12 · 2018: 18 · 2017: 17 · 2016: 20 · 2015: 14
- FWCI
- 11.87
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Biomaterials › Calcium Carbonate Crystallization and Inhibition
- Keywords
- stereocomplexation, co-crystallization, polymer crystallization, steric zipper
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