Cited by 164Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesCalcium Carbonate Crystallization and Inhibition

Stereocomplexed Poly(Limonene Carbonate): A Unique Example of the Cocrystallization of Amorphous Enantiomeric Polymers

Auriemma, Finizia, De Rosa, Claudio, Di Caprio, Maria Rosaria, Di Girolamo, Rocco, Ellis, W. Chadwick, Coates, Geoffrey W.·2015·Angewandte Chemie International Edition

Abstract

We report the cocrystallization of the regio‐ and stereoregular chiral copolymer poly(limonene carbonate). To the best of our knowledge, this marks the first example of an amorphous, enantiomerically pure polymer that becomes crystalline upon stereocomplexation with its complementary enantiomer. By analyzing X‐ray powder diffraction data, we propose a packing model in which sheets of enantiopure chains interdigitate with layers of the opposite enantiomer, forming a “steric zipper”.

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Crossref · 10.1002/anie.201410211

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  • Some epoxides and anhydrides can be prepared from biomass such as limonene oxide (from terpene) and maleic anhydride (from furfuraldehyde), which are attractive monomers for fully renewable aliphatic polyesters and polycarbonates.

    “Some epoxides and anhydrides can be prepared from biomass (Figure 7) such as limonene oxide (from terpene) 365,366 and maleic anhydride (from furfuraldehyde) 138 , which are attractive monomers for fully renewable aliphatic polyesters and polycarbonates.”

    From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [366]

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Authors
Auriemma, F., De Rosa, C., Di Caprio, M. R., Di Girolamo, R., Ellis, W. C., & Coates, G. W.
Affiliations
Cornell University (US)
Corresponding author
  • Auriemma, Finizia
  • Coates, Geoffrey W.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2014-11-24
Volume
54
Issue
4
Pages
1215-1218
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2114863424
Cited by
164
References
33
Citations by year
2026: 3 · 2025: 7 · 2024: 12 · 2023: 17 · 2022: 14 · 2021: 13 · 2020: 17 · 2019: 12 · 2018: 18 · 2017: 17 · 2016: 20 · 2015: 14
FWCI
11.87
Type
journal article
Language
en
Open access
closed
Locations
  • Angewandte Chemie International Edition (publishedVersion)
  • PubMed (publishedVersion)
Topics
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
  • Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
  • Physical Sciences › Materials Science › Biomaterials › Calcium Carbonate Crystallization and Inhibition
Keywords
stereocomplexation, co-crystallization, polymer crystallization, steric zipper

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