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Electrocatalytic Production of C3‐C4 Compounds by Conversion of CO 2 on a Chloride‐Induced Bi‐Phasic Cu 2 O‐Cu Catalyst
Abstract
Electrocatalytic conversion of carbon dioxide (CO 2 ) has recently received considerable attention as one of the most feasible CO 2 utilization techniques. In particular, copper and copper‐derived catalysts have exhibited the ability to produce a number of organic molecules from CO 2 . Herein, we report a chloride (Cl)‐induced bi‐phasic cuprous oxide (Cu 2 O) and metallic copper (Cu) electrode (Cu 2 O Cl ) as an efficient catalyst for the formation of high‐carbon organic molecules by CO 2 conversion, and identify the origin of electroselectivity toward the formation of high‐carbon organic compounds. The Cu 2 O Cl electrocatalyst results in the preferential formation of multi‐carbon fuels, including n ‐propanol and n ‐butane C3–C4 compounds. We propose that the remarkable electrocatalytic conversion behavior is due to the favorable affinity between the reaction intermediates and the catalytic surface.
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“In addition, Xu et al. found that the incorporation of Au not only stabilizes Cu nanoparticles, but also lowers the overpotential for CO2RR.[115]”
From Electrochemical CO 2 Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [115]
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Self-citationTuning Atomically Precise Gold Nanoclusters for Selective Electroreduction of CO 2
Zhao, J., Ziarati, A., & Bürgi, T. (2025) · Angewandte Chemie · doi:10.1002/ange.202504320 · Cited by 2
Understanding the Electrochemical Reduction of Carbon Dioxide at Copper Surfaces
Ren, D., Gao, J., & Grätzel, M. (2019) · ACS symposium series · doi:10.1021/bk-2019-1331.ch009 · Cited by 2
Liu, B., Ran, C., Hao, F., & Ren, D. (2025) · ChemSusChem · doi:10.1002/cssc.202501370 · Cited by 1
Interfacial polarization enables dual pathways for electrosynthesis of propyl acetate
Liu, X., Jiang, Y., Chen, W., Wu, J., He, Y., Huang, Y., Lu, Y., Zhou, Y., & Wang, S. (2025) · Chemical Science · doi:10.1039/d5sc08178e · Cited by 1
Electrocatalytic Production of Methanol from Carbon Dioxide
Ruiz, E., & Sánchez, J. M. (2020) · Environmental chemistry for a sustainable world · doi:10.1007/978-3-030-28622-4_7 · Cited by 1
Metadata
- Authors
- Lee, S., Kim, D., & Lee, J.
- Affiliations
- Gwangju Institute of Science and Technology (KR)
- Corresponding author
- Lee, Jaeyoung
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2015-10-16
- Volume
- 54
- Issue
- 49
- Pages
- 14701-14705
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2144904466
- Cited by
- 320
- References
- 40
- Citations by year
- 2026: 14 · 2025: 32 · 2024: 23 · 2023: 29 · 2022: 31 · 2021: 51 · 2020: 40 · 2019: 37 · 2018: 31 · 2017: 21 · 2016: 11
- FWCI
- 6.22
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Ministry of Education (NRF2013R1A1A2A10063010)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Keywords
- copper oxide, cuprous oxide, 1-propanol, butane, reaction intermediates, copper catalysts
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