The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Boosting Photocatalytic Hydrogen Production of a Metal–Organic Framework Decorated with Platinum Nanoparticles: The Platinum Location Matters
Abstract
Improving the efficiency of electron–hole separation and charge‐carrier utilization plays a central role in photocatalysis. Herein, Pt nanoparticles of ca. 3 nm are incorporated inside or supported on a representative metal–organic framework (MOF), UiO‐66‐NH 2, denoted as Pt@UiO‐66‐NH 2 and Pt/UiO‐66‐NH 2, respectively, for photocatalytic hydrogen production via water splitting. Compared with the pristine MOF, both Pt‐decorated MOF nanocomposites exhibit significantly improved yet distinctly different hydrogen‐production activities, highlighting that the photocatalytic efficiency strongly correlates with the Pt location relative to the MOF. The Pt@UiO‐66‐NH 2 greatly shortens the electron‐transport distance, which favors the electron–hole separation and thereby yields much higher efficiency than Pt/UiO‐66‐NH 2. The involved mechanism has been further unveiled by means of ultrafast transient absorption and photoluminescence spectroscopy.
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Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Roles of Cocatalysts in Photocatalysis and Photoelectrocatalysis
Yang, J., Wang, D., Han, H., & Li, C. (2013) · Accounts of Chemical Research · doi:10.1021/ar300227e · Cited by 2,848
Xiang, Q., Yu, J., & Jaroniec, M. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302846n · Cited by 2,360
Xu, H.-Q., Hu, J., Wang, D., Li, Z., Zhang, Q., Luo, Y., Yu, S.-H., & Jiang, H.-L. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08773 · Cited by 1,166
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Cited by
Encapsulated Metal Nanoparticles for Catalysis
Gao, C., Lyu, F., & Yin, Y. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00237 · Cited by 855
Single Pt Atoms Confined into a Metal–Organic Framework for Efficient Photocatalysis
Fang, X., Shang, Q., Wang, Y., Jiao, L., Yao, T., Li, Y., Zhang, Q., Luo, Y., & Jiang, H. (2018) · Advanced Materials · doi:10.1002/adma.201705112 · Cited by 837
Self-citationZhao, S.-N., Song, X.-Z., Song, S.-Y., & Zhang, H.-J. (2017) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.02.010 · Cited by 336
Multifunctional metal–organic framework heterostructures for enhanced cancer therapy
Liu, J., Huang, J., Zhang, L., & Lei, J. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00178c · Cited by 285
Xu, M., Li, D., Sun, K., Jiao, L., Xie, C., Ding, C., & Jiang, H. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202104219 · Cited by 280
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Metadata
- Authors
- Xiao, J., Shang, Q., Xiong, Y., Zhang, Q., Luo, Y., Yu, S., & Jiang, H.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-06-20
- Volume
- 55
- Issue
- 32
- Pages
- 9389-9393
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2468809886
- Cited by
- 705
- References
- 4
- FWCI
- 17.25
- Type
- journal article
- Language
- en
- Open access
- closed
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