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Potential‐Cycling Synthesis of Single Platinum Atoms for Efficient Hydrogen Evolution in Neutral Media
Open accessAbstract
Single‐atom catalysts (SACs) have exhibited high activities for the hydrogen evolution reaction (HER) electrocatalysis in acidic or alkaline media, when they are used with binders on cathodes. However, to date, no SACs have been reported for the HER electrocatalysis in neutral media. We demonstrate a potential‐cycling method to synthesize a catalyst comprising single Pt atoms on CoP‐based nanotube arrays supported by a Ni foam, termed PtSA‐NT‐NF. This binder‐free catalyst is centimeter‐scale and scalable. It is directly used as HER cathodes, whose performances at low and high current densities in phosphate buffer solutions (pH 7.2) are comparable to and better than, respectively, those of commercial Pt/C. The Pt mass activity of PtSA‐NT‐NF is 4 times of that of Pt/C, and its electrocatalytic stability is also better than that of Pt/C. This work provides a large‐scale production strategy for binder‐free Pt SAC electrodes for efficient HER in neutral media.
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“As previously reported, these results indicate that Pt single atoms and Pt clusters coexist on the surface of the Pt@MC-VA electrode [13,33].”
From Vertically aligned Pt/MXene/carbon nanotubes aerogels for superior hydrogen evolution reaction (2024) · cites this paper as [13]
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“due to its much higher noble metal content (20 wt%) [13].”
From Vertically aligned Pt/MXene/carbon nanotubes aerogels for superior hydrogen evolution reaction (2024) · cites this paper as [13]
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Metadata
- Authors
- Zhang, L., Han, L., Liu, H., Liu, X., & Luo, J.
- Affiliations
- Tianjin University of Technology (CN)
- Corresponding author
- Liu, Xijun
- Luo, Jun
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2017-08-23
- Volume
- 56
- Issue
- 44
- Pages
- 13694-13698
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- PMC
- PMC5659130
- OpenAlex
- W2742693693
- Cited by
- 532
- References
- 54
- Citations by year
- 2026: 22 · 2025: 32 · 2024: 45 · 2023: 53 · 2022: 78 · 2021: 96 · 2020: 92 · 2019: 68 · 2018: 41 · 2017: 5
- FWCI
- 15.09
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- Locations
- Angewandte Chemie International Edition (publishedVersion, cc-by-nc)
- PubMed Central (publishedVersion, cc-by-nc)
- PubMed (publishedVersion)
- Funders
- National Natural Science Foundation of China (21601136, 51572016)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
- Keywords
- single-atom catalysts, platinum single atoms, hydrogen evolution reaction, media neutrality, binder-free electrocatalyst, nickel foam, phosphate buffer, electrocatalytic stability
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