The DOI matches its Crossref record; 9 of the 9 references it cites were found in a registry or an index.
Dynamic Changes in the Structure, Chemical State and Catalytic Selectivity of Cu Nanocubes during CO2 Electroreduction: Size and Support Effects
Open accessAbstract
In situ and operando spectroscopic and microscopic methods were used to gain insight into the correlation between the structure, chemical state, and reactivity of size‐ and shape‐controlled ligand‐free Cu nanocubes during CO 2 electroreduction (CO 2 RR). Dynamic changes in the morphology and composition of Cu cubes supported on carbon were monitored under potential control through electrochemical atomic force microscopy, X‐ray absorption fine‐structure spectroscopy and X‐ray photoelectron spectroscopy. Under reaction conditions, the roughening of the nanocube surface, disappearance of the (100) facets, formation of pores, loss of Cu and reduction of CuOx species observed were found to lead to a suppression of the selectivity for multi‐carbon products (i.e. C 2 H 4 and ethanol) versus CH 4. A comparison with Cu cubes supported on Cu foils revealed an enhanced morphological stability and persistence of Cu I species under CO 2 RR in the former samples. Both factors are held responsible for the higher C 2/C 1 product ratio observed for the Cu cubes/Cu as compared to Cu cubes/C. Our findings highlight the importance of the structure of the active nanocatalyst but also its interaction with the underlying substrate in CO 2 RR selectivity.
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Highly selective plasma-activated copper catalysts for carbon dioxide reduction to ethylene
Mistry, H., Varela, A. S., Bonifacio, C. S., Zegkinoglou, I., Sinev, I., Choi, Y.-W., Kisslinger, K., Stach, E. A., Yang, J. C., Strasser, P., et al. (2016) · Nature Communications · doi:10.1038/ncomms12123 · Cited by 1,214
Self-citationDe Luna, P., Quintero-Bermudez, R., Dinh, C.-T., Ross, M. B., Bushuyev, O. S., Todorović, P., Regier, T., Kelley, S. O., Yang, P., & Sargent, E. H. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0018-9 · Cited by 1,046
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Subsurface Oxygen in Oxide-Derived Copper Electrocatalysts for Carbon Dioxide Reduction
Eilert, A., Cavalca, F., Roberts, F. S., Osterwalder, J., Liu, C., Favaro, M., Crumlin, E. J., Ogasawara, H., Friebel, D., Pettersson, L. G. M., et al. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b02273 · Cited by 443
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Cited by
Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte
Nitopi, S., Bertheussen, E., Scott, S. B., Liu, X., Engstfeld, A. K., Horch, S., Seger, B., Stephens, I. E. L., Chan, K., Hahn, C., et al. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00705 · Cited by 5,223
Designing materials for electrochemical carbon dioxide recycling
Ross, M. B., De Luna, P., Li, Y., Dinh, C.-T., Kim, D., Yang, P., & Sargent, E. H. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0306-7 · Cited by 1,302
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Huang, J., Mensi, M., Oveisi, E., Mantella, V., & Buonsanti, R. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.8b12381 · Cited by 594
Structure- and Electrolyte-Sensitivity in CO2 Electroreduction
Arán-Ais, R. M., Gao, D., & Roldan Cuenya, B. (2018) · Accounts of Chemical Research · doi:10.1021/acs.accounts.8b00360 · Cited by 341
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Metadata
- Authors
- Grosse, P., Gao, D., Scholten, F., Sinev, I., Mistry, H., & Roldan Cuenya, B.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2018-04-26
- Volume
- 57
- Issue
- 21
- Pages
- 6192-6197
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2793543406
- Cited by
- 425
- References
- 9
- FWCI
- 10.41
- Type
- journal article
- Language
- en
- Open access
- green
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- Grosse, P., Gao, D., Scholten, F., Sinev, I., Mistry, H., & Roldan Cuenya, B. (2018). Dynamic Changes in the Structure, Chemical State and Catalytic Selectivity of Cu Nanocubes during CO2 Electroreduction: Size and Support Effects. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201802083
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