The DOI matches its Crossref record; 48 of the 48 references it cites were found in a registry or an index.
Highly Efficient Electroreduction of CO2 to Methanol on Palladium–Copper Bimetallic Aerogels
Abstract
Electrochemical reduction of CO 2 to CH 3 OH is of great interest. Aerogels have fine inorganic superstructure with high porosity and are known to be exceptional materials. Now a Pd-Cu bimetallic aerogel electrocatalyst has been developed for conversion of CO 2 into CH 3 OH. The current density and Faradaic efficiency of CH 3 OH can be as high as 31.8 mA cm -2 and 80.0 % over the Pd 83 Cu 17 aerogel at a very low overpotential (0.24 V). The superior performance of the electrocatalyst results from efficient adsorption and stabilization of the CO 2 radical anion, high Pd 0 /Pd II and Cu I +Cu 0 /Cu II ratios, and sufficient Pd/Cu grain boundaries of aerogel nanochains.
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“Increasing temperature to promote the synthesis of aerogels has been reported, but the time required for the synthesis is not satisfactory, and the reaction time of several hours does not highlight the superiority of this method.31,42−44”
From Ultrafast Generation of Nanostructured Noble Metal Aerogels by a Microwave Method for Electrocatalytic Hydrogen Evolution and Ethanol Oxidation (2021) · cites this paper as [31]
In the citing paper
“it usually requires a longer cycle to settle the gel (up to several days at room temperature).”
From Ultrafast Generation of Nanostructured Noble Metal Aerogels by a Microwave Method for Electrocatalytic Hydrogen Evolution and Ethanol Oxidation (2021) · cites this paper as [31]
Citations
Cites
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21234j · Cited by 3,160
Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel
Gao, S., Lin, Y., Jiao, X., Sun, Y., Luo, Q., Zhang, W., Li, D., Yang, J., & Xie, Y. (2016) · Nature · doi:10.1038/nature16455 · Cited by 1,865
A review of the aqueous electrochemical reduction of CO2 to hydrocarbons at copper
Gattrell, M., Gupta, N., & Co, A. C. (2006) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2006.05.013 · Cited by 1,482
Highly selective plasma-activated copper catalysts for carbon dioxide reduction to ethylene
Mistry, H., Varela, A. S., Bonifacio, C. S., Zegkinoglou, I., Sinev, I., Choi, Y.-W., Kisslinger, K., Stach, E. A., Yang, J. C., Strasser, P., et al. (2016) · Nature Communications · doi:10.1038/ncomms12123 · Cited by 1,214
Size-Dependent Electrocatalytic Reduction of CO 2 over Pd Nanoparticles
Gao, D., Zhou, H., Wang, J., Miao, S., Yang, F., Wang, G., Wang, J., & Bao, X. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b00046 · Cited by 1,107
He, M., Sun, Y., & Han, B. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201209384 · Cited by 942
Self-citationTailoring Copper Nanocrystals towards C2 Products in Electrochemical CO2 Reduction
Loiudice, A., Lobaccaro, P., Kamali, E. A., Thao, T., Huang, B. H., Ager, J. W., & Buonsanti, R. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201601582 · Cited by 913
Ma, S., Sadakiyo, M., Heima, M., Luo, R., Haasch, R. T., Gold, J. I., Yamauchi, M., & Kenis, P. J. A. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b10740 · Cited by 865
Shape-Dependent Electrocatalytic Reduction of CO2 to CO on Triangular Silver Nanoplates
Liu, S., Tao, H., Zeng, L., Liu, Q., Xu, Z., Liu, Q., & Luo, J. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b12103 · Cited by 703
Li, F., Chen, L., Knowles, G. P., MacFarlane, D. R., & Zhang, J. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201608279 · Cited by 637
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Tuning the configuration of Ag–Cu aerogels for electrocatalytic applications
Zhang, D., Chen, J., Duan, J., Yang, Z., Leng, D., Zhou, Q., Shen, J., Song, M., & Zhou, K. (2025) · Nanoscale · doi:10.1039/d5nr02475g
Ning, H., Bai, P., Wang, H., Pang, X., Lv, Y.-P., Chen, X.-H., Liang, S., Wang, X., Wang, M.-H., & Wu, M.-B. (2026) · Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.5c08790
Chen, J., Zhang, Y., Zhang, L., Zhang, S., & Song, W. (2026) · Microchimica Acta · doi:10.1007/s00604-026-08020-8
Song, M.-Y., Li, Y., Lin, C., Tao, X.-Q., & Lu, T. (2026) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2026.127021
Adegoke, K. A., & Tseki, P. F. (2026) · Sustainable Energy & Fuels · doi:10.1039/d5se01689d
Cheng, M.-Y., Luo, S.-S., Ruan, Y., Li, J., Wang, C., & Li, B. (2026) · SSRN Electronic Journal · doi:10.2139/ssrn.7434927
Zhao, Z., & Ren, D. (2026) · Inorganic Chemistry Frontiers · doi:10.1039/d6qi02209j
Zheng, X., Prasad, K., Riley, E., Tao, F., Lata, N. P., Zangeneh, D., Wang, X., Piao, E., Winstead, D., Misal, S. N., et al. (2026) · ACS Applied Energy Materials · doi:10.1021/acsaem.6c02202
Sano, Y., Moteki, H., Tanaka, M., Toyoda, R., Tateishi, T., Takaishi, S., Iwase, K., Nishina, Y., & Sakamoto, R. (2026) · Journal of Materials Chemistry A · doi:10.1039/d6ta05221e
Direct electroreduction of CO 2 from simulated flue gas using ionic liquid electrolyte
Yuan, L., Feng, X., Peng, K., Sun, M., Fan, T., Wu, Y., Zeng, S., Zhang, X., & Wang, J. (2026) · AIChE Journal · doi:10.1002/aic.70718
Metadata
- Authors
- Lu, L., Sun, X., Ma, J., Yang, D., Wu, H., Zhang, B., Zhang, J., & Han, B.
- Affiliations
- Chinese Academy of Sciences (CN)
- East China Normal University (CN)
- Corresponding author
- Sun, Xiaofu
- Han, Buxing
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2018-10-02
- Volume
- 57
- Issue
- 43
- Pages
- 14149-14153
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2889349896
- Cited by
- 310
- References
- 48
- Citations by year
- 2026: 16 · 2025: 34 · 2024: 46 · 2023: 34 · 2022: 51 · 2021: 52 · 2020: 48 · 2019: 28 · 2018: 1
- FWCI
- 7.45
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- Funders
- National Science Foundation
- National Natural Science Foundation of China
- National Key Research and Development Program of China
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Keywords
- electrochemical CO2 reduction, methanol synthesis, palladium-copper bimetallic catalyst, Faradaic efficiency, grain boundaries
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