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Highly Efficient Electroreduction of CO2 to Methanol on Palladium–Copper Bimetallic Aerogels
Abstract
Electrochemical reduction of CO 2 to CH 3 OH is of great interest. Aerogels have fine inorganic superstructure with high porosity and are known to be exceptional materials. Now a Pd-Cu bimetallic aerogel electrocatalyst has been developed for conversion of CO 2 into CH 3 OH. The current density and Faradaic efficiency of CH 3 OH can be as high as 31.8 mA cm -2 and 80.0 % over the Pd 83 Cu 17 aerogel at a very low overpotential (0.24 V). The superior performance of the electrocatalyst results from efficient adsorption and stabilization of the CO 2 radical anion, high Pd 0 /Pd II and Cu I +Cu 0 /Cu II ratios, and sufficient Pd/Cu grain boundaries of aerogel nanochains.
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“Increasing temperature to promote the synthesis of aerogels has been reported, but the time required for the synthesis is not satisfactory, and the reaction time of several hours does not highlight the superiority of this method.31,42−44”
From Ultrafast Generation of Nanostructured Noble Metal Aerogels by a Microwave Method for Electrocatalytic Hydrogen Evolution and Ethanol Oxidation (2021) · cites this paper as [31]
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“it usually requires a longer cycle to settle the gel (up to several days at room temperature).”
From Ultrafast Generation of Nanostructured Noble Metal Aerogels by a Microwave Method for Electrocatalytic Hydrogen Evolution and Ethanol Oxidation (2021) · cites this paper as [31]
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Stalinraja, A., & Gopalram, K. (2023) · Elsevier eBooks · doi:10.1016/b978-0-323-99429-3.00006-0
Bio-inspired Metal-Metal Oxides as Pd Support Catalysts for CO2 Electro-Reduction into Electrofuels
Fuku, X. G., Mkhohlakali, A. C., Xaba, N., Modibedi, M., & Makgopa, K. (2024) · Environmental chemistry for a sustainable world · doi:10.1007/978-3-031-55329-5_9
Li, W., Chen, Y., Liu, C., & Zhang, Y. (2024) · Journal of Physics D Applied Physics · doi:10.1088/1361-6463/ad60d5
Electroreduction of Carbon Dioxide in Ionic Liquid–Based Electrolytes
Liu, Z., & Zhao, Y. (2025) · Wiley eBooks · doi:10.1002/9783527838967.ch04
Kaur, R., Sharma, N., & Sharma, S. (2025) · AIP conference proceedings · doi:10.1063/5.0270749
Metadata
- Authors
- Lu, L., Sun, X., Ma, J., Yang, D., Wu, H., Zhang, B., Zhang, J., & Han, B.
- Affiliations
- Chinese Academy of Sciences (CN)
- East China Normal University (CN)
- Corresponding author
- Sun, Xiaofu
- Han, Buxing
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2018-10-02
- Volume
- 57
- Issue
- 43
- Pages
- 14149-14153
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2889349896
- Cited by
- 310
- References
- 48
- Citations by year
- 2026: 16 · 2025: 34 · 2024: 46 · 2023: 34 · 2022: 51 · 2021: 52 · 2020: 48 · 2019: 28 · 2018: 1
- FWCI
- 7.45
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- Funders
- National Science Foundation
- National Natural Science Foundation of China
- National Key Research and Development Program of China
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Keywords
- electrochemical CO2 reduction, methanol synthesis, palladium-copper bimetallic catalyst, Faradaic efficiency, grain boundaries
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