The DOI matches its Crossref record; 11 of the 11 references it cites were found in a registry or an index.
High‐Curvature Transition‐Metal Chalcogenide Nanostructures with a Pronounced Proximity Effect Enable Fast and Selective CO2 Electroreduction
Abstract
A considerable challenge in the conversion of carbon dioxide into useful fuels comes from the activation of CO 2 to CO 2.− or other intermediates, which often requires precious‐metal catalysts, high overpotentials, and/or electrolyte additives (e.g., ionic liquids). We report a microwave heating strategy for synthesizing a transition‐metal chalcogenide nanostructure that efficiently catalyzes CO 2 electroreduction to carbon monoxide (CO). We found that the cadmium sulfide (CdS) nanoneedle arrays exhibit an unprecedented current density of 212 mA cm−2 with 95.5±4.0 % CO Faraday efficiency at −1.2 V versus a reversible hydrogen electrode (RHE; without i R correction). Experimental and computational studies show that the high‐curvature CdS nanostructured catalyst has a pronounced proximity effect which gives rise to large electric field enhancement, which can concentrate alkali‐metal cations resulting in the enhanced CO 2 electroreduction efficiency.
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Cites
Combining theory and experiment in electrocatalysis: Insights into materials design
Seh, Z. W., Kibsgaard, J., Dickens, C. F., Chorkendorff, I., Nørskov, J. K., & Jaramillo, T. F. (2017) · Science · doi:10.1126/science.aad4998 · Cited by 12,114
CO 2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface
Dinh, C.-T., Burdyny, T., Kibria, M. G., Seifitokaldani, A., Gabardo, C. M., García de Arquer, F. P., Kiani, A., Edwards, J. P., De Luna, P., Bushuyev, O. S., et al. (2018) · Science · doi:10.1126/science.aas9100 · Cited by 2,515
Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration
Liu, M., Pang, Y., Zhang, B., De Luna, P., Voznyy, O., Xu, J., Zheng, X., Dinh, C. T., Fan, F., Cao, C., et al. (2016) · Nature · doi:10.1038/nature19060 · Cited by 2,000
Self-citationPartially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel
Gao, S., Lin, Y., Jiao, X., Sun, Y., Luo, Q., Zhang, W., Li, D., Yang, J., & Xie, Y. (2016) · Nature · doi:10.1038/nature16455 · Cited by 1,865
What Should We Make with CO2 and How Can We Make It?
Bushuyev, O. S., De Luna, P., Dinh, C. T., Tao, L., Saur, G., van de Lagemaat, J., Kelley, S. O., & Sargent, E. H. (2018) · Joule · doi:10.1016/j.joule.2017.09.003 · Cited by 1,593
Ionic Liquid–Mediated Selective Conversion of CO 2 to CO at Low Overpotentials
Rosen, B. A., Salehi-Khojin, A., Thorson, M. R., Zhu, W., Whipple, D. T., Kenis, P. J. A., & Masel, R. I. (2011) · Science · doi:10.1126/science.1209786 · Cited by 1,558
Highly selective plasma-activated copper catalysts for carbon dioxide reduction to ethylene
Mistry, H., Varela, A. S., Bonifacio, C. S., Zegkinoglou, I., Sinev, I., Choi, Y.-W., Kisslinger, K., Stach, E. A., Yang, J. C., Strasser, P., et al. (2016) · Nature Communications · doi:10.1038/ncomms12123 · Cited by 1,214
De Luna, P., Quintero-Bermudez, R., Dinh, C.-T., Ross, M. B., Bushuyev, O. S., Todorović, P., Regier, T., Kelley, S. O., Yang, P., & Sargent, E. H. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0018-9 · Cited by 1,046
Self-citationVerma, S., Lu, X., Ma, S., Masel, R. I., & Kenis, P. J. A. (2016) · Physical Chemistry Chemical Physics · doi:10.1039/c5cp05665a · Cited by 497
One-step electrosynthesis of ethylene and ethanol from CO2 in an alkaline electrolyzer
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Cited by
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Yang, P.-P., Zhang, X.-L., Gao, F.-Y., Zheng, Y.-R., Niu, Z.-Z., Yu, X., Liu, R., Wu, Z.-Z., Qin, S., Chi, L.-P., et al. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c01699 · Cited by 709
Self-citationWang, Q., Feng, Q., Lei, Y., Tang, S., Xu, L., Xiong, Y., Fang, G., Wang, Y., Yang, P., Liu, J., et al. (2022) · Nature Communications · doi:10.1038/s41467-022-31383-4 · Cited by 363
Self-citationMeng, D., Zhang, M., Si, D., Mao, M., Hou, Y., Huang, Y., & Cao, R. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202111136 · Cited by 312
Hu, Q., Han, Z., Wang, X., Li, G., Wang, Z., Huang, X., Yang, H., Ren, X., Zhang, Q., Liu, J., et al. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202009277 · Cited by 241
Metadata
- Authors
- Gao, F., Hu, S., Zhang, X., Zheng, Y., Wang, H., Niu, Z., Yang, P., Bao, R., Ma, T., Dang, Z., Guan, Y., Zheng, X., Zheng, X., Zhu, J., Gao, M., & Yu, S.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2020-02-03
- Volume
- 59
- Issue
- 22
- Pages
- 8706-8712
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2998402750
- Cited by
- 222
- References
- 11
- FWCI
- 4.84
- Type
- journal article
- Language
- en
- Open access
- closed
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- Gao, F., Hu, S., Zhang, X., Zheng, Y., Wang, H., Niu, Z., Yang, P., Bao, R., Ma, T., Dang, Z., Guan, Y., Zheng, X., Zheng, X., Zhu, J., Gao, M., & Yu, S. (2020). High‐Curvature Transition‐Metal Chalcogenide Nanostructures with a Pronounced Proximity Effect Enable Fast and Selective CO2 Electroreduction. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201912348
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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
