The DOI matches its Crossref record; 59 of the 59 references it cites were found in a registry or an index.
Zeolite‐Encaged Single‐Atom Rhodium Catalysts: Highly‐Efficient Hydrogen Generation and Shape‐Selective Tandem Hydrogenation of Nitroarenes
Abstract
Single‐atom catalysts are emerging as a new frontier in heterogeneous catalysis because of their maximum atom utilization efficiency, but they usually suffer from inferior stability. Herein, we synthesized single‐atom Rh catalysts embedded in MFI‐type zeolites under hydrothermal conditions and subsequent ligand‐protected direct H 2 reduction. C s‐corrected scanning transmission electron microscopy and extended X‐ray absorption analyses revealed that single Rh atoms were encapsulated within 5‐membered rings and stabilized by zeolite framework oxygen atoms. The resultant catalysts exhibited excellent H 2 generation rates from ammonia borane (AB) hydrolysis, up to 699 min−1 at 298 K, representing the top level among heterogeneous catalysts for AB hydrolysis. The catalysts also showed superior catalytic performance in shape‐selective tandem hydrogenation of various nitroarenes by coupling with AB hydrolysis, giving >99 % yield of corresponding amine products.
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Single-atom catalysis of CO oxidation using Pt1/FeOx
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Self-citationHydrogen Storage in Microporous Metal-Organic Frameworks
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Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis
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Self-citationHeterogeneous single-atom catalysis
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Self-citationSingle-Atom Catalysts: Synthetic Strategies and Electrochemical Applications
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Thermally stable single-atom platinum-on-ceria catalysts via atom trapping
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Single‐Atom Pt as Co‐Catalyst for Enhanced Photocatalytic H2 Evolution
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Emerging applications of zeolites in catalysis, separation and host–guest assembly
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Self-citationMa, X., Liu, H., Yang, W., Mao, G., Zheng, L., & Jiang, H.-L. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c05032 · Cited by 445
Exploiting Ru‐Induced Lattice Strain in CoRu Nanoalloys for Robust Bifunctional Hydrogen Production
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Self-citationAdvances in Catalytic Applications of Zeolite‐Supported Metal Catalysts
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Metadata
- Authors
- Sun, Q., Wang, N., Zhang, T., Bai, R., Mayoral, A., Zhang, P., Zhang, Q., Terasaki, O., & Yu, J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2019-11-19
- Volume
- 58
- Issue
- 51
- Pages
- 18570-18576
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2981494409
- Cited by
- 454
- References
- 59
- FWCI
- 17.63
- Type
- journal article
- Language
- en
- Open access
- closed
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