The DOI matches its Crossref record; 34 of the 34 references it cites were found in a registry or an index.
Inhibiting Solvent Co‐Intercalation in a Graphite Anode by a Localized High‐Concentration Electrolyte in Fast‐Charging Batteries
Abstract
Lithium‐ion batteries with routine carbonate electrolytes cannot exhibit satisfactory fast‐charging performance and lithium plating is widely observed at low temperatures. Herein we demonstrate that a localized high‐concentration electrolyte consisting of 1.5 M lithium bis(fluorosulfonyl)imide in dimethoxyethane with bis(2,2,2‐trifluoroethyl) ether as the diluent, enables fast‐charging of working batteries. A uniform and robust solid electrolyte interphase (SEI) can be achieved on graphite surface through the preferential decomposition of anions. The established SEI can significantly inhibit ether solvent co‐intercalation into graphite and achieve highly reversible Li+ intercalation/de‐intercalation. The graphite | Li cells exhibit fast‐charging potential (340 mAh g−1 at 0.2 C and 220 mAh g−1 at 4 C), excellent cycling stability (ca. 85.5 % initial capacity retention for 200 cycles at 4 C), and impressive low‐temperature performance.
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Cites
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Cited by
Emerging Era of Electrolyte Solvation Structure and Interfacial Model in Batteries
Cheng, H., Sun, Q., Li, L., Zou, Y., Wang, Y., Cai, T., Zhao, F., Liu, G., Ma, Z., Wahyudi, W., et al. (2022) · ACS Energy Letters · doi:10.1021/acsenergylett.1c02425 · Cited by 640
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Zinc Single‐Atom‐Regulated Hard Carbons for High‐Rate and Low‐Temperature Sodium‐Ion Batteries
Lu, Z., Wang, J., Feng, W., Yin, X., Feng, X., Zhao, S., Li, C., Wang, R., Huang, Q., & Zhao, Y. (2023) · Advanced Materials · doi:10.1002/adma.202211461 · Cited by 373
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Research Progresses of Liquid Electrolytes in Lithium‐Ion Batteries
Liu, Y., Zhao, C., Du, J., Zhang, X., Chen, A., & Zhang, Q. (2023) · Small · doi:10.1002/smll.202205315 · Cited by 328
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Metadata
- Authors
- Jiang, L., Yan, C., Yao, Y., Cai, W., Huang, J., & Zhang, Q.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2020-12-15
- Volume
- 60
- Issue
- 7
- Pages
- 3402-3406
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W3094540307
- Cited by
- 447
- References
- 34
- FWCI
- 18.23
- Type
- journal article
- Language
- en
- Open access
- closed
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