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Eutectic‐Based Ionic Liquids with Metal‐Containing Anions and Cations

Abbott, Andrew P., Barron, John C., Ryder, Karl S., Wilson, David·2007·Chemistry – A European Journal

Abstract

Eutectic mixtures of zinc chloride and donor molecules such as urea and acetamide are described and it is proposed that these constitute a new class of ionic liquids. FAB‐MS analysis shows that the liquids are made up of metal‐containing anions and cations in which the donor is coordinated to the cation. Data on the viscosity, conductivity, density, phase behaviour and surface tension are presented and these are shown to be significantly different to other related ionic liquids that incorporate quaternary ammonium salts. The conductivity and viscosity are comparable with other ionic liquids and the data fit well to the Hole theory model recently proposed.

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Research works printed but not linked: 19

  1. 10.1021/bk-2002-0818.ch017 · DOI
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  3. Wasserscheid P., 2003, Ionic Liquids in Synthesis
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  5. 2005, Electrochemical Aspects of Ionic Liquids
  6. 10.1039/b205170m · DOI · Paper page
  7. 10.1039/b413328e · DOI
  8. 10.1016/S0013-4686(02)00509-1 · DOI
  9. 10.1002/chem.200400127 · DOI · Paper page
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  12. Bockris J. O'M., 1970, Modern Electrochemistry, Vol. 1
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  16. Jeffery G. A., 1997, An Introduction to Hydrogen Bonding, 15
  17. 10.1002/cphc.200500283 · DOI · Paper page
  18. A. P. Abbott R. C. Harris K. S. Ryder J. Phys. Chem. B2007 in press.
  19. “Ionic Liquids as Green Solvents: Progress and Prospects” ACS Symposium Series2003 pp. 439–452.

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Metadata

Authors
Abbott, A. P., Barron, J. C., Ryder, K. S., & Wilson, D.
Venue
Chemistry – A European Journal
Publisher
Wiley
Published
2007-07-17
Volume
13
Issue
22
Pages
6495-6501
ISSN
  • 0947-6539 (ISSN-L)
  • 1521-3765
OpenAlex
W2144817668
Cited by
778
References
5
FWCI
2.38
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Eutectic‐Based Ionic Liquids with Metal‐Containing Anions and Cations. https://app.cochat.ai/papers/10.1002/chem.200601738
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Abbott, A. P., Barron, J. C., Ryder, K. S., & Wilson, D. (2007). Eutectic‐Based Ionic Liquids with Metal‐Containing Anions and Cations. Chemistry – A European Journal. https://doi.org/10.1002/chem.200601738

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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