Importance of Size and Distribution of Ni Nanoparticles for the Hydrodeoxygenation of Microalgae Oil
Abstract
Improved synthetic approaches for preparing small‐sized Ni nanoparticles (d=3 nm) supported on HBEA zeolite have been explored and compared with the traditional impregnation method. The formation of surface nickel silicate/aluminate involved in the two precipitation processes are inferred to lead to the stronger interaction between the metal and the support. The lower Brønsted acid concentrations of these two Ni/HBEA catalysts compared with the parent zeolite caused by the partial exchange of Brønsted acid sites by Ni 2+ cations do not influence the hydrodeoxygenation rates, but alter the product selectivity. Higher initial rates and higher stability have been achieved with these optimized catalysts for the hydrodeoxygenation of stearic acid and microalgae oil. Small metal particles facilitate high initial catalytic activity in the fresh sample and size uniformity ensures high catalyst stability.
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Support acidity (HBEA zeolite or zirconia) plays a key role in the reaction kinetics of nickel-based algae oil deoxygenation.
“support acidity (HBEA zeolite or zirconia) was shown in mechanistic studies with model compounds to play a key role in the reaction kinetics”
From Catalytic Hydroprocessing of Single-Cell Oils to Hydrocarbon Fuels: Converting microbial lipids to fuels is a promising approach to replace fossil fuels (2021) · cites this paper as [94]
Nickel particle size is key to catalyst activity in nickel-based algae oil deoxygenation.
“the nickel particle size was also key to catalyst activity”
From Catalytic Hydroprocessing of Single-Cell Oils to Hydrocarbon Fuels: Converting microbial lipids to fuels is a promising approach to replace fossil fuels (2021) · cites this paper as [94]
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- Authors
- Song, W., Zhao, C., & Lercher, J. A.
- Affiliations
- Technical University of Munich (DE)
- Pacific Northwest National Laboratory (US)
- Corresponding author
- Zhao, Chen
- Lercher, Johannes A.
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2013-06-21
- Volume
- 19
- Issue
- 30
- Pages
- 9833-9842
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2011835332
- Cited by
- 154
- References
- 53
- Citations by year
- 2026: 4 · 2025: 9 · 2024: 9 · 2023: 11 · 2022: 9 · 2021: 7 · 2020: 15 · 2019: 14 · 2018: 9 · 2017: 27 · 2016: 12 · 2015: 14 · 2014: 13 · 2013: 1
- FWCI
- 17.69
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemistry - A European Journal (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Elitenetzwerk Bayern
- Graduate School, Technische Universität München
- Topics
- Physical Sciences › Engineering › Mechanical Engineering › Catalysis and Hydrodesulfurization Studies
- Physical Sciences › Engineering › Biomedical Engineering › Biodiesel Production and Applications
- Physical Sciences › Chemistry › Organic Chemistry › Nanomaterials for catalytic reactions
- Keywords
- nickel nanoparticles, hydrodeoxygenation, microalgae oil, Hβ zeolite, nanoparticle size distribution, supported metal catalysts, Brønsted acid sites, stearic acid, catalyst stability, impregnation method comparison
- MeSH terms
- Catalysis, Nickel, Particle Size, Stearic Acids, Zeolites, Metal Nanoparticles, Biofuels, Microalgae
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