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Metal Nanoparticles as Heterogeneous Fenton Catalysts
Open accessAbstract
The Fenton reaction (the generation of hydroxyl radicals from hydrogen peroxide) is the most useful method for degradation of organic pollutants in aqueous solution at moderate concentrations. In this Review we summarize the use of metal nanoparticles, either unsupported or deposited on large‐surface‐area solids, as Fenton catalysts. The Review complements two other reviews in the field of heterogeneous Fenton catalysis using aluminosilicates and carbonaceous materials. Herein, particular emphasis is given to the reaction conditions in which these catalysts are used, highlighting the operating mechanism and the relative efficiency of the materials. Aspects such as leaching of the metal to the solution, reusability, and the concentration of hydrogen peroxide used are analyzed in detail. Besides a critical description of the present status of the field, future trends and the need to establishing valid comparisons to assess the relative efficiencies of the materials are commented on.
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Intrinsic peroxidase-like activity of ferromagnetic nanoparticles
Gao, L., Zhuang, J., Nie, L., Zhang, J., Zhang, Y., Gu, N., Wang, T., Feng, J., Yang, D., Perrett, S., et al. (2007) · Nature Nanotechnology · doi:10.1038/nnano.2007.260 · Cited by 7,483
Pignatello, J. J., Oliveros, E., & MacKay, A. (2006) · Critical Reviews in Environmental Science and Technology · doi:10.1080/10643380500326564 · Cited by 4,133
Electro-Fenton Process and Related Electrochemical Technologies Based on Fenton’s Reaction Chemistry
Brillas, E., Sirés, I., & Oturan, M. A. (2009) · Chemical Reviews · doi:10.1021/cr900136g · Cited by 3,437
Magnetic iron oxide nanoparticles: synthesis and surface functionalization strategies
Wu, W., He, Q., & Jiang, C. (2008) · Nanoscale Research Letters · doi:10.1007/s11671-008-9174-9 · Cited by 2,300
Supported gold nanoparticles as catalysts for organic reactions
Corma, A., & Garcia, H. (2008) · Chemical Society Reviews · doi:10.1039/b707314n · Cited by 1,883
Cited by
Nanomaterials with enzyme-like characteristics (nanozymes): next-generation artificial enzymes
Wei, H., & Wang, E. (2013) · Chemical Society Reviews · doi:10.1039/c3cs35486e · Cited by 3,779
Interfacial mechanisms of heterogeneous Fenton reactions catalyzed by iron-based materials: A review
He, J., Yang, X., Men, B., & Wang, D. (2016) · Journal of Environmental Sciences · doi:10.1016/j.jes.2015.12.003 · Cited by 587
Rayaroth, M. P., Aravindakumar, C. T., Shah, N. S., & Boczkaj, G. (2022) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.133002 · Cited by 532
Ribeiro, R. S., Frontistis, Z., Mantzavinos, D., Venieri, D., Antonopoulou, M., Konstantinou, I., Silva, A. M. T., Faria, J. L., & Gomes, H. T. (2016) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2016.06.021 · Cited by 81
Metadata
- Authors
- Dhakshinamoorthy, A., Navalon, S., Alvaro, M., & Garcia, H.
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2012-01-09
- Volume
- 5
- Issue
- 1
- Pages
- 46-64
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W2098666192
- Cited by
- 282
- References
- 6
- FWCI
- 21.81
- Type
- journal article
- Language
- en
- Open access
- green
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