Cited by 380Ionic liquids properties and applicationsCatalysis for Biomass ConversionBiofuel production and bioconversion

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Green Processing of Lignocellulosic Biomass and Its Derivatives in Deep Eutectic Solvents

Tang, Xing, Zuo, Miao, Li, Zheng, Liu, Huai, Xiong, Caixia, Zeng, Xianhai, Sun, Yong, Hu, Lei, Liu, Shijie, Lei, Tingzhou, Lin, Lu·2017·ChemSusChem

DOI 10.1002/cssc.201700457

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Abstract

The scientific community has been seeking cost-competitive and green solvents with good dissolving capacity for the valorization of lignocellulosic biomass. At this point, deep eutectic solvents (DESs) are currently emerging as a new class of promising solvents that are generally liquid eutectic mixtures formed by self-association (or hydrogen-bonding interaction) of two or three components. DESs are attractive solvents for the fractionation (or pretreatment) of lignocellulose and the valorization of lignin, owing to the high solubility of lignin in DESs. DESs are also employed as effective media for the modification of cellulose to afford functionalized cellulosic materials, such as cellulose nanocrystals. More interestingly, biomassderived carbohydrates, such as fructose, can be used as one of the constituents of DESs and then dehydrated to 5-hydroxymethylfurfural in high yield. In this review, a comprehensive summary of recent contribution of DESs to the processing of lignocellulosic biomass and its derivatives is provided. Moreover, further discussion about the challenges of the application of DESs in biomass processing is presented.

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Authors: Tang, X., Zuo, M., Li, Z., Liu, H., Xiong, C., Zeng, X., Sun, Y., Hu, L., Liu, S., Lei, T., & Lin, L.
Affiliations: Xiamen University (CN)
Huaiyin Normal University (CN)
State University of New York (US)
Henan Key Lab of Biomass Energy Zhengzhou Henan 450008 P. R. China
Corresponding author: Zeng, Xianhai
Lin, Lu
ORCID: Tang, Xing
Zuo, Miao
Li, Zheng
Liu, Huai
Zeng, Xianhai
Sun, Yong
Hu, Lei
Liu, Shijie
Lin, Lu
Venue: ChemSusChem
Publisher: Wiley
Published: 2017-05-23
Volume: 10
Issue: 13
Pages: 2696-2706
ISSN: 1864-5631 (ISSN-L)
1864-564X
DOI: 10.1002/cssc.201700457
OpenAlex: W2606717551
Cited by: 380
References: 105
Citations by year: 2026: 21 · 2025: 37 · 2024: 41 · 2023: 47 · 2022: 54 · 2021: 56 · 2020: 49 · 2019: 40 · 2018: 27 · 2017: 6
FWCI: 1.16
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor)
Locations: ChemSusChem (publishedVersion)
PubMed (publishedVersion)
Funders: National Natural Science Foundation of China (21676223, 21506177)
Topics: Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Ionic liquids properties and applications
Physical Sciences › Chemical Engineering › Catalysis › Catalysis for Biomass Conversion
Physical Sciences › Engineering › Biomedical Engineering › Biofuel production and bioconversion
Keywords: deep eutectic solvents, lignocellulosic biomass, lignin valorization, lignocellulosic biomass pretreatment, cellulose modification, cellulose nanocrystals, 5-hydroxymethylfurfural, fructose dehydration, biomass-derived carbohydrates, green solvents, hydrogen bonding
MeSH terms: Catalysis, Lignin, Solvents, Biomass, Green Chemistry Technology

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Green Processing of Lignocellulosic Biomass and Its Derivatives in Deep Eutectic Solvents

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