Salen, salan and salalen iron( iii ) complexes as catalysts for CO 2 /epoxide reactions and ROP of cyclic esters
Abstract
Salan, salen and salalen iron complexes as catalysts in CO 2 /epoxide reactions and in the ROP of ε-caprolactone and l -lactide.
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Many iron catalyst studies were performed in solution, sometimes using the toxic propylene oxide as solvent and precursor to the initiating species.
“Many of these studies were performed in solution, sometimes using the toxic propylene oxide as solvent and precursor to the initiating species.”
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- Authors
- Cozzolino, M., Leo, V., Tedesco, C., Mazzeo, M., & Lamberti, M.
- Affiliations
- University of Salerno (IT)
- Corresponding author
- Lamberti, Marina
- Venue
- Dalton Transactions
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2018
- Volume
- 47
- Issue
- 37
- Pages
- 13229-13238
- ISSN
- 1477-9226 (ISSN-L)
- 1477-9234
- OpenAlex
- W2888019086
- Cited by
- 83
- References
- 71
- Citations by year
- 2026: 8 · 2025: 8 · 2024: 5 · 2023: 13 · 2022: 9 · 2021: 7 · 2020: 13 · 2019: 17 · 2018: 3
- FWCI
- 3.33
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Dalton Transactions (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Fondazione Cariplo (Apollo project 2016-0643)
- Topics
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
- Keywords
- salen ligands, iron(III) complexes, ring-opening polymerization, cyclic esters, L-lactide, ε-caprolactone, catalyst reactivity, ligand flexibility, CO2 fixation
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