Cited by 2,327TiO2 Photocatalysis and Solar CellsSpectroscopy Techniques in Biomedical and Chemical ResearchSolid-state spectroscopy and crystallography

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Raman spectrum of anatase, TiO 2

Ohsaka, Toshiaki, Izumi, Fujio, Fujiki, Yoshinori·1978·Journal of Raman Spectroscopy

DOI 10.1002/jrs.1250070606

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Abstract

Raman spectra of anatase have been observed in natural and synthetic crystals. Both crystals show the same spectral features. The Raman band occurring at 516 cm −1 at room temperature is split into two peaks centred at 519 cm −1 and 513 cm −1 at low temperature (73 K). The six Raman active fundamentals predicted by group theory are all observed and assigned. The spectra are analyzed by a simple model considering only short‐range forces and the calculated vibrational frequencies are in good agreement with the observed Raman frequencies.

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“Although the rutile phase also exhibits a peak around this area it is a normally very weak signal, therefore this peak is due to the presence of the anatase phase [30].”
Background

Authors: Ohsaka, T., Izumi, F., & Fujiki, Y.
Venue: Journal of Raman Spectroscopy
Publisher: Wiley
Published: 1978-12
Volume: 7
Issue: 6
Pages: 321-324
ISSN: 0377-0486 (ISSN-L)
1097-4555
DOI: 10.1002/jrs.1250070606
OpenAlex: W2088149984
Cited by: 2,327
References: 12
Citations by year: 2026: 124 · 2025: 113 · 2024: 113 · 2023: 96 · 2022: 102 · 2021: 121 · 2020: 136 · 2019: 162 · 2018: 152 · 2017: 163 · 2016: 135 · 2015: 123 · 2014: 116 · 2013: 98 · 2012: 101
FWCI: 1.90
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor, 9631 d)
Locations: Journal of Raman Spectroscopy (publishedVersion)
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › TiO2 Photocatalysis and Solar Cells
Life Sciences › Biochemistry, Genetics and Molecular Biology › Biophysics › Spectroscopy Techniques in Biomedical and Chemical Research
Physical Sciences › Materials Science › Materials Chemistry › Solid-state spectroscopy and crystallography
Keywords: anatase, titanium dioxide, Raman spectra, vibrational frequencies

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Raman spectrum of anatase, TiO 2

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