Cited by 2,327TiO2 Photocatalysis and Solar CellsSpectroscopy Techniques in Biomedical and Chemical ResearchSolid-state spectroscopy and crystallography

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Raman spectrum of anatase, TiO 2

Ohsaka, Toshiaki, Izumi, Fujio, Fujiki, Yoshinori·1978·Journal of Raman Spectroscopy

DOI 10.1002/jrs.1250070606

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Abstract

Raman spectra of anatase have been observed in natural and synthetic crystals. Both crystals show the same spectral features. The Raman band occurring at 516 cm −1 at room temperature is split into two peaks centred at 519 cm −1 and 513 cm −1 at low temperature (73 K). The six Raman active fundamentals predicted by group theory are all observed and assigned. The spectra are analyzed by a simple model considering only short‐range forces and the calculated vibrational frequencies are in good agreement with the observed Raman frequencies.

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“[63] Ohsaka T, Izumi F, Fujiki Y (1978) Raman spectrum of anatase TiO2.”
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“At the 398 cm intensity, vibration occurs in the B1g mode related to the antisymmetric O–Ti–O, whereas the peak at 513 cm refers to the A1g mode of the symmetrical flexion O–Ti–O of the anatase structure (Ohsaka et al. 1978; Conceição et al. 2017; Jin et al. 2020).”
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Authors: Ohsaka, T., Izumi, F., & Fujiki, Y.
Venue: Journal of Raman Spectroscopy
Publisher: Wiley
Published: 1978-12
Volume: 7
Issue: 6
Pages: 321-324
ISSN: 0377-0486 (ISSN-L)
1097-4555
DOI: 10.1002/jrs.1250070606
OpenAlex: W2088149984
Cited by: 2,327
References: 12
Citations by year: 2026: 124 · 2025: 113 · 2024: 113 · 2023: 96 · 2022: 102 · 2021: 121 · 2020: 136 · 2019: 162 · 2018: 152 · 2017: 163 · 2016: 135 · 2015: 123 · 2014: 116 · 2013: 98 · 2012: 101
FWCI: 1.90
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor, 9631 d)
Locations: Journal of Raman Spectroscopy (publishedVersion)
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › TiO2 Photocatalysis and Solar Cells
Life Sciences › Biochemistry, Genetics and Molecular Biology › Biophysics › Spectroscopy Techniques in Biomedical and Chemical Research
Physical Sciences › Materials Science › Materials Chemistry › Solid-state spectroscopy and crystallography
Keywords: anatase, titanium dioxide, Raman spectra, vibrational frequencies

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Raman spectrum of anatase, TiO 2

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