Cited by 2,327TiO2 Photocatalysis and Solar CellsSpectroscopy Techniques in Biomedical and Chemical ResearchSolid-state spectroscopy and crystallography

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Raman spectrum of anatase, TiO 2

Ohsaka, Toshiaki, Izumi, Fujio, Fujiki, Yoshinori·1978·Journal of Raman Spectroscopy

DOI 10.1002/jrs.1250070606

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Abstract

Raman spectra of anatase have been observed in natural and synthetic crystals. Both crystals show the same spectral features. The Raman band occurring at 516 cm −1 at room temperature is split into two peaks centred at 519 cm −1 and 513 cm −1 at low temperature (73 K). The six Raman active fundamentals predicted by group theory are all observed and assigned. The spectra are analyzed by a simple model considering only short‐range forces and the calculated vibrational frequencies are in good agreement with the observed Raman frequencies.

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Radiative and Non-Radiative Recombination Pathways in Mixed-Phase TiO2 Nanotubes for PEC Water-Splitting
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“Further, the appearance of the peaks at 451 cm–1, 610 cm–1, and the second order peak at 240 cm–1, besi es the peak at 144 cm–1, indicates the presence f rutile in TNT700 [55].”
BackgroundInfluential
Synergistic eminently active catalytic and recyclable Ag, Cu and Ag-Cu alloy nanoparticles supported on TiO2 for sustainable and cleaner environmental applications: A phytogenic mediated synthesis
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“…anatase as main crystalline phase was corroborated; in Figure 2a-b, the vibrational Raman modes for anatase are not labeled, which occur at 396, 515 and 638 cm-1 and are assigned to B1g, Ag + B1g and Eg, respectively (Ohsaka et al., 1978) and also to the presence of the brookite crystalline phase.”
Background
Photocatalytic reduction of CO2 to CO over the Ti–Highly dispersed HZSM-5 zeolite containing Fe
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Photoactive TiO2 coatings obtained by Plasma Electrolytic Oxidation in refrigerated electrolytes
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Catalytic behaviour of TiO 2 –ZrO 2 binary oxide synthesized by sol–gel process for glucose conversion to 5-hydroxymethylfurfural
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Li intercalation in TiO2 anatase: Raman spectroscopy and lattice dynamic studies.
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Structural and Spectroscopic Characterization of TiO2 Nanocrystalline Materials Synthesized by Different Methods
Podelinska, A., Neilande, E., Pankratova, V., Serga, V., Bandarenka, H., Burko, A., Piskunov, S., Pankratov, V. A., Šarakovskis, A., Popov, A. I., et al. (2025) · Nanomaterials · doi:10.3390/nano15070498 · Cited by 45
“144 [32], 143 [33], 144 [35], 147 [39], 144 for O 16 [41], 144 [45] E g [32,41,45] 189.5 169.88–194.66 [34], 171.1 [46] 197 [32], 198 [33], 200 [35], 198 [39], 196 for O 16 [41], 197 [45] E g [32,41,45] 419.6 368.84–413.70 [34], 398.4 [46] 399 [32], 395 [33], 397 [35], 398 [39], 394 for O 16 [41],…”
Influential
Single Nb atom modified anatase TiO2(110) for efficient electrocatalytic nitrogen reduction reaction
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Visible light photocatalytic activity of sol–gel Ni-doped TiO2 on p-arsanilic acid degradation
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“Raman vibrational modes occurred at frequencies of 144 (Eg), 199 (Eg), 399 (B1g), 515 (A1g+ B1g), and 640 (Eg) cm −1 corroborated the presence of anatase crystalline phase in these samples [40].”
Background
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Microstructure and optical dispersion characterization of nanocomposite sol-gel TiO₂-SiO₂ thin films with different compositions.
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Authors: Ohsaka, T., Izumi, F., & Fujiki, Y.
Venue: Journal of Raman Spectroscopy
Publisher: Wiley
Published: 1978-12
Volume: 7
Issue: 6
Pages: 321-324
ISSN: 0377-0486 (ISSN-L)
1097-4555
DOI: 10.1002/jrs.1250070606
OpenAlex: W2088149984
Cited by: 2,327
References: 12
Citations by year: 2026: 124 · 2025: 113 · 2024: 113 · 2023: 96 · 2022: 102 · 2021: 121 · 2020: 136 · 2019: 162 · 2018: 152 · 2017: 163 · 2016: 135 · 2015: 123 · 2014: 116 · 2013: 98 · 2012: 101
FWCI: 1.90
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor, 9631 d)
Locations: Journal of Raman Spectroscopy (publishedVersion)
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › TiO2 Photocatalysis and Solar Cells
Life Sciences › Biochemistry, Genetics and Molecular Biology › Biophysics › Spectroscopy Techniques in Biomedical and Chemical Research
Physical Sciences › Materials Science › Materials Chemistry › Solid-state spectroscopy and crystallography
Keywords: anatase, titanium dioxide, Raman spectra, vibrational frequencies

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Raman spectrum of anatase, TiO 2

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