Cited by 2,327TiO2 Photocatalysis and Solar CellsSpectroscopy Techniques in Biomedical and Chemical ResearchSolid-state spectroscopy and crystallography

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Raman spectrum of anatase, TiO 2

Ohsaka, Toshiaki, Izumi, Fujio, Fujiki, Yoshinori·1978·Journal of Raman Spectroscopy

DOI 10.1002/jrs.1250070606

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Abstract

Raman spectra of anatase have been observed in natural and synthetic crystals. Both crystals show the same spectral features. The Raman band occurring at 516 cm −1 at room temperature is split into two peaks centred at 519 cm −1 and 513 cm −1 at low temperature (73 K). The six Raman active fundamentals predicted by group theory are all observed and assigned. The spectra are analyzed by a simple model considering only short‐range forces and the calculated vibrational frequencies are in good agreement with the observed Raman frequencies.

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“which is characteristic of the Raman signature of anatase [76].”
Background
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Hybrid cotton–anatase prepared under mild conditions with high photocatalytic activity under sunlight
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Effect of substrate temperature on the arrangement of ultra-thin TiO2 films grown by a dc-magnetron sputtering deposition
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Facile one step synthesis of novel TiO2 nanocoral by sol–gel method using Aloe vera plant extract
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Improved efficiency of sol-gel synthesized mesoporous anatase nanopowders in photocatalytic degradation of metoprolol
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Visible-Light-Induced Bactericidal Activity of Vanadium-Pentoxide (V2O5)-Loaded TiO2 Nanoparticles
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“The peaks centering at 143, 199, 396, 514, and 636 cm were attributed to the anatase phase, while the other peaks, located at 235, 443, 608, and 826 cm, corresponded to the rutile phase [24, 25].”
Improving the electron mobility of TiO2 nanorods for enhanced efficiency of a polymer–nanoparticle solar cell
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Mechanism of the performance improvement of TiO2-x-based field-effect transistor using SiO2 as gate insulator
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Sphere-like MoS2 and porous TiO2 composite film on Ti foil as lithium-ion battery anode synthesized by plasma electrolytic oxidation and magnetron sputtering
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Photocatalytic reduction of nitroaromatics into anilines using CeO2-TiO2 nanocomposite
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Polymer-oriented evaporation induced self-assembly strategy to synthesize highly crystalline mesoporous metal oxides
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Marimo Bead-Supported Core-Shell Nanocomposites of Titanium Nitride and Chromium-Doped Titanium Dioxide as Highly Efficient Water Floatable Green Photocatalyst.
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Towards a durable high performance anode material for lithium storage: stabilizing N-doped carbon encapsulated FeS nanosheets with amorphous TiO2
Xie, X., Hu, Y., Fang, G., Cao, X.-X., Yin, B., Wang, Y., Liang, S., Cao, G., & Pan, A. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta03196k · Cited by 29
Photodegradation of Microcystin-LR Using Visible Light-Activated C/N-co-Modified Mesoporous TiO2 Photocatalyst
Khedr, T. M., El-Sheikh, S., Ismail, A., Kowalska, E., & Bahnemann, D. (2019) · Materials · doi:10.3390/ma12071027 · Cited by 29
“The phonon–ph on i teractions, which may be due to the O-Ti-O bo d vibr tional type, were very obvious in the Eg mode, hence the phonon co finement effects should cause an increase n the shif and asymmetric broadening of Raman peaks [33,34].”
BackgroundInfluential
UV–vis light induced photocatalytic activity of TiO2/graphene oxide nanocomposite coatings
Datcu, A., Mendoza, M., del Pino, Á. P., Logofatu, C., Luculescu, C., & Gyorgy, E. (2019) · Catalysis Today · doi:10.1016/j.cattod.2018.02.026 · Cited by 29
Defect generation in TiO2 nanotube anodes via heat treatment in various atmospheres for lithium-ion batteries.
Savva, A., Smith, K. A., Lawson, M., Croft, S., Weltner, A. E., Jones, C., Bull, H., Simmonds, P., Li, L., & Xiong, H. (2018) · Physical Chemistry, Chemical Physics - PCCP · doi:10.1039/c8cp04368j · Cited by 29
Photoreduction synthesis of silver on Bi2O3/TiO2 nanocomposites and their catalytic activity for the degradation of methyl orange
Malligavathy, M., Iyyapushpam, S., Nishanthi, S., & Padiyan, D. (2017) · Journal of materials science. Materials in electronics · doi:10.1007/s10854-017-7777-6 · Cited by 29
“Additionally, the peaks observed at around 398, 514 and 638 cm−1 also confirm the anatase phase of TiO2 and are assigned for the modes of B1g, A1g and Eg respectively [17].”
Background
One-step synthesis of size-controlled Br-doped TiO2 nanoparticles with enhanced visible-light photocatalytic activity
Wang, Q.-Q., Zhu, S.-L., Liang, Y.-Q., Cui, Z., Yang, X.-J., Liang, C.-Y., & Inoue, A. (2017) · doi:10.1016/j.materresbull.2016.10.026 · Cited by 29
Deposition of photocatalytic anatase titanium dioxide films by atmospheric dielectric barrier discharge
Chen, Q.-Q., Liu, Q.-R., Hubert, J., Huang, W.-D., Baert, K., Wallaert, G., Terryn, H., Delplancke-Ogletree, M., & Reniers, F. (2017) · doi:10.1016/j.surfcoat.2016.12.077 · Cited by 29
A generation of 2 μm Q-switched thulium-doped fibre laser based on anatase titanium(IV) oxide film saturable absorber
Latiff, A., Rusdi, M., Hisyam, M. B., Ahmad, H., & Harun, S. W. (2017) · doi:10.1080/09500340.2016.1220641 · Cited by 29

Authors: Ohsaka, T., Izumi, F., & Fujiki, Y.
Venue: Journal of Raman Spectroscopy
Publisher: Wiley
Published: 1978-12
Volume: 7
Issue: 6
Pages: 321-324
ISSN: 0377-0486 (ISSN-L)
1097-4555
DOI: 10.1002/jrs.1250070606
OpenAlex: W2088149984
Cited by: 2,327
References: 12
Citations by year: 2026: 124 · 2025: 113 · 2024: 113 · 2023: 96 · 2022: 102 · 2021: 121 · 2020: 136 · 2019: 162 · 2018: 152 · 2017: 163 · 2016: 135 · 2015: 123 · 2014: 116 · 2013: 98 · 2012: 101
FWCI: 1.90
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor, 9631 d)
Locations: Journal of Raman Spectroscopy (publishedVersion)
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › TiO2 Photocatalysis and Solar Cells
Life Sciences › Biochemistry, Genetics and Molecular Biology › Biophysics › Spectroscopy Techniques in Biomedical and Chemical Research
Physical Sciences › Materials Science › Materials Chemistry › Solid-state spectroscopy and crystallography
Keywords: anatase, titanium dioxide, Raman spectra, vibrational frequencies

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Raman spectrum of anatase, TiO 2

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