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Cited by 41biodegradable polymer synthesis and propertiesAdvanced Polymer Synthesis and CharacterizationPolymer composites and self-healing

Addition–Fragmentation Ring‐Opening Polymerization of Bio‐Based Thiocarbonyl l‐Lactide for Dual Degradable Vinyl Copolymers

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Kamiki, Ryoya, Kubo, Tomohiro, Satoh, Kotaro·2023·Macromolecular Rapid Communications
DOI 10.1002/marc.202200537
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Abstract

This study is designed to synthesize novel degradable polymers by radical addition–fragmentation ring‐opening copolymerization of bio‐based thiocarbonyl compounds with various vinyl monomers. Thiocarbonyl l‐lactide is capable of radical copolymerization with acrylates and styrene via radical addition to the carbon–sulfur double bonds followed by ring‐opening as well as controlled copolymerization in conjunction with the reversible addition–fragmentation chain transfer (RAFT) process. The obtained polymers possess ring‐opened thioester and ring‐retained thioacetal functionalities in the backbone, both of which could be cleaved under appropriate conditions with different chemical stimuli.

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  • Very recently, a few reports on radical polymerizations of cyclic thiocarbonyl compounds indicated that some thionolactones were incorporated into a polymer as a mixture of ring-opened and cyclic structures with and without β-scission, depending on the monomer structure and polymerization conditions.

    “Very recently, a few reports on radical polymerizations of cyclic thiocarbonyl compounds indicated that some thionolactones were incorporated into a polymer as a mixture of ring-opened and cyclic structures with and without β-scission, respectively, which depended on the monomer structure and the polymerization conditions.37−39”

    From Direct Radical Copolymerizations of Thioamides To Generate Vinyl Polymers with Degradable Thioether Bonds in the Backbones (2023) · cites this paper as [38]

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Authors
Kamiki, R., Kubo, T., & Satoh, K.
Affiliations
Tokyo Institute of Technology (JP)
Corresponding author
Satoh, Kotaro
ORCID
Venue
Macromolecular Rapid Communications
Publisher
Wiley
Published
2022-09-13
Volume
44
Issue
2
Pages
e2200537-e2200537
ISSN
  • 1022-1336 (ISSN-L)
  • 1521-3927
DOI
10.1002/marc.202200537
OpenAlex
W4294287303
Cited by
41
References
30
Citations by year
2026: 10 · 2025: 12 · 2024: 7 · 2023: 11 · 2022: 1
FWCI
1.94
Type
journal article
Language
en
Open access
Licence
Locations
  • Macromolecular Rapid Communications (publishedVersion, cc-by-nc)
  • PubMed (publishedVersion)
Funders
Japan Society for the Promotion of Science (JPNP18016, 20H05734, 18H05397)
Topics
  • Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
  • Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
Keywords
RAFT polymerization, bio-based polymers, acrylates, styrene, stimuli-responsive polymers, controlled radical copolymerization
MeSH terms
Acrylates, Dioxanes, Polymers, Polymerization

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