Renewable building blocks for sustainable polyesters: new biotechnological routes for greener plastics
Abstract
The next generation of plastics are expected to contribute to a massive reduction in the carbon footprint by the exploitation, in industrial productive processes, of renewable monomers such as polyols and dicarboxylic acids obtainable via biotechnological production. More specifically, there is a rising demand for advanced polyesters displaying new functional properties while meeting higher sustainability criteria. Polyesters are part of everyday life with applications in clothing, food packaging, car manufacturing and biomedical devices. This review is intended to provide an overview of the array of renewable building blocks already available for synthetic purposes and exploitable in the production of polyesters. Moreover, new greener routes for more environmentally friendly polyester production and processing are discussed, pointing out the major technological challenges. © 2016 Society of Chemical Industry
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Step-growth polymerization mediated by mild and selective enzyme catalysis provides a metal-free and eco-friendly route to polyesters and polycarbonates.
“SGP mediated by mild and selective enzyme catalysis also provides a metal-free and eco-friendly route to polyesters and polycarbonates.[255][256][257][258][259]”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [255]
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- Authors
- Pellis, A., Herrero Acero, E., Gardossi, L., Ferrario, V., & Guebitz, G. M.
- Affiliations
- BOKU University (AT)
- Austrian Centre of Industrial Biotechnology Division of Enzymes and Polymers Konrad Lorenz Strasse 20 A‐3430 Tulln an der Donau Austria
- University of Trieste (IT)
- Austrian Centre of Industrial Biotechnology (Austria) (AT)
- Corresponding author
- Ferrario, Valerio
- Venue
- Polymer International
- Publisher
- Wiley
- Published
- 2016-02-24
- Volume
- 65
- Issue
- 8
- Pages
- 861-871
- ISSN
- 0959-8103 (ISSN-L)
- 1097-0126
- OpenAlex
- W2299940306
- Cited by
- 151
- References
- 105
- Citations by year
- 2026: 1 · 2025: 11 · 2024: 12 · 2023: 6 · 2022: 9 · 2021: 12 · 2020: 10 · 2019: 18 · 2018: 37 · 2017: 26 · 2016: 8 · 2014: 1
- FWCI
- 12.12
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Polymer International (publishedVersion)
- ArTS Archivio della ricerca di Trieste (University of Trieste https://www.units.it/) (submittedVersion)
- CINECA IRIS Institutial Research Information System (University of Genoa) (submittedVersion)
- Funders
- Seventh Framework Programme (289253)
- Ministero dell’Istruzione, dell’Università e della Ricerca
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Engineering › Biomedical Engineering › Catalysis for Biomass Conversion
- Keywords
- bio-based monomers, sugar alcohols, dicarboxylic acids, biotechnological production, green plastics, carbon footprint reduction
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