Phase Behaviour and Morphologies of Block Copolymers

Block Copolymer Thermodynamics: Theory and Experiment

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Theory of Microphase Separation in Block Copolymers

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Block Copolymers—Designer Soft Materials

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The Physics of Block Copolymers

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Unifying Weak- and Strong-Segregation Block Copolymer Theories

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The physics of block copolymers

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Enabling nanotechnology with self assembled block copolymer patterns

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Fluctuation effects in the theory of microphase separation in block copolymers

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Polyisoprene-Polystyrene Diblock Copolymer Phase Diagram near the Order-Disorder Transition

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Block copolymers in tomorrow's plastics

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The Gyroid: A New Equilibrium Morphology in Weakly Segregated Diblock Copolymers

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Predicting the Mesophases of Copolymer-Nanoparticle Composites

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Phase Behavior of Block Copolymer/Homopolymer Blends

Matsen, M. W. (1995) · Macromolecules · doi:10.1021/ma00121a011 · Cited by 483

Block copolymer microstructures in the intermediate-segregation regime

Matsen, M. W., & Bates, F. S. (1997) · The Journal of Chemical Physics · doi:10.1063/1.473153 · Cited by 474

Nanostructured Thermosets from Self-Assembled Amphiphilic Block Copolymer/Epoxy Resin Mixtures

Lipic, P. M., Bates, F. S., & Hillmyer, M. A. (1998) · Journal of the American Chemical Society · doi:10.1021/ja981544s · Cited by 454

Complex Phase Behavior of Polyisoprene-Polystyrene Diblock Copolymers Near the Order-Disorder Transition

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The Full Phase Behavior for Block Copolymers in Solvents of Varying Selectivity

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Chain Architecture and Asymmetry in Copolymer Microphases

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Phase Behavior of a Block Copolymer in Solvents of Varying Selectivity

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Electrochemical Surface Science

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Block Copolymer-Directed Assembly of Nanoparticles: Forming Mesoscopically Ordered Hybrid Materials

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Stability of the Perforated Layer (PL) Phase in Diblock Copolymer Melts

Hajduk, D. A., Takenouchi, H., Hillmyer, M. A., Bates, F. S., Vigild, M. E., & Almdal, K. (1997) · Macromolecules · doi:10.1021/ma961673y · Cited by 281

Theory of microphase separation in graft and star copolymers

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Epitaxial Relationship for Hexagonal-to-Cubic Phase Transition in a Book Copolymer Mixture

Schulz, M. F., Bates, F. S., Almdal, K., & Mortensen, K. (1994) · Physical Review Letters · doi:10.1103/physrevlett.73.86 · Cited by 273

Block Copolymer−Ceramic Hybrid Materials from Organically Modified Ceramic Precursors

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Morphology and rheology of polystyrene nanocomposites based upon organoclay

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Conformationally asymmetric block copolymers

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Determination of the Micelle Architecture of Polystyrene/Poly(4-vinylpyridine) Block Copolymers in Dilute Solution

Antonietti, M., Heinz, S., Schmidt, M., & Rosenauer, C. (1994) · Macromolecules · doi:10.1021/ma00090a021 · Cited by 246

A Noncubic Triply Periodic Network Morphology in Poly(isoprene-b-styrene-b-ethylene oxide) Triblock Copolymers

Bailey, T. S., Hardy, C. M., Epps, T. H., & Bates, F. S. (2002) · Macromolecules · doi:10.1021/ma011716x · Cited by 244

Discovering New Ordered Phases of Block Copolymers

Bohbot‐Raviv, Y., & Wang, Z. (2000) · Physical Review Letters · doi:10.1103/physrevlett.85.3428 · Cited by 239

Transformations to and from the Gyroid Phase in a Diblock Copolymer

Vigild, M. E., Almdal, K., Mortensen, K., et al. (1998) · Macromolecules · doi:10.1021/ma9716746 · Cited by 233

Ordered Network Phases in Linear Poly(isoprene-b-styrene-b-ethylene oxide) Triblock Copolymers

Epps, T. H., Cochran, E. W., Bailey, T. S., Waletzko, R. S., Hardy, C. M., & Bates, F. S. (2004) · Macromolecules · doi:10.1021/ma048762s · Cited by 225

Micellar structure and mechanical properties of block copolymer‐modified epoxies

Dean, J. M., Lipic, P. M., Grubbs, R. B., Cook, R. F., & Bates, F. S. (2001) · Journal of Polymer Science Part B: Polymer Physics · doi:10.1002/polb.10062 · Cited by 224

Chemistry and Mechanical Properties of Epoxy-Based Thermosets Reinforced by Reactive and Nonreactive SBMX Block Copolymers

Rebizant, V., Venet, A.-S., Tournilhac, F., Girard-Reydet, E., Navarro, C., Pascault, J.-P., & Leibler, L. (2004) · Macromolecules · doi:10.1021/ma0490754 · Cited by 222

Synthesis and morphology of ABC heteroarm star terpolymers of polystyrene, polybutadiene and poly(2-vinylpyridine)

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Non-centrosymmetric superlattices in block copolymer blends

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Core−Shell Gyroid Morphology in a Poly(isoprene-block-styrene-block-dimethylsiloxane) Triblock Copolymer

Shefelbine, T. A., Vigild, M. E., Matsen, M. W., Hajduk, D. A., Hillmyer, M. A., Cussler, E. L., & Bates, F. S. (1999) · Journal of the American Chemical Society · doi:10.1021/ja991442h · Cited by 207

Isothermal morphology diagrams for binary blends of diblock copolymer and homopolymer

Winey, K. I., Thomas, E. L., & Fetters, L. J. (1992) · Macromolecules · doi:10.1021/ma00036a014 · Cited by 206

Phase Behavior of Polystyrene−Poly(2-vinylpyridine) Diblock Copolymers

Schulz, M. F., Khandpur, A. K., Bates, F. S., Almdal, K., Mortensen, K., Hajduk, D. A., & Gruner, S. M. (1996) · Macromolecules · doi:10.1021/ma951714a · Cited by 202

Gyroid versus double-diamond in ABC triblock copolymer melts

Matsen, M. W. (1998) · The Journal of Chemical Physics · doi:10.1063/1.475439 · Cited by 199

Epitaxial growth and shearing of the body centered cubic phase in diblock copolymer melts

Koppi, K. A., Tirrell, M., Bates, F. S., Almdal, K., & Mortensen, K. (1994) · Journal of Rheology · doi:10.1122/1.550600 · Cited by 182

Equilibrium behavior of asymmetric ABA triblock copolymer melts

Matsen, M. W. (2000) · The Journal of Chemical Physics · doi:10.1063/1.1289889 · Cited by 181

Three-Dimensionally Packed Nanohelical Phase in Chiral Block Copolymers

Ho, R.-M., Chiang, Y.-W., Tsai, C.-C., Lin, C.-C., Ko, B.-T., & Huang, B.-H. (2004) · Journal of the American Chemical Society · doi:10.1021/ja039627i · Cited by 178

Reactive Tetrablock Copolymers Containing Glycidyl Methacrylate. Synthesis and Morphology Control in Epoxy−Amine Networks

Rebizant, V., Abetz, V., Tournilhac, F., et al. (2003) · Macromolecules · doi:10.1021/ma0347565 · Cited by 171

Structural Characterization of the “Knitting Pattern” in Polystyrene-block-poly(ethylene-co-butylene)-block-poly(methyl methacrylate) Triblock Copolymers

Breiner, U., Krappe, U., Thomas, E. L., & Stadler, R. (1998) · Macromolecules · doi:10.1021/ma961550d · Cited by 170

Morphological Behavior Bridging the Symmetric AB and ABC States in the Poly(styrene-b-isoprene-b-ethylene oxide) Triblock Copolymer System

Bailey, T. S., Pham, H. D., & Bates, F. S. (2001) · Macromolecules · doi:10.1021/ma0103371 · Cited by 168

Observation of a non-constant mean curvature interface in an ABC triblock copolymer

Gido, S. P., Schwark, D. W., Thomas, E. L., & Gonçalves, M. D. C. (1993) · Macromolecules · doi:10.1021/ma00062a040 · Cited by 166

Phase Behavior and Block Sequence Effects in Lithium Perchlorate-Doped Poly(isoprene-b-styrene-b-ethylene oxide) and Poly(styrene-b-isoprene-b-ethylene oxide) Triblock Copolymers

Epps, T. H. I., Bailey, T. S., Waletzko, R. S., & Bates, F. S. (2003) · Macromolecules · doi:10.1021/ma021231o · Cited by 164

Structural transitions from spherical to nonspherical micelles in blends of poly(styrene-butadiene) diblock copolymer and polystyrene homopolymers

Kinning, D. J., Winey, K. I., & Thomas, E. L. (1988) · Macromolecules · doi:10.1021/ma00190a027 · Cited by 161

Interfaces in Diblocks: A Study of Miktoarm Star Copolymers

Grason, G. M., & Kamien, R. D. (2004) · Macromolecules · doi:10.1021/ma049255d · Cited by 160

Poly(ethylene oxide-b-isoprene) Diblock Copolymer Phase Diagram

Floudas, G. A., Vazaiou, B., Schipper, F., Ulrich, R., Wiesner, U. B., Iatrou, H., & Hadjichristidis, N. (2001) · Macromolecules · doi:10.1021/ma001957p · Cited by 157

Network Phases in ABC Triblock Copolymers

Epps, T. H. I., Cochran, E. W., Hardy, C. M., Bailey, T. S., Waletzko, R. S., & Bates, F. S. (2004) · Macromolecules · doi:10.1021/ma0493426 · Cited by 152

Phase Behavior of Block Copolymers in a Neutral Solvent

Lodge, T. P., Hanley, K. J., Pudil, B., & Alahapperuma, V. (2003) · Macromolecules · doi:10.1021/ma0209601 · Cited by 148

Self-consistent field theory of block copolymers with conformational asymmetry

Vavasour, J. D., & Whitmore, M. D. (1993) · Macromolecules · doi:10.1021/ma00077a054 · Cited by 146

Thin Film Morphologies of ABC Triblock Copolymers Prepared from Solution

Elbs, H., Drummer, C., Abetz, V., & Krausch, G. (2002) · Macromolecules · doi:10.1021/ma011734e · Cited by 142

Tricontinuous morphology of triblock copolymers of the ABC type

Mogi, Y., Mori, K., Matsushita, Y., & Noda, I. (1992) · Macromolecules · doi:10.1021/ma00046a044 · Cited by 139

Microdomain Morphology of Thin ABC Triblock Copolymer Films

Elbs, H., Fukunaga, K., Stadler, R., Sauer, G., Magerle, R., & Krausch, G. (1999) · Macromolecules · doi:10.1021/ma981321m · Cited by 136

Microphases of a Diblock Copolymer with Conformational Asymmetry

Matsen, M. W., & Michael Schick, C. (1994) · Macromolecules · doi:10.1021/ma00092a049 · Cited by 128

Cryo-TEM Imaging the Flow-Induced Transition from Vesicles to Threadlike Micelles

Zheng, Y., Lin, Z., Zakin, J. L., Talmon, Y., Davis, H. T., & Scriven, L. E. (2000) · The Journal of Physical Chemistry B · doi:10.1021/jp0002998 · Cited by 123

Theory of phase equilibria in block copolymer-homopolymer blends

Whitmore, M. D., & Noolandi, J. (1985) · Macromolecules · doi:10.1021/ma00154a024 · Cited by 120

Nano-objects with Controlled Shape, Size, and Composition from Block Copolymer Mesophases

Ulrich, R., Chesne, A. D., Templin, M., & Wiesner, U. B. (1999) · Advanced Materials · Cited by 118

Closed-loop phase behaviour in block copolymers

Ryu, D. Y., Jeong, U., Kim, J. K., & Russell, T. P. (2002) · Nature Materials · doi:10.1038/nmat724 · Cited by 117

Transition Mechanisms for Complex Ordered Phases in Block Copolymer Melts

Hajduk, D. A., Ho, R., Hillmyer, M. A., Bates, F. S., & Almdal, K. (1998) · The Journal of Physical Chemistry B · doi:10.1021/jp972871+ · Cited by 112

Kinetics and Mechanisms for the Cylinder-to-Gyroid Transition in a Block Copolymer Solution

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Rheology and Shear-Induced Alignment of Lamellar Diblock and Triblock Copolymers

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Effect of Composition Distribution on Microphase-Separated Structure from Diblock Copolymers

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Order−Order Phase Transition between Spherical and Cylindrical Microdomain Structures of Block Copolymer. I. Mechanism of the Transition

Kimishima, K., Koga, T., & Hashimoto, T. (2000) · Macromolecules · doi:10.1021/ma991470k · Cited by 108

Phase Behavior of Lithium Perchlorate-Doped Poly(styrene-b-isoprene-b-ethylene oxide) Triblock Copolymers

Epps, T. H. I., Bailey, T. S., Pham, H. D., & Bates, F. S. (2002) · Chemistry of Materials · doi:10.1021/cm010971t · Cited by 106

Microphase separation in poly(isoprene-b-ethylene oxide) diblock copolymer melts. I. Phase state and kinetics of the order-to-order transitions

Floudas, G. A., Ulrich, R., & Wiesner, U. B. (1999) · The Journal of Chemical Physics · doi:10.1063/1.478122 · Cited by 106

Influence of the block sequence on the morphological behavior of ABC triblock copolymers

Hückstädt, H., Göpfert, A., & Abetz, V. (2000) · Polymer · doi:10.1016/s0032-3861(00)00290-1 · Cited by 105

Bridging and looping in multiblock copolymer melts

Matsen, M. W. (1995) · The Journal of Chemical Physics · doi:10.1063/1.468548 · Cited by 104

Evolution of the “knitting pattern” morphology in ABC triblock copolymers

Breiner, U., Krappe, U., & Stadler, R. (1996) · Macromolecular Rapid Communications · doi:10.1002/marc.1996.030170810 · Cited by 100

Microphase Separation in Star Block Copolymers of Styrene and Isoprene. Theory, Experiment, and Simulation

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Effect of Hydrostatic Pressure on Closed-Loop Phase Behavior of Block Copolymers

Ryu, D. Y., Lee, D. J., Kim, J. K., Lavery, K. A., Russell, T. P., Han, Y. S., Seong, B. S., Lee, C., & Thiyagarajan, P. (2003) · Physical Review Letters · doi:10.1103/physrevlett.90.235501 · Cited by 95

The Order−Disorder Transition and the Disordered Micelle Regime in Sphere-Forming Block Copolymer Melts

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Microphase separation of block copolymer rings

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Self-Assembly of a Lamellar ABC Triblock Copolymer Thin Film

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Lattice Disordering/Ordering and Demicellization/Micellization Transitions in Highly Asymmetric Polystyrene-block-Polyisoprene Copolymers

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Polymer alloys based on poly(2,6-dimethyl-1,4-phenylene ether) and poly(styrene-co-acrylonitrile) using poly(styrene-b-(ethylene-co-butylene)-b-methyl methacrylate) triblock copolymers as compatibilizers

Auschra, C., & Stadler, R. (1993) · Macromolecules · doi:10.1021/ma00076a011 · Cited by 87

Perfectly‐alternating linear (AB)nmultiblock copolymers: Effect of molecular design on morphology and properties

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Immiscibility of large and small symmetric diblock copolymers

Matsen, M. W. (1995) · The Journal of Chemical Physics · doi:10.1063/1.470260 · Cited by 82

One-Component Approximation for Binary Diblock Copolymer Blends

Matsen, M. W., & Bates, F. S. (1995) · Macromolecules · doi:10.1021/ma00125a041 · Cited by 82

Synthesis, Characterization, and Interaction Strengths of Difluorocarbene-Modified Polystyrene−Polyisoprene Block Copolymers

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Microphase Separation in Model 3-MiktoarmStar Copolymers (Simple Graft and Terpolymers). 1. Statics and Kinetics

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Ordered melts of block copolymers of ethylene oxide and 1,2-butylene oxide

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Thermodynamic Stability and Anisotropic Fluctuations in the Cylinder-to-Sphere Transition of a Block Copolymer

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Morphological Studies of Binary Mixtures of Block Copolymers. 1. Cosurfactant Effects and Composition Dependence of Morphology

Court, F., & Hashimoto, T. (2001) · Macromolecules · doi:10.1021/ma001314+ · Cited by 74

The Order−Disorder Transition and the Disordered Micelle Regime for Poly(ethylenepropylene- b -dimethylsiloxane) Spheres

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Preparation and Morphology of Ring-Shaped Polystyrene-block-polyisoprenes

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Synthesis and Morphological Behavior of Model Linear and Miktoarm Star Copolymers of 2-Methyl-1,3-Pentadiene and Styrene

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Core−Shell Double Gyroid Morphologies in ABC Triblock Copolymers with Different Chain Topologies

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A Phase Diagram for the Binary Blends of Nearly Symmetric Diblock Copolymers. 1. Parameter Space of Molecular Weight Ratio and Blend Composition

Yamaguchi, D., & Hashimoto, T. (2001) · Macromolecules · doi:10.1021/ma0021489 · Cited by 70

Lattice Disordering and Domain Dissolution Transitions in Polystyrene-block-poly(ethylene-co-but-1-ene)-block-polystyrene Triblock Copolymer Having a Highly Asymmetric Composition

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Block copolymer modified novolac epoxy resin

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Determination of Order−Order and Order−Disorder Transition Temperatures of SIS Block Copolymers by Differential Scanning Calorimetry and Rheology

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Microphase Separation of Linear and Cyclic Block Copolymers Poly(styrene- b -isoprene): SAXS Experiments

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Self-Diffusion and Tracer Diffusion in Sphere-Forming Block Copolymers

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I5S Miktoarm Star Block Copolymers: Packing Constraints on Morphology and Discontinuous Chevron Tilt Grain Boundaries

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Microphase Separation in Poly(oxyethylene)−Poly(oxybutylene) Diblock Copolymers

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Influence of conformational asymmetry on polymer-polymer interactions: An entropic or enthalpic effect?

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Molecular characterization of poly(2-methyl-1,3-pentadiene) and its hydrogenated derivative, atactic polypropylene

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Light-Scattering Studies of a Polystyrene-Poly(methyl methacrylate) Two-Block Copolymer in Mixed Solvents

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Morphological behavior of model poly(ethylene‐alt‐propylene)‐b‐polylactide diblock copolymers

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Morphological Studies of Poly(styrene)-block-poly(ethylene-co-butylene)-block-poly(methyl methacrylate) in the Composition Region of the “Knitting Pattern” Morphology§

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Four-Phase Triple Coaxial Cylindrical Microdomain Morphology in a Linear Tetrablock Quaterpolymer of Styrene, Isoprene, Dimethylsiloxane, and 2-Vinylpyridine

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Morphology, Dynamic Mechanical Properties, and Phase Behavior of ABC-Triblock Copolymers with Two Semicompatible Elastomer Blocks

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Persistence of the Gyroid Morphology at Strong Segregation in Diblock Copolymers

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