Novel macromolecular architectures based on aliphatic polyesters: relevance of the coordination- insertion ring-opening polymerization
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Aluminum alkoxide initiators can polymerize other cyclic monomers such as adipic anhydride and trimethylene carbonate.
“This type of initiator can also polymerize other cyclic monomers, such as adipic anhydride and trimethylene carbonate [9]”
From Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization☆ (2008) · cites this paper as [9]
The available indexed passages (ORBi record, no page number) discuss ring-opening polymerization and tin alkoxide initiators, but do not address aluminum alkoxide initiators polymerizing adipic anhydride or trimethylene carbonate. Searches for both named monomers and aluminum alkoxide initiators found no passage establishing the claim. (LLM, conf=0.72)
Experimental — accuracy not yet measuredThe very good control imparted by aluminum alkoxides is a unique platform for macromolecular engineering of aliphatic polyesters, making comb-like, star-shaped, graft and hyperbranched (co)polyesters available.
“The very good control imparted to ring-opening polymerization by aluminum alkoxides is a unique platform for the macromolecular engineering of aliphatic polyesters, for instance, making comb-like, star-shaped, graft and hyperbranched (co)polyesters available [9].”
From Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization☆ (2008) · cites this paper as [9]
The indexed material identifies the cited paper in a publication-record section (Advances in Polymer Science, vol. 147, pp. 1–59), but the retrieved passages do not provide its discussion of aluminum alkoxides. Searches for aluminum alkoxides and for the listed comb-like, star-shaped, graft, and hyperbranched architectures found no passage from the cited paper that establishes the claim; passages describing some architectures belong to other publications listed nearby. (LLM, conf=0.72)
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Cites
Wang, J.-S., & Matyjaszewski, K. (1995) · Journal of the American Chemical Society · doi:10.1021/ja00125a035 · Cited by 4,622 · see citing works
Lewis acid catalyzed polymerization of L-lactide. Kinetics and mechanism of the bulk polymerization
Nijenhuis, A. J., Grijpma, D. W., & Pennings, A. J. (1992) · Macromolecules · doi:10.1021/ma00050a006 · Cited by 407 · see citing works
Highly reactive yttrium alkoxide as new initiator for the polymerization of β‐butyrolactone
Borgne, A. L., Pluta, C., & Spassky, N. (1994) · Macromolecular Rapid Communications · doi:10.1002/marc.1994.030151208 · Cited by 72 · see citing works
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Research works printed but not linked: 2
- Yamashita Y, McGrath JE (eds) (1981) Anionic polymerization: kinetics, mechamism and synthesis, ACS Symposium Series 66:199
- Kricheldorf HR, Kreiser-Saunders I, Scharnagl N (1992) Makromol Chem Macromol Symp 32:285
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Controlled Ring-Opening Polymerization of Lactide and Glycolide
Dechy-Cabaret, O., Martin-Vaca, B., & Bourissou, D. (2004) · Chemical Reviews · doi:10.1021/cr040002s · Cited by 2,257 · see citing works
Recent Developments in Ring Opening Polymerization of Lactones for Biomedical Applications
Albertsson, A.-C., & Varma, I. K. (2003) · Biomacromolecules · doi:10.1021/bm034247a · Cited by 1,582 · see citing works
Hong, M., & Chen, E. Y.-X. (2016) · Nature Chemistry · doi:10.1038/nchem.2391 · Cited by 677 · see citing works
Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization☆
JEROME, C., & LECOMTE, P. (2008) · Advanced Drug Delivery Reviews · doi:10.1016/j.addr.2008.02.008 · Cited by 590 · see citing works
Synthesis of Poly(Lactic Acid): A Review
Mehta, R., Kumar, V., Bhunia, H., & Upadhyay, S. N. (2005) · Journal of Macromolecular Science, Part C: Polymer Reviews · doi:10.1080/15321790500304148 · Cited by 510 · see citing works
Mechanisms and Kinetics of Thermal Degradation of Poly(ε-caprolactone)
Persenaire, O., Alexandre, M., Degée, P., & Dubois, P. (2001) · Biomacromolecules · doi:10.1021/bm0056310 · Cited by 444 · see citing works
Self-citationMetal catalysts for ε-caprolactone polymerisation
Arbaoui, A., & Redshaw, C. (2010) · Polymer Chemistry · doi:10.1039/b9py00334g · Cited by 383 · see citing works
Controlled Ring-Opening Polymerization: Polymers with designed Macromolecular Architecture
Stridsberg, K. M., Ryner, M., & Albertsson, A.-C. (2002) · Advances in Polymer Science · doi:10.1007/3-540-45734-8_2 · Cited by 375 · see citing works
Tang, X., Hong, M., Falivene, L., Caporaso, L., Cavallo, L., & Chen, E. Y.-X. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b07974 · Cited by 179 · see citing works
Florczak, M., & Duda, A. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200803540 · Cited by 94 · see citing works
Branched aliphatic polyesters by ring-opening (co)polymerization
Bednarek, M. (2016) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2016.02.002 · Cited by 79 · see citing works
Wang, J., & Dong, C. (2006) · Macromolecular Chemistry and Physics · doi:10.1002/macp.200500546 · Cited by 76 · see citing works
Wang, J.-L., & Dong, C.-M. (2006) · Polymer · doi:10.1016/j.polymer.2006.02.047 · Cited by 64 · see citing works
Zhang, S., Yang, J., Liu, X., Chang, J., & Cao, A. (2003) · Biomacromolecules · doi:10.1021/bm0201183 · Cited by 62 · see citing works
Florczak, M., Libiszowski, J., Mosnacek, J., Duda, A., & Penczek, S. (2007) · Macromolecular Rapid Communications · doi:10.1002/marc.200700160 · Cited by 57 · see citing works
Low-Temperature Processable Degradable Polyesters
Taniguchi, I., & Lovell, N. G. (2012) · Macromolecules · doi:10.1021/ma301230y · Cited by 33 · see citing works
Synthetic biodegradable medical polyesters
Cama, G., Mogosanu, D. E., Houben, A., & Dubruel, P. (2017) · Science and Principles of Biodegradable and Bioresorbable Medical Polymers · doi:10.1016/b978-0-08-100372-5.00003-9 · Cited by 33 · see citing works
Ma, W.-A., Wang, L., & Wang, Z.-X. (2011) · Dalton Transactions · doi:10.1039/c0dt01713b · Cited by 29 · see citing works
Initiation of ring-opening polymerization of lactide: The effect of metal alkoxide catalyst
Cheshmedzhieva, D., Angelova, I., Ilieva, S., Georgiev, G. S., & Galabov, B. (2012) · Computational and Theoretical Chemistry · doi:10.1016/j.comptc.2012.06.015 · Cited by 27 · see citing works
Valente, A., Zinck, P., Mortreux, A., Visseaux, M., Mendes, P. J. G., Silva, T. J. L., & Garcia, M. H. (2011) · Journal of Molecular Catalysis A: Chemical · doi:10.1016/j.molcata.2011.06.015 · Cited by 9 · see citing works
- Authors
- Mecerreyes, D., Jérôme, R., & Dubois, P.
- Affiliations
- University of Liège (BE)
- ORCID
- Mecerreyes, David
- Venue
- Advances in Polymer Science
- Publisher
- Springer Berlin Heidelberg
- Published
- 2007-10-09
- Pages
- 1-59
- OpenAlex
- W141053126
- Cited by
- 272
- References
- 3
- Citations by year
- 2025: 1 · 2024: 4 · 2023: 1 · 2022: 1 · 2021: 5 · 2020: 3 · 2019: 5 · 2018: 9 · 2017: 9 · 2016: 12 · 2015: 11 · 2014: 11 · 2013: 12 · 2012: 17
- FWCI
- 62.21
- Type
- book chapter
- Language
- en
- Open access
- green
- orbi.uliege.be
- Licence
- other-oa
- Locations
- Springer eBooks (publishedVersion)
- ORBi (University of Liège) (submittedVersion, other-oa)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Keywords
- aliphatic polyesters, living ring-opening polymerization, coordination-insertion mechanism, aluminum alkoxide, lactones, lactide, glycolide, telechelic polymers, block copolymers, random copolymers, macromolecular architecture, anionic polymerization, cationic polymerization, radical polymerization, metathesis polymerization, polycondensation, biomedical materials, microelectronics materials
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