Effect of the Configuration of the Active Center on Comonomer Reactivities: The Case of ε‐Caprolactone/ l,l‐Lactide Copolymerization

Biodegradable polymers as biomaterials

Nair, L. S., & Laurencin, C. T. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2007.05.017 · Cited by 4,416 · see citing works

Organocatalytic Ring-Opening Polymerization

Kamber, N. E., Jeong, W., Waymouth, R. M., Pratt, R. C., Lohmeijer, B. G. G., & Hedrick, J. L. (2007) · Chemical Reviews · doi:10.1021/cr068415b · Cited by 1,489 · see citing works

Polymerization of lactide and related cyclic esters by discrete metal complexes

O'Keefe, B. J., Hillmyer, M. A., & Tolman, W. B. (2001) · Journal of the Chemical Society, Dalton Transactions · doi:10.1039/b104197p · Cited by 825 · see citing works

Stereochemistry of Lactide Polymerization with Chiral Catalysts:  New Opportunities for Stereocontrol Using Polymer Exchange Mechanisms

Ovitt, T. M., & Coates, G. W. (2002) · Journal of the American Chemical Society · doi:10.1021/ja012052+ · Cited by 713 · see citing works

Highly stereoelective polymerization of <i>rac</i>‐(<scp>D</scp>,<scp>L</scp>)‐lactide with a chiral schiff's base/aluminium alkoxide initiator

Spassky, N., Wisniewski, M., Pluta, C., & Le Borgne, A. (1996) · Macromolecular Chemistry and Physics · doi:10.1002/macp.1996.021970902 · Cited by 627 · see citing works

Controlled and Stereoselective Polymerization of Lactide: Kinetics, Selectivity, and Microstructures

Zhong, Z., Dijkstra, P. J., & Feijén, J. (2003) · Journal of the American Chemical Society · doi:10.1021/ja0347585 · Cited by 503 · see citing works

Stereoselective Ring-Opening Polymerization of Racemic Lactide Using Aluminum-Achiral Ligand Complexes: Exploration of a Chain-End Control Mechanism

Nomura, N., Ishii, R., Akakura, M., & Aoi, K. (2002) · Journal of the American Chemical Society · doi:10.1021/ja0175789 · Cited by 478 · see citing works

Polymerization of l , l -Lactide Initiated by Aluminum Isopropoxide Trimer or Tetramer

Kowalski, A., Duda, A., & Penczek, S. (1998) · Macromolecules · doi:10.1021/ma971737k · Cited by 470 · see citing works

Ring‐Opening Polymerization of Lactide with Group 3 Metal Complexes Supported by Dianionic Alkoxy‐Amino‐Bisphenolate Ligands: Combining High Activity, Productivity, and Selectivity

Amgoune, A., Thomas, C. M., Roisnel, T., & Carpentier, J. (2005) · Chemistry - A European Journal · doi:10.1002/chem.200500856 · Cited by 424 · see citing works

Stereoselective Ring‐Opening Polymerization of a Racemic Lactide by Using Achiral Salen– and Homosalen–Aluminum Complexes

Nomura, N., Ishii, R., Yamamoto, Y., & Kondo, T. (2007) · Chemistry - A European Journal · doi:10.1002/chem.200601308 · Cited by 410 · see citing works

Stereoselective Polymerization of a Racemic Monomer with a Racemic Catalyst:  Direct Preparation of the Polylactic Acid Stereocomplex from Racemic Lactide

Radano, C. P., Baker, G. L., & Smith, M. R. (2000) · Journal of the American Chemical Society · doi:10.1021/ja9930519 · Cited by 403 · see citing works

From controlled ring-opening polymerization to biodegradable aliphatic polyester: Especially poly(β-malic acid) derivatives

Coulembier, O., Degée, P., Hedrick, J. L., & Dúbois, P. (2006) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.08.004 · Cited by 374 · see citing works

Kinetics and mechanism of cyclic esters polymerization initiated with tin(II) octoate, 1. Polymerization ofη-caprolactone

Kowalski, A., Duda, A., & Penczek, S. (1998) · Macromolecular Rapid Communications · doi:10.1002/(sici)1521-3927(19981101)19:11 · Cited by 290 · see citing works

Group 4 Complexes with Aminebisphenolate Ligands and Their Application for the Ring Opening Polymerization of Cyclic Esters

Chmura, A. J., Davidson, M. G., Jones, M. D., Lunn, M. D., Mahon, M. F., Johnson, A. F., Khunkamchoo, P., Roberts, S. L., & Wong, S. S. F. (2006) · Macromolecules · doi:10.1021/ma061028j · Cited by 277 · see citing works

Novel macromolecular architectures based on aliphatic polyesters: relevance of the coordination- insertion ring-opening polymerization

Mecerreyes, D., Jérôme, R., & Dubois, P. (2007) · Advances in Polymer Science · doi:10.1007/3-540-49196-1_1 · Cited by 272 · see citing works

Polymerization of l , l -Dilactide Initiated by Tin(II) Butoxide

Kowalski, A., Libiszowski, J., Duda, A., & Penczek, S. (2000) · Macromolecules · doi:10.1021/ma991751s · Cited by 271 · see citing works

Stereocontrolled Polymerization of Racemic Lactide with Chiral Initiator: Combining Stereoelection and Chiral Ligand-Exchange Mechanism

Majerska, K., & Duda, A. (2004) · Journal of the American Chemical Society · doi:10.1021/ja0388966 · Cited by 247 · see citing works

Macromolecular engineering of polylactones and polylactides. 5. Synthesis and characterization of diblock copolymers based on poly-iε-caprolactone and poly(L,L or D,L)lactide by aluminum alkoxides

Jacobs, C., Dúbois, P., Jérôme, R., & Teyssié, P. (1991) · Macromolecules · doi:10.1021/ma00011a001 · Cited by 218 · see citing works

Thermodynamics of L-lactide polymerization. Equilibrium monomer concentration

Duda, A., & Penczek, S. (1990) · Macromolecules · doi:10.1021/ma00208a012 · Cited by 197 · see citing works

Macromolecular engineering of polylactones and polylactides. 7. Structural analysis of copolyesters of iε-caprolactone and L- or D,L-lactide initiated by triisopropoxyaluminum

Vanhoorne, P., Dúbois, P., Jérôme, R., & Teyssié, P. (1992) · Macromolecules · doi:10.1021/ma00027a008 · Cited by 184 · see citing works

Morphology of Elastic Poly(<scp>l</scp>-lactide-<i>co</i>-ε-caprolactone) Copolymers and in Vitro and in Vivo Degradation Behavior of Their Scaffolds

Jeong, S. I., Kim, B.-S., Lee, Y. M., Ihn, K. J., Kim, S. H., & Kim, Y. H. (2004) · Biomacromolecules · doi:10.1021/bm049921i · Cited by 182 · see citing works

Synthesis, characterization, and miscibility of caprolactone random copolymers

Vion, J. M., Jérôme, R., Teyssié, P., Aubin, M., & Prud'homme, R. E. (1986) · Macromolecules · doi:10.1021/ma00161a009 · Cited by 162 · see citing works

Synthesis and properties of ( D )‐ and ( L )‐lactide stereocopolymers using the system achiral Schiff's base/aluminium methoxide as initiator

Wisniewski, M., Borgne, A. L., & Spassky, N. (1997) · Macromolecular Chemistry and Physics · doi:10.1002/macp.1997.021980424 · Cited by 162 · see citing works

Coordination polymerization of lactides, 4. The role of transesterification in the copolymerization of L , L ‐lactide and ε‐caprolactone

Kasperczyk, J., & Bero, M. (1993) · Die Makromolekulare Chemie · doi:10.1002/macp.1993.021940315 · Cited by 156 · see citing works

Novel Rare Earth Catalysts for the Living Polymerization and Block Copolymerization of ε-Caprolactone

Shen, Y., Shen, Z., Zhang, Y., & Yao, K. (1996) · Macromolecules · doi:10.1021/ma9518060 · Cited by 152 · see citing works

Coordination polymerization of lactides, 2. Microstructure determination of poly[( L , L ‐lactide)‐ co ‐(ε‐caprolactone)] with 13 C nuclear magnetic resonance spectroscopy

Kasperczyk, J., & Bero, M. (1991) · Die Makromolekulare Chemie · doi:10.1002/macp.1991.021920812 · Cited by 133 · see citing works

Coordination polymerization of lactides, 3. Copolymerization of <scp>L</scp>,<scp>L</scp>‐lactide and ε‐caprolactone in the presence of initiators containing Zn and Al

Bero, M., Kasperczyk, J., & Adamus, G. (1993) · Die Makromolekulare Chemie · doi:10.1002/macp.1993.021940314 · Cited by 125 · see citing works

Ring‐opening oligomerization reactions using aluminium complexes of schiff's bases as initiators

Borgne, A. L., Vincens, V., Jouglard, M., & Spassky, N. (1993) · Makromolekulare Chemie Macromolecular Symposia · doi:10.1002/masy.19930730106 · Cited by 101 · see citing works

Well defined block copolymers of ε‐caprolactone and L ‐lactide using Y5(μ‐O)(OiPr)13 as an initiator

Stevels, W. M., Ankoné, M. J. K., Dijkstra, P. J., & Feijén, J. (1995) · Macromolecular Chemistry and Physics · doi:10.1002/macp.1995.021960415 · Cited by 96 · see citing works

Synthesis of ABA triblock copolymers of iε-caprolactone and DL-lactide

Song, C. X., & Feng, X. D. (1984) · Macromolecules · doi:10.1021/ma00142a057 · Cited by 88 · see citing works

On the difference of reactivities of various aggregated forms of aluminium triisopropoxide in initiating ring‐opening polymerizations

Duda, A., & Penczek, S. (1995) · Macromolecular Rapid Communications · doi:10.1002/marc.1995.030160112 · Cited by 75 · see citing works

<scp>L,L</scp>‐Lactide and <i>ε</i>‐Caprolactone Block Copolymers by a ‘Poly(<scp>L,L</scp>‐lactide) Block First’ Route

Florczak, M., Libiszowski, J., Mosnacek, J., Duda, A., & Penczek, S. (2007) · Macromolecular Rapid Communications · doi:10.1002/marc.200700160 · Cited by 57 · see citing works

Controlled synthesis of vinylmethylsiloxane–dimethylsiloxane gradient, block and alternate copolymers by anionic ROP of cyclotrisiloxanes

Chojnowski, J., Cypryk, M., Fortuniak, W., Rózga‐Wijas, K., & Šcibiorek, M. (2002) · Polymer · doi:10.1016/s0032-3861(01)00793-5 · Cited by 55 · see citing works

Synthesis and characterization of biodegradable block copolymers of ?-caprolactone and D,L-lactide initiated by potassium poly(ethylene glycol)ate

Deng, X., Zhu, Z., Xiong, C., & Zhang, L. (1997) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/(sici)1099-0518(199703)35:4 · Cited by 54 · see citing works

Stereocomplex formation in enantiomeric diblock and triblock copolymers of poly (ε-caprolactone) and polylactide

Pensec, S., Leroy, M., Akkouche, H., & Spassky, N. (2000) · Polymer Bulletin · doi:10.1007/s002890070010 · Cited by 49 · see citing works

Polymerization of (L,L)‐lactide and copolymerization with ϵ‐caprolactone initiated by dibutyltin dimethoxide in supercritical carbon dioxide

Stassin, F., & Jérôme, R. (2005) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.20735 · Cited by 41 · see citing works

l-Lactide homopolymerization and l-lactide-ε-caprolactone block copolymerization by lanthanide tris(2,4,6-trimethylphenolate)s

Fan, L., Xiong, Y., Xu, H. G., & Shen, Z. (2005) · European Polymer Journal · doi:10.1016/j.eurpolymj.2005.02.008 · Cited by 31 · see citing works

Tetrakis Sn(IV) alkoxides as novel initiators for living ring‐opening polymerization of lactides

Kalmi, M., Lahcini, M., Castro, P. M., Lehtonen, O., Belfkira, A., Leskelä, M. A., & Repo, T. (2004) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.20028 · Cited by 31 · see citing works

Thermodynamics, Kinetics, and Mechanisms of Cyclic Esters Polymerization

Duda, A., & Penczek, S. (2001) · ACS symposium series · doi:10.1021/bk-2000-0764.ch013 · Cited by 28 · see citing works

Ring‐opening polymerization and block copolymerization of L ‐lactide with divalent samarocene complex

Cui, D., Tang, T., Bi, W., Cheng, J., Chen, W., & Huang, B. (2003) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.10814 · Cited by 25 · see citing works

Controlled Synthesis of L-Lactide-b-ε-Caprolactone Block Copolymers Using a Rare Earth Complex as Catalyst

Zhong, Z., Yu, D., Meng, F., Gan, Z., & Jing, X. (1999) · Polymer Journal · doi:10.1295/polymj.31.633 · Cited by 23 · see citing works

Definitions relating to stereochemically asymmetric polymerizations (IUPAC Recommendations 2001)

Hatada, K., Kahovec, J., Barón, M., Horie, K., Kitayama, T., Kubisa, P., Moss, G. P., Stepto, R. F. T., & Wilks, E. S. (2002) · Pure and Applied Chemistry · doi:10.1351/pac200274060915 · Cited by 22 · see citing works

Block Copolymerization of ϵ‐Caprolactone and L ‐Lactide by Lanthanumtris(2,6‐Dimethylphenolate)s

Zhang, L., Shen, Z., Yu, C., & Fan, L. (2004) · Journal of Macromolecular Science Part A · doi:10.1081/ma-120039179 · Cited by 16 · see citing works

Web Site: The Gallery of Sweet Rendezvous

Gabius, H., & Rüdiger, H. E. F. (2002) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20021202)41:23

Untitled work

(2000) · doi:10.1002/1099-0518(200012)38:1+

Biodegradable lactone copolymers. I. Characterization and mechanical behavior of ?-caprolactone and lactide copolymers

Hiljanen-Vainio, M., Karjalainen, T., & Sepp�l�, J. (1996) · Journal of Applied Polymer Science · doi:10.1002/(sici)1097-4628(19960222)59:8

Synthesis and enzymatic hydrolysis of lactic acid-depsipeptide copolymers with functionalized pendant groups

(1997) · doi:10.1002/(sici)1099-0518(19970130)35:2

Random Copolymerization of ε-Caprolactone with Lactide Using a Homosalen−Al Complex

Nomura, N., Akita, A., Ishii, R., & Mizuno, M. (2010) · Journal of the American Chemical Society · doi:10.1021/ja9089395 · Cited by 222 · see citing works

ε-Decalactone: A Thermoresilient and Toughening Comonomer to Poly( l -lactide)

Olsén, P., Borke, T., Odelius, K., & Albertsson, A. (2013) · Biomacromolecules · doi:10.1021/bm400733e · Cited by 128 · see citing works

Exploitation of dinuclear salan aluminum complexes for versatile copolymerization of ε-caprolactone and l-lactide

Wang, Y., & Ma, H. (2012) · Chemical Communications · doi:10.1039/c2cc31716h · Cited by 127 · see citing works

Thermodynamics and Kinetics of Ring‐Opening Polymerization

Duda, A., & Kowalski, A. (2009) · doi:10.1002/9783527628407.ch1 · Cited by 128 · see citing works

Kinetic Investigation on the Catalytic Ring-Opening (Co)Polymerization of (Macro)Lactones Using Aluminum Salen Catalysts

Pepels, M. P. F., Bouyahyi, M., Heise, A., & Duchateau, R. (2013) · Macromolecules · doi:10.1021/ma400731c · Cited by 121 · see citing works

Random Copolymerization of ε-Caprolactone and Lactides Promoted by Pyrrolylpyridylamido Aluminum Complexes

Li, G., Lamberti, M., Pappalardo, D., & Pellecchia, C. (2012) · Macromolecules · doi:10.1021/ma3019848 · Cited by 107 · see citing works

Catalytic metal-based systems for controlled statistical copolymerisation of lactide with a lactone

Stirling, E., Champouret, Y., & Visseaux, M. (2018) · Polymer Chemistry · doi:10.1039/c8py00310f · Cited by 101 · see citing works

Chemistry of magnesium alkyls supported by 1,5,9-trimesityldipyrromethene and 2-[(2,6-diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)imino]pent-2-ene. A comparative study

Chisholm, M. H., Choojun, K., Gallucci, J. C., & Wambua, P. M. (2012) · Chemical Science · doi:10.1039/c2sc21017g · Cited by 94 · see citing works

Ring‐Opening Polymerization of Cyclic Esters by an Enantiopure Heteroscorpionate Rare Earth Initiator

Otero, A., Fernández‐Baeza, J., Lara‐Sánchez, A., Alonso‐Moreno, C., Márquez‐Segovia, I., Sánchez‐Barba, L. F., & Rodrı́guez, A. M. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200806202 · Cited by 92 · see citing works

Chirality-Directed Regioselectivity: An Approach for the Synthesis of Alternating Poly(Lactic- co -Glycolic Acid)

Lu, Y., Swisher, J. H., Meyer, T. Y., & Coates, G. W. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c00248 · Cited by 90 · see citing works

Self-Switchable Polymerization: A Smart Approach to Sequence-Controlled Degradable Copolymers

Hu, C., Pang, X., & Chen, X. (2022) · Macromolecules · doi:10.1021/acs.macromol.2c00085 · Cited by 87 · see citing works

Ring-opening homo- and co-polymerization of lactides and ε-caprolactone by salalen aluminum complexes

Pilone, A., Maio, N. D., Press, K., Venditto, V., Pappalardo, D., Mazzeo, M., Pellecchia, C., Kol, M., & Lamberti, M. (2014) · Dalton Transactions · doi:10.1039/c4dt02616k · Cited by 83 · see citing works

Iminophosphorane Neodymium(III) Complexes As Efficient Initiators for Lactide Polymerization

Buchard, A., Platel, R. H., Auffrant, A., Goff, X. F. L., Floch, P. L., & Williams, C. K. (2010) · Organometallics · doi:10.1021/om1001233 · Cited by 78 · see citing works

Redox Control of Aluminum Ring-Opening Polymerization: A Combined Experimental and DFT Investigation

Wei, J., Riffel, M. N., & Diaconescu, P. L. (2017) · Macromolecules · doi:10.1021/acs.macromol.6b02402 · Cited by 76 · see citing works

Synthesis and characterization of poly (l-lactide/ε-caprolactone) statistical copolymers with well resolved chain microstructures

Fernández, J., Meaurio, E., Chaos, A., Etxeberria, A., Alonso‐Varona, A., & Sarasua, J.-R. (2013) · Polymer · doi:10.1016/j.polymer.2013.03.009 · Cited by 71 · see citing works

Copolymerization of ε-Caprolactone and <scp>l</scp>-Lactide Catalyzed by Multinuclear Aluminum Complexes: An Immortal Approach

Li, L., Liu, B., Liu, D., Wu, C., Li, S., Liu, B., & Cui, D. (2014) · Organometallics · doi:10.1021/om5008264 · Cited by 70 · see citing works

Titanium pyridonates and amidates: novel catalysts for the synthesis of random copolymers

Webster, R. L., Noroozi, N., Hatzikiriakos, S. G., Thomson, J. A., & Schafer, L. L. (2012) · Chemical Communications · doi:10.1039/c2cc37201k · Cited by 67 · see citing works

Ligand Recognition Processes in the Formation of Homochiral C3‐Symmetric LnL3 Complexes of a Chiral Alkoxide

Arnold, P. L., Buffet, J., Blaudeck, R. P., Sujecki, S., & Wilson, C. (2009) · Chemistry - A European Journal · doi:10.1002/chem.200900522 · Cited by 61 · see citing works

Synthesis of Poly(l-lactide-co-ε-caprolactone) Copolymer: Structure, Toughness, and Elasticity

Zhang, M., Chang, Z., Wang, X., & Li, Q. (2021) · Polymers · doi:10.3390/polym13081270 · Cited by 59 · see citing works

Copolymerization of l -lactide and ε-caprolactone catalyzed by mono-and dinuclear salen aluminum complexes bearing bulky 6,6′-dimethylbipheyl-bridge: random and tapered copolymer

Kan, C., & Ma, H. (2016) · RSC Advances · doi:10.1039/c6ra07374c · Cited by 56 · see citing works

Synthesis of biodegradable thermoplastic elastomers from ε‐caprolactone and lactide

Nakayama, Y., Aihara, K., Yamanishi, H., Fukuoka, H., Tanaka, R., Cai, Z., & Shiono, T. (2014) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.27463 · Cited by 53 · see citing works

Copolymerization of Cyclic Esters Controlled by Chiral NNO-Scorpionate Zinc Initiators

Honrado, M., Otero, A., Fernández‐Baeza, J., Sánchez‐Barba, L. F., Garcés, A., Lara‐Sánchez, A., & Rodrı́guez, A. M. (2016) · Organometallics · doi:10.1021/acs.organomet.5b00919 · Cited by 51 · see citing works

Preparation and characterization of bisphenolato magnesium derivatives: an efficient catalyst for the ring-opening polymerization of ε-caprolactone and L-lactide

Shen, M.-Y., Peng, Y., Hung, W., & Lin, C. (2009) · Dalton Transactions · doi:10.1039/b912443h · Cited by 49 · see citing works

Synthesis and structural characterization of titanium and zirconium complexes containing half-salen ligands as catalysts for polymerization reactions

Mandal, M., Monkowius, U. V., & Chakraborty, D. (2016) · New Journal of Chemistry · doi:10.1039/c6nj02148d · Cited by 46 · see citing works

Poly(lactide-co-ε-caprolactone) copolymers prepared using bis-thioetherphenolate group 4 metal complexes: synthesis, characterization and morphology

Monica, F. D., Luciano, E., Buonerba, A., Grassi, A., Milione, S., & Capacchione, C. (2014) · RSC Advances · doi:10.1039/c4ra10255j · Cited by 45 · see citing works

Synthesis and Characterization of Dialkylaluminum Amidates and Their Ring-Opening Polymerization of ε-Caprolactone

Zhang, W., Wang, Y., Cao, J., Wang, L., Pan, Y., Redshaw, C., & Sun, W. (2011) · Organometallics · doi:10.1021/om2008343 · Cited by 45 · see citing works

Ring‐opening polymerization of cyclic esters promoted by phosphido‐diphosphine pincer group 3 complexes

D’Auria, I., Mazzeo, M., Pappalardo, D., Lamberti, M., & Pellecchia, C. (2010) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.24447 · Cited by 44 · see citing works

Controlled random copolymerization of <i>rac</i>‐lactide and <i>ɛ</i>‐caprolactone by well‐designed phenoxyimine Al complexes

Shi, T., Luo, W., Liu, S., & Li, Z. (2018) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.28932 · Cited by 39 · see citing works

β-Pyridylenolate zinc catalysts for the ring-opening homo- and copolymerization of ε-caprolactone and lactides

Bai, J., Xiao, X., Zhang, Y., Chao, J., & Chen, X. (2017) · Dalton Transactions · doi:10.1039/c7dt01877k · Cited by 39 · see citing works

Synthesis of poly(ε-caprolactone)-grafted guar gum by surface-initiated ring-opening polymerization

Assimi, T. E., Blažic, R., Kadib, A. E., Raihane, M., Beniazza, R., Luinstra, G. A., Vidović, E., & Lahcini, M. (2019) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2019.05.049 · Cited by 39 · see citing works

Ring-Opening Polymerization (ROP) of cyclic esters by a versatile aluminum Diphenoxyimine Complex: From polylactide to random copolymers

Garcı́a-Valle, F. M., Cuenca, T., Mosquera, M. E. G., Milione, S., & Cano, J. (2020) · European Polymer Journal · doi:10.1016/j.eurpolymj.2020.109527 · Cited by 38 · see citing works

Bulk Organocatalytic Synthetic Access to Statistical Copolyesters from l -Lactide and ε-Caprolactone Using Benzoic Acid

Mezzasalma, L., Harrisson, S., Saba, S., Loyer, P., Coulembier, O., & Taton, D. (2019) · Biomacromolecules · doi:10.1021/acs.biomac.9b00190 · Cited by 37 · see citing works

Highly Elastic Scaffolds Produced by Melt Electrowriting of Poly(L‐lactide‐co‐ε‐caprolactone)

Díaz, R. S., Park, J., Rodrigues, L. L., Dalton, P. D., De‐Juan‐Pardo, E. M., & Dargaville, T. R. (2021) · Advanced Materials Technologies · doi:10.1002/admt.202100508 · Cited by 37 · see citing works

Microstructure analysis and thermal properties of l-lactide/ɛ-caprolactone copolymers obtained with magnesium octoate

Wei, Z., Liu, L., Qu, C. Y., & Qi, M. (2009) · Polymer · doi:10.1016/j.polymer.2009.01.015 · Cited by 37 · see citing works

Bimetallic Schiff base complexes for stereoselective polymerisation of racemic-lactide and copolymerisation of racemic-lactide with ε-caprolactone

Sun, Z., Duan, R., Yang, J., Zhang, H., Li, S., Pang, X., Chen, W., & Chen, X. (2016) · RSC Advances · doi:10.1039/c6ra00289g · Cited by 35 · see citing works

Cationic copolymerization of racemic -β-butyrolactone with L,L-lactide: One-pot synthesis of block copolymers

Baśko, M., Duda, A., Kaźmierski, S., & Kubisa, P. (2013) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.26916 · Cited by 34 · see citing works

Synthesis and Characterization of Dinuclear Salan Rare-Earth Metal Complexes and Their Application in the Homo- and Copolymerization of Cyclic Esters

Ouyang, H., Yuan, D., Nie, K., Zhang, Y., Yao, Y., & Cui, D. (2018) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.8b01046 · Cited by 34 · see citing works

Use of titanium complexes bearing diphenolate or calix [n]arene ligands in α-olefin polymerization and the ROP of cyclic esters

Santoro, O., & Redshaw, C. (2020) · Catalysts · doi:10.3390/catal10020210 · Cited by 34 · see citing works

Establishing α-bromo-γ-butyrolactone as a platform for synthesis of functional aliphatic polyesters – bridging the gap between ROP and SET-LRP

Olsén, P., Undin, J., Odelius, K., & Albertsson, A. (2014) · Polymer Chemistry · doi:10.1039/c4py00148f · Cited by 33 · see citing works

Monoamidinate titanium complexes: highly active catalysts for the polymerization and copolymerization of l -lactide and ε-caprolactone

Lapenta, R., Mazzeo, M., & Grisi, F. (2015) · RSC Advances · doi:10.1039/c5ra15599a · Cited by 33 · see citing works

Synthesis, Characterization, and Catalytic Studies of (Aryloxido)magnesium Complexes

Ejfler, J., Krauzy-Dziedzic, K., Szafert, S., Jerzykiewicz, L. B., & Sobota, P. (2010) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.200901207 · Cited by 33 · see citing works

Master of Chaos and Order: Opposite Microstructures of PCL‐<i>co</i>‐PGA‐<i>co</i>‐PLA Accessible by a Single Catalyst**

Rittinghaus, R. D., Zenner, J., Pich, A., Kol, M., & Herres‐Pawlis, S. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202112853 · Cited by 32 · see citing works

A DFT study of the ring-opening polymerization mechanism of l-lactide and ε-caprolactone using aluminium salen-type initiators: Towards an understanding of their reactivities in homo- and copolymerization

Chandanabodhi, D., & Nanok, T. (2017) · Molecular Catalysis · doi:10.1016/j.mcat.2017.04.005 · Cited by 31 · see citing works

Harnessing synergies in tin-clay catalyst for the preparation of poly(ε-caprolactone)/halloysite nanocomposites

Lahcini, M., Elhakioui, S., Szopinski, D., Neuer, B., Kadib, A. E., Scheliga, F., Raihane, M., Calleja, F. J. B., & Luinstra, G. A. (2016) · European Polymer Journal · doi:10.1016/j.eurpolymj.2016.05.014 · Cited by 31 · see citing works

Lactide-caprolactone copolymers with tuneable barrier properties for packaging applications

Sangroniz, A., Sangroniz, L., Hamzehlou, S., del Río, J., Santamaría, A., Sarasua, J.-R., Iriarte, M., Leiza, J. R., & Etxeberria, A. (2020) · Polymer · doi:10.1016/j.polymer.2020.122681 · Cited by 29 · see citing works

Comparing l -lactide and ε-caprolactone polymerization by using aluminum complexes bearing ketiminate ligands: steric, electronic, and chelating effects

Chen, Y., Chen, Y., Tseng, H., Lian, C.-J., Tsai, H.-Y., Lai, Y., Hsu, S. C. N., Chiang, M. Y.-N., & Chen, H. (2015) · RSC Advances · doi:10.1039/c5ra15530d · Cited by 27 · see citing works

Selective Transesterification to Control Copolymer Microstructure in the Ring-Opening Copolymerization of Lactide and ε-Caprolactone by Lanthanum Complexes

Beament, B., Britton, D., Malcomson, T., Akien, G. R., Halcovitch, N. R., Coogan, M. P., & Platel, R. H. (2024) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.3c03120 · Cited by 27 · see citing works

Hemi-salen aluminum catalysts bearing N, N, O-tridentate type binaphthyl-Schiff-base ligands for the living ring-opening polymerisation of lactide

Gao, B., Li, X., Duan, R., Duan, Q., Li, Y., Pang, X., Zhuang, H., & Chen, X. (2015) · RSC Advances · doi:10.1039/c5ra00956a · Cited by 27 · see citing works

Preparation and property evaluation of biodegradable elastomeric PTMC/PLCL networks used as ureteral stents

Liu, X., Liu, S., Li, K., Fan, Y., Feng, S., Peng, L., Zhang, T., Wang, X., Chen, D., Xiong, C., et al. (2021) · Colloids and Surfaces A: Physicochemical and Engineering Aspects · doi:10.1016/j.colsurfa.2021.127550 · Cited by 24 · see citing works

ROP of Cyclic Esters. Mechanisms of Ionic and Coordination Processes

Duda, A. (2012) · Elsevier eBooks · doi:10.1016/b978-0-444-53349-4.00104-7 · Cited by 23 · see citing works

Facile Synthesis of Gradient Polycarbonate–Polyester Terpolymers from Monomer Mixtures Mediated by an Asymmetric Chromium Complex

Zhou, Y., Gao, Z., Hu, C., Meng, S., Duan, R., Sun, Z., & Pang, X. (2022) · Macromolecules · doi:10.1021/acs.macromol.2c01680 · Cited by 22 · see citing works

Synthesis of lactide/ɛ‐caprolactone quasi‐random copolymer by using rationally designed mononuclear aluminum complexes with modified β‐ketiminato ligand

Huang, H., Li, Z., Wang, B., Chen, X., & Li, Y. (2017) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.28886 · Cited by 21 · see citing works

Copolymerization of Lactide and Cyclic Carbonate via Highly Stereoselective Catalysts To Modulate Copolymer Sequences

Liu, X., Hua, X., & Cui, D. (2018) · Macromolecules · doi:10.1021/acs.macromol.7b02696 · Cited by 21 · see citing works

A convenient method to prepare random LA/CL copolymers from poly(L-lactide) and ε-caprolactone

Ouyang, H., Nie, K., Yuan, D., Zhang, Y., Cui, D., & Yao, Y. (2018) · Science China Chemistry · doi:10.1007/s11426-017-9212-1 · Cited by 21 · see citing works

Lanthanum complexes stabilized by a pentadentate Schiff-base ligand: synthesis, characterization, and reactivity in statistical copolymerization of ε-caprolactone and l -lactide

Shao, J., Zhou, H., Wang, Y., Luo, Y., & Yao, Y. (2020) · Dalton Transactions · doi:10.1039/d0dt00179a · Cited by 21 · see citing works

Comparative Experimental and Theoretical Study of Mg, Al and Zn Aryloxy Complexes in Copolymerization of Cyclic Esters: The Role of the Metal Coordination in Formation of Random Copolymers

Nifant'ev, I. E., Komarov, P. D., Ovchinnikova, V. I., Kiselev, A. V., Minyaev, M. E., & Ivchenko, P. V. (2020) · Polymers · doi:10.3390/polym12102273 · Cited by 21 · see citing works

Synthesis of Aluminum Complexes Bearing 8-Anilide-5,6,7-trihydroquinoline Ligands: Highly Active Catalyst Precursors for Ring-Opening Polymerization of Cyclic Esters

Liu, S., Zhang, J., Zuo, W., Zhang, W., Sun, W., Ye, H., & Li, Z. (2017) · Polymers · doi:10.3390/polym9030083 · Cited by 20 · see citing works

Ring-opening polymerization of rac-lactide, copolymerization of rac-lactide and ε-caprolactone by zinc complexes bearing pyridyl-based tridentate amino-phenolate ligands

Fang, C., & Ma, H. (2019) · European Polymer Journal · doi:10.1016/j.eurpolymj.2019.07.046 · Cited by 20 · see citing works

Copolymerization of L-Lactide and ε-Caprolactone promoted by zinc complexes with phosphorus based ligands

D'Auria, I., Lamberti, M., Rescigno, R., Venditto, V., & Mazzeo, M. (2021) · Heliyon · doi:10.1016/j.heliyon.2021.e07630 · Cited by 19 · see citing works

Ring-opening polymerization of lactide using salen–aluminum complexes bearing Schiff-base ligands derived from cis-1,2-cyclohexanediamine

Cui, Y., Li, D., Gao, B., Zhou, Y., Chen, L., Baoguo, Q., Li, Y., Duan, Q., & Hu, N. (2015) · Journal of Coordination Chemistry · doi:10.1080/00958972.2015.1121248 · Cited by 18 · see citing works

Random copolymerisations catalysed by simple titanium α-amino acid complexes

Webster, R. L. (2013) · RSC Advances · doi:10.1039/c3ra45810e · Cited by 18 · see citing works

Titanium complexes of pyrrolylaldiminate ligands and their exploitation for the ring-opening polymerization of cyclic esters

Upitak, K., Wattanathana, W., Nanok, T., Chuawong, P., & Hormnirun, P. (2021) · Dalton Transactions · doi:10.1039/d1dt01470f · Cited by 18 · see citing works

DFT Visualization and Experimental Evidence of BHT-Mg-Catalyzed Copolymerization of Lactides, Lactones and Ethylene Phosphates

Nifant’ev, I., Shlyakhtin, A., Kosarev, M., Gavrilov, D., Karchevsky, S., & Ivchenko, P. (2019) · Polymers · doi:10.3390/polym11101641 · Cited by 17 · see citing works

Synthesis and characterization of bisphenol sodium complexes: An efficient catalyst for the ring-opening polymerization of l-lactide

Xu, X., Pan, X., Tang, S., Lv, X., Li, L., Wu, J., & Zhao, X. (2013) · Inorganic Chemistry Communications · doi:10.1016/j.inoche.2012.12.029 · Cited by 17 · see citing works

Random l-lactide/ε-caprolactone copolymers as drug delivery materials

Dalmoro, A., Barba, A. A., Lamberti, M., Mazzeo, M., Venditto, V., & Lamberti, G. (2014) · Journal of Materials Science · doi:10.1007/s10853-014-8317-x · Cited by 18 · see citing works

Catalytic polymerization of ε-caprolactone in air

Pärssinen, A., Kohlmayr, M., Leskelä, M. A., Lahcini, M., & Repo, T. (2010) · Polymer Chemistry · doi:10.1039/c0py00107d · Cited by 17 · see citing works

Random copolymerization of ε-caprolactone and l-lactide with molybdenum complexes

Maruta, Y., & Abiko, A. (2014) · Polymer Bulletin · doi:10.1007/s00289-014-1106-5 · Cited by 17 · see citing works

Ring‐Opening Polymerization of Cyclic Esters by an Enantiopure Heteroscorpionate Rare Earth Initiator

Otero, A., Fernández‐Baeza, J., Lara‐Sánchez, A., Alonso‐Moreno, C., Márquez‐Segovia, I., Sánchez‐Barba, L. F., & Rodrı́guez, A. M. (2009) · Angewandte Chemie · doi:10.1002/ange.200806202 · Cited by 17 · see citing works

Inverse dependencies on the polymerization rate in atom transfer radical polymerization of N-isopropylacrylamide in aqueous medium

Vachaudez, M., D’hooge, D., Socka, M., Libiszowski, J., Coulembier, O., Reyniers, M., Duda, A., Marin, G. B., & Dúbois, P. (2012) · Reactive and Functional Polymers · doi:10.1016/j.reactfunctpolym.2012.11.004 · Cited by 16 · see citing works

Active Ga-catalysts for the ring opening homo- and copolymerization of cyclic esters, and copolymerization of epoxide and anhydrides

Ghosh, S., Glöckler, E., Wölper, C., Tjaberings, A., Gröschel, A. H., & Schulz, S. (2020) · Dalton Transactions · doi:10.1039/d0dt02831b · Cited by 16 · see citing works

Synthesis of dinuclear aluminum complexes bearing bis-phenolate ligand and application in ring-opening polymerization of ε-caprolactone

Zhang, J., Liu, S., Zuo, W., Ye, H., & Li, Z. (2017) · New Journal of Chemistry · doi:10.1039/c6nj03818b · Cited by 15 · see citing works

Random copolymerization of l ‐lactide and ε‐caprolactone by aluminum alkoxide complexes supported by N2O2 bis(phenolate)‐amine ligands

Chumsaeng, P., Haesuwannakij, S., Virachotikul, A., & Phomphrai, K. (2019) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.29425 · Cited by 13 · see citing works

Synthesis, spectroscopy, and crystallography of mononuclear, five-coordinate aluminum complexes that act as cyclic ester polymerization initiators

McCollum, A. M., Longo, A. M., Stahl, A. E., Butler, A. S., Rheingold, A. L., Cundari, T. R., Green, D. B., Brereton, K. R., & Fritsch, J. M. (2021) · Polyhedron · doi:10.1016/j.poly.2021.115233 · Cited by 13 · see citing works

Ring–Chain Equilibria in Ring-Opening Polymerization

Szymański, R. (2012) · Elsevier eBooks · doi:10.1016/b978-0-444-53349-4.00115-1 · Cited by 13 · see citing works

Synthesis and Structure of Lanthanide Aryloxo Complexes and Their Polymerization Behavior for ϵ‐Caprolactone

Fang, L., Yao, Y., Zhang, Y., Shen, Q., & Wang, Y. (2013) · Zeitschrift für anorganische und allgemeine Chemie · doi:10.1002/zaac.201300218 · Cited by 12 · see citing works

Rare-earth metal complexes derived from the acids Ph2C(X)CO2H (X= OH, NH2): Structural and ring opening polymerization (ROP) studies

Collins, J., Santoro, O., Prior, T. J., Chen, K., & Redshaw, C. (2020) · Journal of Molecular Structure · doi:10.1016/j.molstruc.2020.129083 · Cited by 11 · see citing works

Synthesis of N-Methyl-o-phenylenediamine-Bridged Bis(phenolato) Lanthanide Alkoxides and Their Catalytic Performance for the (Co)Polymerization of rac-Butyrolactone and l -Lactide

Tian, T., Feng, C., Wang, Y., Zhu, X., Yuan, D., & Yao, Y. (2022) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.2c00582 · Cited by 8 · see citing works

Extending the Scope of Benign and Thermally Stable Organocatalysts: Application of Dibenzoylmethane for the Bulk Copolymerization of l ‐Lactide and ɛ‐Caprolactone

Mezzasalma, L., Winter, J. D., Taton, D., & Coulembier, O. (2017) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.28921 · Cited by 8 · see citing works

Ring-opening polymerization of lactide using Salen aluminum complexes bearing Schiff-base ligands derived from cis-1,2-cyclohexanediamine

Cui, Y., Li, D., Gao, B., Zhou, Y., Li, C., Baoguo, Q., Li, Y., Duan, Q., & Hu, N. (2015) · Figshare · doi:10.6084/m9.figshare.1609734 · Cited by 7 · see citing works

Catalysts as Key Enablers for the Synthesis of Bioplastics with Sophisticated Architectures

Rittinghaus, R. D., & Herres‐Pawlis, S. (2022) · Chemistry - A European Journal · doi:10.1002/chem.202202222 · Cited by 6 · see citing works

Investigating the Ring-Opening Polymerization Activity of Niobium and Tantalum Ethoxides Supported by Phenoxyimine Ligands

Plaman, A. S., & Durr, C. B. (2022) · ACS Omega · doi:10.1021/acsomega.2c02880 · Cited by 7 · see citing works

Iron( <scp>ii</scp> ) carboxylates and simple carboxamides: an inexpensive and modular catalyst system for the synthesis of PLLA and PLLA-PCL block copolymers

Kirchhecker, S., Nguyen, N., Reichert, S., Lützow, K., Eselem Bungu, P. S., Jacobi von Wangelin, A., Sandl, S., & Neffe, A. T. (2023) · RSC Advances · doi:10.1039/d3ra03112h · Cited by 6 · see citing works

Effect of the Configuration of a Bulky Aluminum Initiator on the Structure of Copolymers of l,l-Lactide with Symmetric Comonomer Trimethylene Carbonate

Socka, M., Szymański, R., Sosnowski, S., & Duda, A. (2018) · Polymers · doi:10.3390/polym10010070 · Cited by 5 · see citing works

Aluminium complexes supported by a thioether-bridged salen ligand: synthesis, characterization and application in ε-caprolactone homopolymerization and copolymerization with L-lactide

Qian, C., Yuan, D., Wang, Y., & Yao, Y. (2021) · Journal of Organometallic Chemistry · doi:10.1016/j.jorganchem.2021.122007 · Cited by 6 · see citing works

Living Ring‐Opening Polymerization of Heterocyclic Monomers

Penczek, S., Cypryk, M., Duda, A., Kubisa, P., & Słomkowski, S. (2009) · Wiley eBooks · doi:10.1002/9783527629091.ch5 · Cited by 5 · see citing works

Recent developments of stereoselective ring-opening polymerization of lactides

Sun, Z., Zhang, H., Chen, X., Pang, X., Zhou, Y., & Duan, R. (2020) · Scientia Sinica Chimica · doi:10.1360/ssc-2020-0005 · Cited by 5 · see citing works

Comment on “Synthesis of cyclic polymers and flaws of the Jacobson–Stockmayer theory” by H. R. Kricheldorf, et al ., Polym. Chem ., 2020, 11, 2595

Szymański, R. (2020) · Polymer Chemistry · doi:10.1039/d0py00592d · Cited by 3 · see citing works

Kontrolle über Chaos und Ordnung: Gegensätzliche Mikrostrukturen von PCL‐co‐PGA‐co‐PLA durch einen einzigen Katalysator zugänglich**

Rittinghaus, R. D., Zenner, J., Pich, A., Kol, M., & Herres‐Pawlis, S. (2022) · Angewandte Chemie · doi:10.1002/ange.202112853 · Cited by 3 · see citing works

Access to Microstructurally Complex Block Copolymers via Switchable Ring-Opening Polymerization of Cyclic Ester Mixtures

Seed, D. J. E., Milner, A. B., Walker, G. R., & Platel, R. H. (2025) · Macromolecules · doi:10.1021/acs.macromol.5c00822 · Cited by 2 · see citing works

Catalytic Ring-Opening Homopolymerization and Copolymerization of rac-Lactide and δ-Valerolactone Utilizing Rare-Earth Metal Complexes with Indol-2-yl-Based Ligands in Tridentate and Tetradentate Bonding Modes

Huang, Z., Yi, X., Pan, R., Huang, H., Liu, C., Chen, L., Wang, F., & Wang, S. (2025) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.5c00790 · Cited by 1 · see citing works

Alternating copolymerization of l -lactide and ε-caprolactone via enantiomorphic site and chain-end synergistic control

Xian, J., Li, G. L., Wu, L., Fu, H., Wang, C., Lü, S., Pan, X., & Wu, J. (2026) · Chemical Science · doi:10.1039/d6sc04630d · Cited by 1 · see citing works

Polymerization of ε-Caprolactone and Copolymerization with rac-Lactide Cata-lyzed by Mono(amidinate) Aluminum Complexes

Feng, Q. I. A. N., Liu, K., & Ma, H. (2011) · CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION) · doi:10.3724/sp.j.1088.2011.00739

Professor Andrzej Duda In Memoriam

Penczek, S., Lewiński, P., Pretula, J., & Socka, M. (2017) · Polimery · doi:10.14314/polimery.2017.239

A nature « copy-paste » approach for an efficient metal-free polymerization route

Mezzasalma, L. (2019) · theses.fr (ABES) · doi:10.70675/b3eae817z9ef5z4b85z8b71z4af37be33182

Cationic copolymerization of ε‐caprolactone and <scp>L,L</scp>‐lactide by an activated monomer mechanism

Baśko, M., & Kubisa, P. (2006) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.21712 · Cited by 122 · see citing works

Cationic copolymerization of ε-caprolactone and L,L-lactide by an activated monomer mechanism Part A Polymer chemistry

Baśko, M., & Kubisa, P. (2006)

Kinetic study and determination of reactivity ratios in the copolymerization of cyclic lactones using ROP chemistry

Quintero, M. A. O., López-González, H. R., & Saldívar‐Guerra, E. (2026) · Polymer · doi:10.1016/j.polymer.2026.130418

The copolymerization of l-lactide and ɛ-caprolactone using magnesium octoate as a catalyst

Wei, Z., Liu, L., Jun, G., Wang, P., & Qi, M. (2008) · Chinese Chemical Letters · doi:10.1016/j.cclet.2008.01.004 · Cited by 9 · see citing works

Coordination polymerization of lactides, 3. Copolymerization of <scp>L</scp>,<scp>L</scp>‐lactide and ε‐caprolactone in the presence of initiators containing Zn and Al

Bero, M., Kasperczyk, J., & Adamus, G. (1993) · Die Makromolekulare Chemie · doi:10.1002/macp.1993.021940314 · Cited by 125 · see citing works