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Effect of Alloy Composition and Exposure Conditions on the Selective Oxidation Behavior of Ferritic Fe–Cr and Fe–Cr–X Alloys
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“Reaction in dry [7] and wet CO 2 gases resulted in both oxidation and carburization for the undoped Fe-20Cr-20Ni alloy, as shown in Fig. 12 for the wet case.”
From Effects of Silicon on High Temperature Corrosion of Fe–Cr and Fe–Cr–Ni Alloys in Carbon Dioxide (2014) · cites this paper as [7]
Experimental — accuracy not yet measuredThe source backs part of the claim, not all of it — or backs it for a different population, condition or comparison.
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“The addition of a small amount of Si to Fe-20Cr-20Ni greatly reduced oxygen uptake in both dry [7] and wet (Fig. 7) CO 2 gases.”
From Effects of Silicon on High Temperature Corrosion of Fe–Cr and Fe–Cr–Ni Alloys in Carbon Dioxide (2014) · cites this paper as [7]
Experimental — accuracy not yet measuredThe source backs part of the claim, not all of it — or backs it for a different population, condition or comparison.
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“Addition of Si to Fe-20Cr and Fe-20Cr-20Ni resulted in the formation of an additional silicon oxide layer beneath the chromia layer during reaction in dry [7] and wet CO 2 (Figs. 5, 11).”
From Effects of Silicon on High Temperature Corrosion of Fe–Cr and Fe–Cr–Ni Alloys in Carbon Dioxide (2014) · cites this paper as [7]
Experimental — accuracy not yet measuredThe source backs part of the claim, not all of it — or backs it for a different population, condition or comparison.
In the citing paper
“The chromia scale formed in the early stages was therefore replaced by a uniform iron oxide scale when reactions proceeded to longer times in both dry [7] and wet [10] gases.”
From Effects of Silicon on High Temperature Corrosion of Fe–Cr and Fe–Cr–Ni Alloys in Carbon Dioxide (2014) · cites this paper as [7]
Experimental — accuracy not yet measuredThe check wasn’t confident either way, so it gives no verdict — never disputed.
In the citing paper
“However, weight uptakes of the Si-containing alloys in dry CO 2 [7] and wet CO 2 gas (Fig. 1) were markedly smaller than those of the undoped Fe-20Cr alloy.”
From Effects of Silicon on High Temperature Corrosion of Fe–Cr and Fe–Cr–Ni Alloys in Carbon Dioxide (2014) · cites this paper as [7]
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In the citing paper
“The undoped Fe-20Cr-20Ni alloy underwent breakaway oxidation in dry [7] and wet CO 2 (Fig. 8), but the additions of Si to this alloy markedly reduced the oxygen uptake in both dry CO 2 [7] and wet CO 2 (Fig. 7).”
From Effects of Silicon on High Temperature Corrosion of Fe–Cr and Fe–Cr–Ni Alloys in Carbon Dioxide (2014) · cites this paper as [7]
Experimental — accuracy not yet measuredThe check wasn’t confident either way, so it gives no verdict — never disputed.
In the citing paper
“Blade-shaped whiskers were observed on chromia scales in the wet CO 2 reaction (Fig. 2b), but not in dry CO 2 [7].”
From Effects of Silicon on High Temperature Corrosion of Fe–Cr and Fe–Cr–Ni Alloys in Carbon Dioxide (2014) · cites this paper as [7]
Experimental — accuracy not yet measuredThe check wasn’t confident either way, so it gives no verdict — never disputed.
In the citing paper
“In contrast, metallographic examination confirmed that no carbides were formed in any Si-containing Fe-20Cr-20Ni alloy in either dry [7] or wet CO 2 gases.”
From Effects of Silicon on High Temperature Corrosion of Fe–Cr and Fe–Cr–Ni Alloys in Carbon Dioxide (2014) · cites this paper as [7]
Experimental — accuracy not yet measuredThe check wasn’t confident either way, so it gives no verdict — never disputed.
In the citing paper
“The thin scale regions on Fe-20Cr-20Ni-(0.1, 0.2, 0.5)Si alloys after reactions in dry [7] and wet CO 2 (Figs. 5, 11) reactions contained the same corrosion products of chromia and silicon oxide.”
From Effects of Silicon on High Temperature Corrosion of Fe–Cr and Fe–Cr–Ni Alloys in Carbon Dioxide (2014) · cites this paper as [7]
Experimental — accuracy not yet measuredThe check wasn’t confident either way, so it gives no verdict — never disputed.
In the citing paper
“Solid chromia scales on these Si-bearing austenitic alloys were thin and almost the same thickness in dry (about 0.8~1.5 µm thick after 240 h) [7] and wet CO 2 (about 1.6 µm thick after 240 h).”
From Effects of Silicon on High Temperature Corrosion of Fe–Cr and Fe–Cr–Ni Alloys in Carbon Dioxide (2014) · cites this paper as [7]
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Metadata
- Authors
- Meier, G. H., Jung, K., Mu, N., Yanar, N. M., Pettit, F. S., Pirón Abellán, J., Olszewski, T., Nieto Hierro, L., Quadakkers, W. J., & Holcomb, G. R.
- Affiliations
- University of Pittsburgh (US)
- Forschungszentrum Jülich (DE)
- National Energy Technology Laboratory (US)
- Corresponding author
- Jung, Keeyoung
- Venue
- Oxidation of Metals
- Published
- 2010-09-05
- Volume
- 74
- Issue
- 5-6
- Pages
- 319-340
- ISSN
- 0030-770X (ISSN-L)
- 1573-4889
- OpenAlex
- W2082495205
- Cited by
- 204
- References
- 29
- Citations by year
- 2026: 6 · 2025: 16 · 2024: 15 · 2023: 17 · 2022: 18 · 2021: 14 · 2020: 16 · 2019: 14 · 2018: 11 · 2017: 13 · 2016: 12 · 2015: 13 · 2014: 15 · 2013: 13 · 2012: 8
- FWCI
- 15.08
- Type
- journal article
- Language
- en
- Open access
- green
- www.osti.gov
- Licence
- www.springer.com/tdm (tdm)
- Locations
- Oxidation of Metals (publishedVersion)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- Funders
- National Energy Technology Laboratory
- Topics
- Physical Sciences › Materials Science › Surfaces, Coatings and Films › High-Temperature Coating Behaviors
- Physical Sciences › Materials Science › Materials Chemistry › Nuclear Materials and Properties
- Physical Sciences › Materials Science › Materials Chemistry › Advancements in Solid Oxide Fuel Cells
- Keywords
- selective oxidation, ferritic-martensitic steel, Fe-Cr alloys, oxy-fuel combustion, chromia scale, Wagner model, chromium content, alloying elements, silicon, oxide scale formation, high-temperature oxidation
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