Assessment of amendments for the immobilization of Cu in soils containing EDDS leachates
Abstract
In this study, the effectiveness of six soil amendments (ferrihydrite, manganese dioxide, gibbsite, calcium carbonate, biochar, and organic fertilizer) was investigated to assess the feasibility of minimizing possible environmental contaminant leaching during S,S-ethylenediaminedisuccinic acid (EDDS)-enhanced phytoextraction process based on 0.01-M CaCl2 extraction. Results showed that the application of EDDS could significantly increase Cu concentrations in the leaching solution. Compared with control, incorporation of six amendments (excluding organic fertilizer) significantly decreased CaCl2-extractable Cu concentrations in both soils. When EDDS-containing solutions leached from the soil columns (mimicking the upper soil layers) were added to soils with different amendments (mimicking the subsoil), CaCl2-extractable Cu in the soils amended with ferrihydrite, manganese dioxide, gibbsite, and calcium carbonate was significantly lower than that in the control soil (no amendments) and remained relatively constant during the first 14 days. Incorporation of biochar or organic fertilizer had no positive effect on the immobilization of Cu in EDDS leachates in soils. After 14 days, CaCl2-extractable Cu concentration decreased rapidly in soils incorporated with various amendments. Integrating soil washing with biodegradable chelating agents or chelant-enhanced phytoextraction and immobilization of heavy metals in subsoil could be used to rapidly reduce the concentration of bioavailable metal fractions in the upper soil layers and minimize environmental risks of secondary pollution.
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Incorporating gibbsite significantly reduced CaCl2-extractable Cu concentrations in Cu-contaminated soil.
“In contrast, Yang et al. (2015) reported that incorporating gibbsite significantly reduced CaCl 2 -extractable Cu concentrations in Cu-contaminated soil.”
From Soil amendments for immobilization of potentially toxic elements in contaminated soils: A critical review (2020) · cites this paper as Yang et al., 2015
Applying ferrihydrite significantly reduced CaCl2-extractable Cu concentrations in Cu-contaminated soil.
“Nevertheless, Yang et al. (2015) reported that applying ferrihydrite significantly reduced CaCl 2extractable Cu concentrations in Cu-contaminated soil.”
From Soil amendments for immobilization of potentially toxic elements in contaminated soils: A critical review (2020) · cites this paper as Yang et al., 2015
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- Authors
- Yang, L., Jiang, L., Wang, G., Chen, Y., Shen, Z., & Luo, C.
- Affiliations
- Nanjing Agricultural University (CN)
- Chinese Academy of Sciences (CN)
- Corresponding author
- Shen, Zhenguo
- Luo, Chunling
- Venue
- Environmental Science and Pollution Research
- Published
- 2015-06-17
- Volume
- 22
- Issue
- 21
- Pages
- 16525-16534
- ISSN
- 0944-1344 (ISSN-L)
- 1614-7499
- OpenAlex
- W2181571531
- Cited by
- 14
- References
- 55
- Citations by year
- 2025: 1 · 2021: 1 · 2020: 1 · 2019: 2 · 2018: 3 · 2017: 3 · 2016: 3
- FWCI
- 1.86
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- www.springer.com/tdm (tdm)
- Locations
- Environmental Science and Pollution Research (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Environmental Science › Pollution › Heavy metals in environment
- Physical Sciences › Environmental Science › Water Science and Technology › Environmental and Analytical Chemistry Studies
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Keywords
- copper immobilization, soil amendment, ferrihydrite, manganese dioxide, gibbsite, calcium carbonate, biochar, organic fertilizer, heavy metal leaching, subsoil contamination, secondary pollution, copper bioavailability
- MeSH terms
- Calcium Chloride, Copper, Ethylenediamines, Fertilizers, Soil, Soil Pollutants, Solutions, Succinates, Environmental Restoration and Remediation
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