Chemical stabilization of metals and arsenic in contaminated soils using oxides–a review
Abstract
Oxides and their precursors have been extensively studied, either singly or in combination with other amendments promoting sorption, for in situ stabilization of metals and As in contaminated soils. This remediation option aims at reducing the available fraction of metal(loid)s, notably in the root zone, and thus lowering the risks associated with their leaching, ecotoxicity, plant uptake and human exposure. This review summarizes literature data on mechanisms involved in the immobilization process and presents results from laboratory and field experiments, including the subsequent influence on higher plants and aided phytostabilization. Despite the partial successes in the field, recent knowledge highlights the importance of long-term and large-scale field studies evaluating the stability of the oxide-based amendments in the treated soils and their efficiency in the long-term.
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Arsenic adsorption into iron oxides can be explained by ligand exchange of As species for OH and OH2 groups on the surfaces of iron oxides.
“Arsenic adsorption into iron oxides can be explained by ligand exchange of As species for OH -and OH 2 groups on the surfaces of iron oxides (Komárek et al., 2013).”
From Soil amendments for immobilization of potentially toxic elements in contaminated soils: A critical review (2020) · cites this paper as Komárek et al., 2013
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Palansooriya, K. N., Shaheen, S. M., Chen, S. S., Tsang, D. C. W., Hashimoto, Y., Hou, D., Bolan, N. S., Rinklebe, J., & Ok, Y. S. (2020) · Environment International · doi:10.1016/j.envint.2019.105046 · Cited by 1,272 · see citing works
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Assessment of amendments for the immobilization of Cu in soils containing EDDS leachates
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- Authors
- Komárek, M., Vaněk, A., & Ettler, V.
- Affiliations
- Czech University of Life Sciences Prague (CZ)
- Charles University (CZ)
- Corresponding author
- Komárek, Michael
- Venue
- Environmental Pollution
- Publisher
- Elsevier BV
- Published
- 2013-01
- Volume
- 172
- Pages
- 9-22
- ISSN
- 0269-7491 (ISSN-L)
- OpenAlex
- W1977336833
- Cited by
- 602
- References
- 171
- Citations by year
- 2026: 16 · 2025: 36 · 2024: 47 · 2023: 55 · 2022: 52 · 2021: 60 · 2020: 59 · 2019: 48 · 2018: 39 · 2017: 51 · 2016: 56 · 2015: 39 · 2014: 30 · 2013: 14
- FWCI
- 2.42
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Environmental Pollution (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Czech Science Foundation (GAČR P503/11/0840, GAČR P210/11/1597)
- Topics
- Physical Sciences › Environmental Science › Pollution › Heavy metals in environment
- Physical Sciences › Environmental Science › Environmental Chemistry › Arsenic contamination and mitigation
- Physical Sciences › Environmental Science › Water Science and Technology › Environmental and Analytical Chemistry Studies
- Keywords
- chemical stabilization, contaminated soil, metal immobilization, arsenic, in situ remediation, leaching risk, phytostabilization, plant uptake, ecotoxicity, human exposure
- MeSH terms
- Arsenic, Metals, Oxides, Soil, Soil Pollutants, Environmental Restoration and Remediation
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
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