Influence of a low content of PEO segment on the thermal, surface and morphological properties of triblock and diblock PCL copolymers

Ponjavic, Marijana; Nikolic, Marija S.; Jevtic, Sanja; Rogan, Jelena; Stevanovic, Sanja; Djonlagic, Jasna

doi:10.1007/s13233-016-4048-y

Cited by 20biodegradable polymer synthesis and propertiesPolymer crystallization and propertiesBlock Copolymer Self-Assembly

Influence of a low content of PEO segment on the thermal, surface and morphological properties of triblock and diblock PCL copolymers

Ponjavic, Marijana, Nikolic, Marija S., Jevtic, Sanja, Rogan, Jelena, Stevanovic, Sanja, Djonlagic, Jasna·2016·Macromolecular Research

DOI 10.1007/s13233-016-4048-y

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In the triblock terpolymer PE217.1-b-PCL124.2-b-PLLA67.23, both PE and PLLA exhibit significant crystallinity levels around 30-35%, which are low compared to typical homopolymer values but appear enough to produce a clear E′ and H improvement and an E′′/E′ decrease with respect to the terpolymer PE227.1-b-PEO4615.1-b-PCL3210.4.
“As a final point, the role of crystalline PLLA and PE can be clearly discerned with the triblock terpolymer PE217.1-b-PCL124.2-b-PLLA67.23 In this case, both PE and PLLA exhibit significant crystallinity levels around 30–35%, which seem low compared to typical values for the homopolymers (Table S9) but appear to be enough to produce a clear E′ and H improvement (and a E″/E′ decrease, see Table S9)”
From Sequential Crystallization and Multicrystalline Morphology in PE- b -PEO- b -PCL- b -PLLA Tetrablock Quarterpolymers (2021) · cites this paper as [23]

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Authors: Ponjavic, M., Nikolic, M. S., Jevtic, S., Rogan, J., Stevanovic, S., & Djonlagic, J.
Affiliations: University of Belgrade (RS)
ORCID: Rogan, Jelena
Venue: Macromolecular Research
Publisher: Springer Science and Business Media LLC
Published: 2016-04
Volume: 24
Issue: 4
Pages: 323-335
ISSN: 1225-5947 (ISSN-L)
1598-5032
2092-7673
DOI: 10.1007/s13233-016-4048-y
OpenAlex: W2345228867
Cited by: 20
References: 44
Citations by year: 2026: 1 · 2025: 1 · 2023: 1 · 2021: 2 · 2020: 5 · 2019: 5 · 2018: 2 · 2017: 2 · 2016: 1
FWCI: 1.37
Type: journal article
Language: en
Open access: closed
Licence: www.springer.com/tdm (tdm)
Locations: Macromolecular Research (publishedVersion)
TechnoRep (University of Belgrade – Faculty of Technology and Metallurgy) (publishedVersion)
CER (University of Belgrade, Institute of Chemistry, Technology and Metallurgy) (submittedVersion)
Topics: Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
Keywords: polycaprolactone, poly(ethylene oxide), triblock copolymers, diblock copolymers, ring-opening polymerization, macroinitiator, crystallinity, thermal degradation, spherulitic morphology, surface roughness, water absorption, semicrystalline polymers

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Influence of a low content of PEO segment on the thermal, surface and morphological properties of triblock and diblock PCL copolymers

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