Nanosunscreens: from nanoencapsulated to nanosized cosmetic active forms

Nanoparticles - A review

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Titanium dioxide and zinc oxide nanoparticles in sunscreens: focus on their safety and effectiveness

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Correlating Nanoscale Titania Structure with Toxicity: A Cytotoxicity and Inflammatory Response Study with Human Dermal Fibroblasts and Human Lung Epithelial Cells

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Inorganic and organic UV filters: Their role and efficacy in sunscreens and suncare products

Serpone, N., Dondi, D., & Albini, A. (2007) · Inorganica Chimica Acta · doi:10.1016/j.ica.2005.12.057 · Cited by 711 · see citing works

<i>Grey Goo</i>on the Skin? Nanotechnology, Cosmetic and Sunscreen Safety

Nohynek, G. J., Lademann, J., Ribaud, C., & Roberts, M. S. (2007) · Critical Reviews in Toxicology · doi:10.1080/10408440601177780 · Cited by 644 · see citing works

DNA damaging potential of zinc oxide nanoparticles in human epidermal cells

Sharma, V., Shukla, R. K., Saxena, N., Parmar, D., Das, M., & Dhawan, A. (2009) · Toxicology Letters · doi:10.1016/j.toxlet.2009.01.008 · Cited by 633 · see citing works

The safety of nanosized particles in titanium dioxide– and zinc oxide–based sunscreens

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Polymeric Nanoparticles, Nanospheres and Nanocapsules, for Cutaneous Applications

Guterres, S. S., Alves, M. P., & Pohlmann, A. R. (2007) · Drug Target Insights · doi:10.1177/117739280700200002 · Cited by 462 · see citing works

Handbook of Cosmetic Science and Technology

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Dispersion and surface functionalization of oxide nanoparticles for transparent photocatalytic and UV-protecting coatings and sunscreens

Faure, B., Salazar‐Alvarez, G., Ahniyaz, A., Villaluenga, I., Berriozabal, G., de Miguel, Y. R., & Bergström, L. (2013) · Science and Technology of Advanced Materials · doi:10.1088/1468-6996/14/2/023001 · Cited by 395 · see citing works

Safety Evaluation of Sunscreen Formulations Containing Titanium Dioxide and Zinc Oxide Nanoparticles in UVB Sunburned Skin: An In Vitro and In Vivo Study

Monteiro-Riviere, N. A., Wiench, K., Landsiedel, R., Schulte, S., Inman, A. O., & Riviere, J. E. (2011) · Toxicological Sciences · doi:10.1093/toxsci/kfr148 · Cited by 389 · see citing works

Human safety review of “nano” titanium dioxide and zinc oxide

Schilling, K., Bradford, B., Castelli, D., Dufour, E. K., Nash, J. F., Pape, W. J. W., Schulte, S., Tooley, I. R., van den Bosch, J., & Schellauf, F. (2010) · Photochemical & Photobiological Sciences · doi:10.1039/b9pp00180h · Cited by 381 · see citing works

β-Carotene nanodispersions: preparation, characterization and stability evaluation

Tan, C. P., & Nakajima, M. (2004) · Food Chemistry · doi:10.1016/j.foodchem.2004.08.044 · Cited by 337 · see citing works

Nanotechnology, Cosmetics and the Skin: Is There a Health Risk?

Nohynek, G. J., Dufour, E. K., & Roberts, M. S. (2008) · Skin Pharmacology and Physiology · doi:10.1159/000131078 · Cited by 314 · see citing works

Lack of Significant Dermal Penetration of Titanium Dioxide from Sunscreen Formulations Containing Nano- and Submicron-Size TiO2 Particles

Sadrieh, N. K., Wokovich, A. M., Gopee, N. V., Zheng, J., Haines, D. C., Parmiter, D., Siitonen, P. H., Cozart, C. R., Patri, A. K., McNeil, S. E., et al. (2010) · Toxicological Sciences · doi:10.1093/toxsci/kfq041 · Cited by 309 · see citing works

Polymeric nanoparticles, nanospheres and nanocapsules, for cutaneous applications.

Guterres, S. S., Alves, M. P., & Pohlmann, A. R. (2007) · PubMed · Cited by 302 · see citing works

The effect of surface modification with silane coupling agent on suppressing the photo-catalytic activity of fine TiO2 particles as inorganic UV filter

Ukaji, E., Furusawa, T., Sato, M., & Suzuki, N. (2007) · Applied Surface Science · doi:10.1016/j.apsusc.2007.06.061 · Cited by 301 · see citing works

Ultraviolet filters

Shaath, N. A. (2010) · Photochemical & Photobiological Sciences · doi:10.1039/b9pp00174c · Cited by 270 · see citing works

The influence of solid lipid nanoparticles on skin hydration and viscoelasticity – in vivo study

Wissing, S. A., & Müller, R. H. (2003) · European Journal of Pharmaceutics and Biopharmaceutics · doi:10.1016/s0939-6411(03)00040-7 · Cited by 245 · see citing works

Characteristics of silica‐coated TiO 2 and its UV absorption for sunscreen cosmetic applications

Jaroenworaluck, A., Sunsaneeyametha, W., Kosachan, N., & Stevens, R. (2006) · Surface and Interface Analysis · doi:10.1002/sia.2313 · Cited by 234 · see citing works

Stratum Corneum Is an Effective Barrier to TiO2 and ZnO Nanoparticle Percutaneous Absorption

Filipe, P., Silva, J. M., Silva, R., de Castro, J. L. C., Gomes, M. M., Alves, L. C., Santus, R. C., & Pinheiro, T. (2009) · Skin Pharmacology and Physiology · doi:10.1159/000235554 · Cited by 226 · see citing works

Application of nanostructured Ca doped CeO2 for ultraviolet filtration

Truffault, L., Ta, M.-T., Devers, T., Konstantinov, K., Harel, V., Simmonard, C., Andreazza-Vignolle, C., Nevirkovets, I. P., Pineau, A., Véron, O., et al. (2010) · Materials Research Bulletin · doi:10.1016/j.materresbull.2010.02.008 · Cited by 212 · see citing works

Investigations on the occlusive properties of solid lipid nanoparticles (SLN).

Wissing, S. A., Lippacher, A., & Müller, R. (2001) · PubMed · Cited by 202 · see citing works

Biodegradable polymer nanocapsules containing a sunscreen agent: preparation and photoprotection

Álvarez-Román, R. (2001) · European Journal of Pharmaceutics and Biopharmaceutics · doi:10.1016/s0939-6411(01)00188-6 · Cited by 181 · see citing works

Quantitative determination of OH radical generation and its cytotoxicity induced by TiO2–UVA treatment

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Migration of Intradermally Injected Quantum Dots to Sentinel Organs in Mice

Gopee, N. V., Roberts, D. W., Webb, P., Cozart, C. R., Siitonen, P. H., Warbritton, A. R., Yu, W. W., Colvin, V. L., Walker, N. J., & Howard, P. C. (2007) · Toxicological Sciences · doi:10.1093/toxsci/kfm074 · Cited by 169 · see citing works

Nano-sized cosmetic formulations or solid nanoparticles in sunscreens: A risk to human health?

Nohynek, G., & Dufour, E. (2012) · Archives of Toxicology · doi:10.1007/s00204-012-0831-5 · Cited by 161 · see citing works

Effect of nanoparticle encapsulation on the photostability of the sunscreen agent, 2-ethylhexyl-p-methoxycinnamate

Perugini, P., Simeoni, S., Scalia, S., Genta, I., Modena, T., Conti, B., & Pavanetto, F. (2002) · International Journal of Pharmaceutics · doi:10.1016/s0378-5173(02)00356-3 · Cited by 161 · see citing works

Study on penetration of titanium dioxide (TiO2) nanoparticles into intact and damaged skin in vitro

Senzui, M., Tamura, T., Miura, K., Ikarashi, Y., Watanabe, Y., & Fujii, M. (2010) · The Journal of Toxicological Sciences · doi:10.2131/jts.35.107 · Cited by 161 · see citing works

Preparation of nanodispersions containing β-carotene by solvent displacement method

Ribeiro, H. S., Chu, B., Ichikawa, S., & Nakajima, M. (2007) · Food Hydrocolloids · doi:10.1016/j.foodhyd.2007.04.009 · Cited by 155 · see citing works

Impact of solar UV radiation on toxicity of ZnO nanoparticles through photocatalytic reactive oxygen species (ROS) generation and photo-induced dissolution

Ma, H., Wallis, L. K., Diamond, S., Li, S., Cañas‐Carrell, J. E., & Parra, A. (2014) · Environmental Pollution · doi:10.1016/j.envpol.2014.06.027 · Cited by 151 · see citing works

Gene toxicity studies on titanium dioxide and zinc oxide nanomaterials used for UV-protection in cosmetic formulations

Landsiedel, R., Ma‐Hock, L., van Ravenzwaay, B., Schulz, M., Wiench, K., Champ, S., Schulte, S., Wohlleben, W., & Oesch, F. (2010) · Nanotoxicology · doi:10.3109/17435390.2010.506694 · Cited by 147 · see citing works

Photocatalytic reactive oxygen species production and phototoxicity of titanium dioxide nanoparticles are dependent on the solar ultraviolet radiation spectrum

Ma, H., Brennan, A. A., & Diamond, S. A. (2012) · Environmental Toxicology and Chemistry · doi:10.1002/etc.1916 · Cited by 135 · see citing works

Inorganic Sunscreens

Dransfield, G. P. (2000) · Radiation Protection Dosimetry · doi:10.1093/oxfordjournals.rpd.a033216 · Cited by 123 · see citing works

Nanostructured lipid carriers as novel carrier for sunscreen formulations

Xia, Q., Saupe, A., Müller, R. H., & Souto, E. B. (2007) · International Journal of Cosmetic Science · doi:10.1111/j.1468-2494.2007.00410.x · Cited by 112 · see citing works

Novel nanoparticulate carrier system based on carnauba wax and decyl oleate for the dispersion of inorganic sunscreens in aqueous media

Villalobos-Hernández, J. R., & Müller-Goymann, C. C. (2005) · European Journal of Pharmaceutics and Biopharmaceutics · doi:10.1016/j.ejpb.2004.11.002 · Cited by 91 · see citing works

Modified titania nanomaterials for sunscreen applications – reducing free radical generation and DNA damage

Wakefield, G., Green, M., Lipscomb, S. J., & Flutter, B. R. (2004) · Materials Science and Technology · doi:10.1179/026708304225019803 · Cited by 89 · see citing works

The effects of manganese doping on UVA absorption and free radical generation of micronised titanium dioxide and its consequences for the photostability of UVA absorbing organic sunscreen components

Wakefield, G., Lipscomb, S. J., Holland, E., & Knowland, J. (2004) · Photochemical & Photobiological Sciences · doi:10.1039/b403697b · Cited by 81 · see citing works

The development of an improved carrier system for sunscreen formulations based on crystalline lipid nanoparticles

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Modified TiO2 particles differentially affect human skin fibroblasts exposed to UVA light

Tiano, L., Armeni, T., Venditti, E., Barucca, G., Mincarelli, L., & Damiani, E. (2010) · Free Radical Biology and Medicine · doi:10.1016/j.freeradbiomed.2010.04.032 · Cited by 75 · see citing works

Damaging and protective properties of inorganic components of sunscreens applied to cultured human skin cells

Rampaul, A., Parkin, I. P., & Cramer, L. P. (2007) · Journal of Photochemistry and Photobiology A Chemistry · doi:10.1016/j.jphotochem.2007.04.014 · Cited by 70 · see citing works

The influence of corneocyte structure on the interpretation of permeation profiles of nanoparticles across skin

Pinheiro, T., Pallon, J., Alves, L. C., Veríssimo, A., Filipe, P., Silva, J. M., & Silva, R. (2007) · Nuclear Instruments and Methods in Physics Research Section B Beam Interactions with Materials and Atoms · doi:10.1016/j.nimb.2007.02.014 · Cited by 69 · see citing works

In vitro cytotoxicity assessment of selected nanoparticles using human skin fibroblasts

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Cerium phosphate nanoparticles with low photocatalytic activity for UV light absorption application in photoprotection

de Lima, J. F., & Serra, O. A. (2013) · Dyes and Pigments · doi:10.1016/j.dyepig.2012.12.020 · Cited by 64 · see citing works

Semisolid Formulation Containing a Nanoencapsulated Sunscreen: Effectiveness, In Vitro Photostability and Immune Response

Paese, K., Jäger, A., Poletto, F. S., Pinto, E. F., Rossi‐Bergmann, B., Pohlmann, A. R., & Guterres, S. S. (2009) · Journal of Biomedical Nanotechnology · doi:10.1166/jbn.2009.1028 · Cited by 63 · see citing works

Singlet oxygen plays a key role in the toxicity and DNA damage caused by nanometric TiO2 in human keratinocytes

Fenoglio, I., Ponti, J., Alloa, E., Ghiazza, M., Corazzari, I., Capomaccio, R. B., Rembges, D., Oliaro‐Bosso, S., & Rossi, F. (2013) · Nanoscale · doi:10.1039/c3nr01191g · Cited by 62 · see citing works

Sunblocks: Mechanisms of action

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In vitro erythemal UV-A protection factors of inorganic sunscreens distributed in aqueous media using carnauba wax–decyl oleate nanoparticles

Villalobos-Hernández, J. R., & Müller-Goymann, C. C. (2006) · European Journal of Pharmaceutics and Biopharmaceutics · doi:10.1016/j.ejpb.2006.07.013 · Cited by 56 · see citing works

Effects of iron or manganese doping of ZnO nanoparticles on their dissolution, ROS generation and cytotoxicity

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Synthesis and UV-shielding properties of calcia-doped ceria nanoparticles coated with amorphous silica

Sato, T. (2004) · Solid State Ionics · doi:10.1016/j.ssi.2004.02.057 · Cited by 50 · see citing works

Nanostructured Polymer and Lipid Carriers for Sunscreen. Biological Effects and Skin Permeation

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Influence of liposphere preparation on butyl-methoxydibenzoylmethane photostability

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Physical sunscreens: On the comeback trail

More, B. (2007) · Indian Journal of Dermatology Venereology and Leprology · doi:10.4103/0378-6323.31890 · Cited by 47 · see citing works

Decreasing the oxidative potential of TiO2 nanoparticles through modification of the surface with carbon: a new strategy for the production of safe UV filters

Livraghi, S., Corazzari, I., Paganini, M. C., Ceccone, G., Giamello, E., Fubini, B., & Fenoglio, I. (2010) · Chemical Communications · doi:10.1039/c0cc02537b · Cited by 46 · see citing works

In vivoeffect of industrial titanium dioxide nanoparticles experimentally exposed to hairless rat skin

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The effect of Fe doping on the suppression of photocatalytic activity of ZnO nanopowder for the application in sunscreens

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Solid lipid microparticles containing the sunscreen agent, octyl-dimethylaminobenzoate: Effect of the vehicle

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Stability of sunscreens containing CePO4: Proposal for a new inorganic UV filter

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Cerium oxide based particles as possible alternative to ZnO in sunscreens: Effect of the synthesis method on the photoprotection results

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Preparation of TiO2 Nanocrystallite Powders Coated with 9 mol% ZnO for Cosmetic Applications in Sunscreens

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Inactivation of TiO2 nano-powders for the preparation of photo-stable sunscreens via carbon-based surface modification

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Oil-based nanoparticles containing alternative vegetable oils (grape seed oil and almond kernel oil): preparation and characterization

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Phosphates nanoparticles doped with zinc and manganese for sunscreens

de Araujo, T. S., de Souza, S. O., Miyakawa, W., & de Sousa, E. M. B. (2010) · Materials Chemistry and Physics · doi:10.1016/j.matchemphys.2010.08.034 · Cited by 27 · see citing works

Cerium Dioxide: Future UV-filter in Sunscreen ?

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Comparison of UVA-induced ROS and sunscreen nanoparticle-generated ROS in human immune cells

Shen, C., Turney, T. W., Piva, T., Feltis, B. N., & Wright, P. F. A. (2014) · Photochemical and Photobiological Sciences · doi:10.1039/c3pp50428j · Cited by 25 · see citing works

Influence of Cyclodextrin Complexation on the in vitro Human Skin Penetration and Retention of the Sunscreen Agent, Oxybenzone

Simeoni, S., Scalia, S., Tursilli, R., & Benson, H. A. (2005) · Journal of Inclusion Phenomena and Macrocyclic Chemistry · doi:10.1007/s10847-005-9002-0 · Cited by 24 · see citing works

Poly‐Epsilon‐Caprolactone Nanocapsules Containing Octyl Methoxycinnamate: Preparation and Characterization

Jiménez, M. M., Pelletier, J., Bobin, M.-F., Martini, M. C., & Fessi, H. (2004) · Pharmaceutical Development and Technology · doi:10.1081/pdt-200031456 · Cited by 23 · see citing works

Protective effect of TiO2 particles on UV light induced pyrimidine dimer formation

Kubota, Y., Niwa, C., Ohnuma, T., Ohko, Y., Tatsuma, T., Mori, T., & Fujishima, A. (2001) · Journal of Photochemistry and Photobiology A Chemistry · doi:10.1016/s1010-6030(01)00444-0 · Cited by 22 · see citing works

The real value of novel particulate carriers for sunscreen formulation

Blasi, P., Schoubben, A., Giovagnoli, S., Rossi, C. R., & Ricci, M. (2011) · Expert Review of Dermatology · doi:10.1586/edm.11.57 · Cited by 20 · see citing works

Inhibition of the ROS-mediated cytotoxicity and genotoxicity of nano-TiO2 toward human keratinocyte cells by iron doping

Ghiazza, M., Alloa, E., Oliaro‐Bosso, S., Viola, F., Livraghi, S., Rembges, D., Capomaccio, R. B., Rossi, F., Ponti, J., & Fenoglio, I. (2014) · Journal of Nanoparticle Research · doi:10.1007/s11051-014-2263-z · Cited by 20 · see citing works

Development of semi-solid cosmetic formulations containing coenzyme Q10-loaded nanocapsules

Terroso, T. F., Külkamp‐Guerreiro, I. C., Jornada, D. S., Pohlmann, A. R., & Guterres, S. S. (2009) · El Servicio de Difusión de la Creación Intelectual (National University of La Plata) · Cited by 19 · see citing works

Preparation of nano‐sized cerium and titanium pyrophosphates via solid‐state reaction at room temperature

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Preparation of TiO2-loaded nanocapsules and their sun protection behaviors

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History and Genesis of the Detailed Review of Thyroid Hormone Disruption Assays

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Preparation of nano-sized cerium and titanium pyrophosphates via solid-state reaction at room temperature

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Photostabilization of sunscreen oil through preparation of a free-flowing powder

Latif, R., Refai, H., & Tawakkol, S. M. (2011) · Journal of Microencapsulation · doi:10.3109/02652048.2010.520092 · Cited by 7 · see citing works

Sun Protection and Sunscreens

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Sunscreens causing cancer? The facts.

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Penetration of Nanoparticles through Intact and Compromised Skin

Korinth, G., & Drexler, H. (2013) · Nanomaterials · doi:10.1002/9783527673919.ch4 · Cited by 2 · see citing works

Biocosmetics: Technological Advances and Future Outlook

Goyal, N., & Jerold, F. (2021) · Environmental Science and Pollution Research · doi:10.1007/s11356-021-17567-3 · Cited by 191 · see citing works

UV Filters: Challenges and Prospects

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Three Millennia of Nanocrystals

Montanarella, F., & Kovalenko, M. V. (2022) · ACS Nano · doi:10.1021/acsnano.1c11159 · Cited by 85 · see citing works

Development, Cytotoxicity and Eye Irritation Profile of a New Sunscreen Formulation Based on Benzophenone-3-poly(ε-caprolactone) Nanocapsules

Barbosa, T. C., Nascimento, L. É. D., Bani, C., Almeida, T. S., Nery, M., Santos, R. S., Menezes, L. R. D. O., Zielińska, A., Fernandes, A. R., Cardoso, J. C., et al. (2019) · Toxics · doi:10.3390/toxics7040051 · Cited by 38 · see citing works

The effect of reaction medium and hydrothermal synthesis conditions on morphological parameters and thermal behavior of calcium phosphate nanoparticles

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Physiological impact of personal care product constituents on non-target aquatic organisms

Jyoti, D., & Sinha, R. (2023) · The Science of The Total Environment · doi:10.1016/j.scitotenv.2023.167229 · Cited by 22 · see citing works

Preparation of melanoidin/TiO2 composites with improved UV screening ability and suppressed photocatalytic activity for cosmetic application

Kim, N. H., Kim, J. Y., Kim, J., Hong, I. K., & Oh, S. (2020) · Journal of Industrial and Engineering Chemistry · doi:10.1016/j.jiec.2020.03.002 · Cited by 21 · see citing works

Polyphosphazene Microparticles with High Free Radical Scavenging Activity for Skin Photoprotection

Zhou, S., Hou, S., & Lu, Q. (2024) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.4c04171 · Cited by 11 · see citing works

Advancing topical drug delivery: NLC innovations in dermatological therepeutics

Balaji, & Prakash Goudanavar, S. O. P. (2025) · Nano Trends · doi:10.1016/j.nwnano.2025.100108 · Cited by 8 · see citing works

A Microparticle Sunscreen with Highly Effective ROS Scavenging and Nonpenetration

Zhou, S., Hou, S., & Lu, Q. (2025) · Polymer science & technology. · doi:10.1021/polymscitech.4c00010 · Cited by 11 · see citing works

Ceric phosphates and nanocrystalline ceria: selective toxicity to melanoma cells

Kozlova, T. O., Popov, A. L., Romanov, M. V., Savintseva, I. V., Vasilyeva, D. N., Baranchikov, A. E., & Ivanov, V. K. (2023) · Nanosystems Physics Chemistry Mathematics · doi:10.17586/2220-8054-2023-14-2-223-230 · Cited by 6 · see citing works

Application Possibilities of Sustainable Nanostructured Silica-Based Materials in Cosmetics

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Biocosmetics: An Era of Natural Friendly Constituents in the Cosmetic Market

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Nanosunscreens for cosmeceutical applications

Singha, L. R., & Das, M. K. (2022) · Elsevier eBooks · doi:10.1016/b978-0-323-91077-4.00012-0 · Cited by 2 · see citing works

Future Challenges and Opportunities of Marine Algae in Cosmeceuticals

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