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A review on the visible light active titanium dioxide photocatalysts for environmental applications

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Dynamic Molecular Structure of Plant Biomass-Derived Black Carbon (Biochar)

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Bio-char Sequestration in Terrestrial Ecosystems – A Review

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Biochar for environmental management: science and technology

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Environmental Applications of Carbon-Based Nanomaterials

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Dairy-Manure Derived Biochar Effectively Sorbs Lead and Atrazine

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Carbonaceous nanomaterials for the enhancement of TiO2 photocatalysis

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Redox Properties of Plant Biomass-Derived Black Carbon (Biochar)

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Physical Properties of Biochar

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Catalytic Removal of Aqueous Contaminants on N-Doped Graphitic Biochars: Inherent Roles of Adsorption and Nonradical Mechanisms

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New Insights into the Aging Behavior of Microplastics Accelerated by Advanced Oxidation Processes

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Biochar Aging: Mechanisms, Physicochemical Changes, Assessment, And Implications for Field Applications

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Long-term phototransformation of microplastics under simulated sunlight irradiation in aquatic environments: Roles of reactive oxygen species

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Magnetic nitrogen-doped sludge-derived biochar catalysts for persulfate activation: Internal electron transfer mechanism

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Biochar for environmental management: Mitigating greenhouse gas emissions, contaminant treatment, and potential negative impacts

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Metal-free carbon materials for persulfate-based advanced oxidation process: Microstructure, property and tailoring

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Formation, characteristics, and applications of environmentally persistent free radicals in biochars: A review

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Biochar-based materials and their applications in removal of organic contaminants from wastewater: state-of-the-art review

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Roles of biochar-derived dissolved organic matter in soil amendment and environmental remediation: A critical review

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Persistent free radicals in carbon-based materials on transformation of refractory organic contaminants (ROCs) in water: A critical review

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Selective Degradation of Electron-Rich Organic Pollutants Induced by CuO@Biochar: The Key Role of Outer-Sphere Interaction and Singlet Oxygen

Zhao, Y. D., Yu, L., Song, C., Chen, Z., Meng, F., & Song, M. (2022) · Environmental Science & Technology · doi:10.1021/acs.est.2c01759 · Cited by 329

Bio-inspired and biomaterials-based hybrid photocatalysts for environmental detoxification: A review

Kumar, A., Sharma, G., Naushad, M., Al-Muhtaseb, A. H., García‐Peñas, A., Mola, G. T., Si, C., & Stadler, F. J. (2019) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.122937 · Cited by 329

New notion of biochar: A review on the mechanism of biochar applications in advannced oxidation processes

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Application of biochar-based photocatalysts for adsorption-(photo)degradation/reduction of environmental contaminants: mechanism, challenges and perspective

Lu, Y., Cai, Y., Zhang, S., Zhuang, L., Hu, B., Wang, S., Chen, J., & Wang, X. (2022) · Biochar · doi:10.1007/s42773-022-00173-y · Cited by 319

Nitrogen Vacancy-Modulated Peroxymonosulfate Nonradical Activation for Organic Contaminant Removal via High-Valent Cobalt-Oxo Species

Jiang, J., Zhao, Z., Gao, J., Li, T., Li, M., Zhou, D., & Dong, S. (2022) · Environmental Science & Technology · doi:10.1021/acs.est.2c01913 · Cited by 305

Biochar-induced Fe(III) reduction for persulfate activation in sulfamethoxazole degradation: Insight into the electron transfer, radical oxidation and degradation pathways

Wang, H., Guo, W., Yin, R., Du, J., Wu, Q., Luo, H., Liu, B., Sseguya, F., & Ren, N. (2019) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.01.053 · Cited by 294

Potential role of biochar in advanced oxidation processes: A sustainable approach

Nidheesh, P. V., Gopinath, A., Ranjith, N., Akre, A. P., Sreedharan, V., & Kumar, M. (2020) · Chemical Engineering Journal · doi:10.1016/j.cej.2020.126582 · Cited by 295

Recent advances in biochar-based catalysts: Properties, applications and mechanisms for pollution remediation

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Fenton chemistry and reactive oxygen species in soil: Abiotic mechanisms of biotic processes, controls and consequences for carbon and nutrient cycling

Yu, G., & Kuzyakov, Y. V. (2021) · Earth-Science Reviews · doi:10.1016/j.earscirev.2021.103525 · Cited by 283

Tuning oxygenated functional groups on biochar for water pollution control: A critical review

Dai, L., Lu, Q., Zhou, H., Shen, F., Liu, Z., Zhu, W., & Huang, H. (2021) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2021.126547 · Cited by 279

Degradation of organic pollutants from water by biochar-assisted advanced oxidation processes: Mechanisms and applications

Jiang, T., Wang, B., Gao, B., Cheng, N., Feng, Q., Chen, M., & Wang, S. (2022) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2022.130075 · Cited by 265

Environmentally persistent free radicals: Occurrence, formation mechanisms and implications

Pan, B., Li, H., Lang, D., & Xing, B. (2019) · Environmental Pollution · doi:10.1016/j.envpol.2019.02.032 · Cited by 251

A scientometric review of biochar research in the past 20 years (1998–2018)

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Biochar based catalysts for the abatement of emerging pollutants: a review

Do Minh, T., Song, J., Deb, A., Cha, L., Srivastava, V., & Sillanpää, M. (2020) · Chemical Engineering Journal · doi:10.1016/j.cej.2020.124856 · Cited by 231

Occurrence, formation, environmental fate and risks of environmentally persistent free radicals in biochars

Odinga, E. S., Waigi, M. G., Gudda, F. O., Wang, J., Yang, B., Hu, X., Li, S., & Gao, Y. (2019) · Environment International · doi:10.1016/j.envint.2019.105172 · Cited by 230

Review of the artificially-accelerated aging technology and ecological risk of microplastics

Liu, P., Shi, Y., Wu, X., Wang, H., Huang, H., Guo, X., & Gao, S. (2021) · The Science of The Total Environment · doi:10.1016/j.scitotenv.2021.144969 · Cited by 224

The superoxide radicals’ production via persulfate activated with CuFe2O4@Biochar composites to promote the redox pairs cycling for efficient degradation of o-nitrochlorobenzene in soil

Zhao, Y., Song, M., Cao, Q., Sun, P., Chen, Y., & Meng, F. (2020) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2020.122887 · Cited by 216

Lignocellulosic biomass carbonization for biochar production and characterization of biochar reactivity

Qin, F., Zhang, C., Zeng, G., Huang, D., Tan, X., & Duan, A. (2022) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2021.112056 · Cited by 220

Non-Radical Activation of Peracetic Acid by Powdered Activated Carbon for the Degradation of Sulfamethoxazole

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Review on design and evaluation of environmental photocatalysts

Li, X., Xie, J., Jiang, C., Yu, J., & Zhang, P. (2018) · Frontiers of Environmental Science & Engineering · doi:10.1007/s11783-018-1076-1 · Cited by 210

Biochar as a novel carbon-negative electron source and mediator: electron exchange capacity (EEC) and environmentally persistent free radicals (EPFRs): a review

Yuan, J., Wen, Y., Dionysiou, D. D., Sharma, V. K., & Ma, X. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.132313 · Cited by 204

Enhanced Transformation of Cr(VI) by Heterocyclic‑N within Nitrogen-Doped Biochar: Impact of Surface Modulatory Persistent Free Radicals (PFRs)

Zhu, S., Huang, X., Yang, X., Peng, P., Li, Z., & Jin, C. (2020) · Environmental Science & Technology · doi:10.1021/acs.est.0c02713 · Cited by 199

Effects of ball milling on the photochemistry of biochar: Enrofloxacin degradation and possible mechanisms

Xiao, Y., Lyu, H., Tang, J., Wang, K., & Sun, H. (2019) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.123311 · Cited by 193

Application of biochars in the remediation of chromium contamination: Fabrication, mechanisms, and interfering species

Zheng, C., Yang, Z., Si, M., Zhu, F., Yang, W., Zhao, F., & Shi, Y. (2020) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2020.124376 · Cited by 190

Pathway for the Production of Hydroxyl Radicals during the Microbially Mediated Redox Transformation of Iron (Oxyhydr)oxides

Han, R., Lv, J., Huang, Z., Zhang, S., & Zhang, S. (2019) · Environmental Science & Technology · doi:10.1021/acs.est.9b06220 · Cited by 177

ZnO hierarchical microsphere for enhanced photocatalytic activity

Wang, S., Kuang, P., Cheng, B., Yu, J., & Jiang, C. (2018) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2018.01.141 · Cited by 174

Effects of thermal modification of a biochar on persulfate activation and mechanisms of catalytic degradation of a pharmaceutical

Kim, D.-G., & Ko, S. (2020) · Chemical Engineering Journal · doi:10.1016/j.cej.2020.125377 · Cited by 168

Integrated adsorption and photodegradation of tetracycline by bismuth oxycarbonate/biochar nanocomposites

Luo, Y., Zheng, A., Li, J., Han, Y., Xue, M., Zhang, L., Yin, Z., Xie, C., Chen, Z., Ji, L., et al. (2022) · Chemical Engineering Journal · doi:10.1016/j.cej.2022.141228 · Cited by 169

Degradation of organic pollutants by ferrate/biochar: Enhanced formation of strong intermediate oxidative iron species

Tian, S., Wang, L., Liu, Y.-L., & Ma, J. (2020) · Water Research · doi:10.1016/j.watres.2020.116054 · Cited by 164

Visible-LED-light-driven photocatalytic degradation of ofloxacin and ciprofloxacin by magnetic biochar modified flower-like Bi2WO6: The synergistic effects, mechanism insights and degradation pathways

Wang, Z., Cai, X., Xie, X., Li, S., Zhang, X., & Wang, Z. (2020) · The Science of The Total Environment · doi:10.1016/j.scitotenv.2020.142879 · Cited by 166

Biochar based nanocomposites for photocatalytic degradation of emerging organic pollutants from water and wastewater

Ahmaruzzaman, M. (2021) · Materials Research Bulletin · doi:10.1016/j.materresbull.2021.111262 · Cited by 168

Sustainable remediation with an electroactive biochar system: mechanisms and perspectives

Wan, Z., Sun, Y., Tsang, D. C. W., Hou, D., Cao, X., Zhang, S., Gao, B., & Ok, Y. S. (2020) · Green Chemistry · doi:10.1039/d0gc00717j · Cited by 162

Novel magnetic rod-like Mn-Fe oxycarbide toward peroxymonosulfate activation for efficient oxidation of butyl paraben: Radical oxidation versus singlet oxygenation

Yang, J. E., Lin, Y. H., Peng, H., Yuan, B., Dionysiou, D. D., Huang, X.-D., Zhang, D., & Fu, M. (2020) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.118549 · Cited by 160

A critical review on the application of biochar in environmental pollution remediation: Role of persistent free radicals (PFRs)

Luo, K., Pang, Y., Wang, D., Li, X., Wang, L., Lei, M., Huang, Q., & Yang, Q. X. (2021) · Journal of Environmental Sciences · doi:10.1016/j.jes.2021.02.021 · Cited by 161

Photocatalytic reactive oxygen species generation and their mechanisms of action in pollutant removal with biochar supported photocatalysts: A review

Rangarajan, G., Arun, J., & Farnood, R. (2022) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2022.131155 · Cited by 163

Metal-free activation of persulfates by corn stalk biochar for the degradation of antibiotic norfloxacin: Activation factors and degradation mechanism

Wang, B., Li, Y., & Wang, L. (2019) · Chemosphere · doi:10.1016/j.chemosphere.2019.124454 · Cited by 153

Application of biochar in advanced oxidation processes: supportive, adsorptive, and catalytic role

Faheem, F., Du, J., Kim, S. H., Hassan, M. A., Irshad, S., & Bao, J. (2020) · Environmental Science and Pollution Research · doi:10.1007/s11356-020-07612-y · Cited by 156

Enhanced cytotoxicity of photoaged phenol-formaldehyde resins microplastics: Combined effects of environmentally persistent free radicals, reactive oxygen species, and conjugated carbonyls

Zhu, K., Jia, H., Sun, Y., Dai, Y., Zhang, C., Guo, X., Wang, T., & Zhu, L. Y. (2020) · Environment International · doi:10.1016/j.envint.2020.106137 · Cited by 146

The photochemical behaviors of microplastics through the lens of reactive oxygen species: Photolysis mechanisms and enhancing photo-transformation of pollutants

Shi, X., Chen, Z., Liu, X., Wei, W., & Ni, B. (2022) · The Science of The Total Environment · doi:10.1016/j.scitotenv.2022.157498 · Cited by 149

Metallic Active Sites on MoO2(110) Surface to Catalyze Advanced Oxidation Processes for Efficient Pollutant Removal

Ji, J., Aleisa, R. M., Duan, H., Zhang, J., Yin, Y., & Xing, M. (2020) · iScience · doi:10.1016/j.isci.2020.100861 · Cited by 132

Peroxymonosulfate activation by localized electrons of ZnO oxygen vacancies for contaminant degradation

Kong, L., Fang, G., Fang, Z., Zou, Y., Zhu, F., Zhou, D., & Zhan, J. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.128996 · Cited by 133

Inorganic anions influenced the photoaging kinetics and mechanism of polystyrene microplastic under the simulated sunlight: Role of reactive radical species

Zhu, K., Sun, Y., Jiang, W., Zhang, C., Dai, Y., Liu, Z., Wang, T., Guo, X., & Jia, H. (2022) · Water Research · doi:10.1016/j.watres.2022.118294 · Cited by 133

Plastisphere community assemblage of aquatic environment: plastic-microbe interaction, role in degradation and characterization technologies

Dey, S., Rout, A. K., Behera, B. K., & Ghosh, K. (2022) · Environmental Microbiome · doi:10.1186/s40793-022-00430-4 · Cited by 138

Efficient activation of peracetic acid by mixed sludge derived biochar: Critical role of persistent free radicals

Wu, L., Li, Z., Cheng, P., She, Y., Wang, W., Tian, Y., Ma, J., & Sun, Z. (2022) · Water Research · doi:10.1016/j.watres.2022.119013 · Cited by 128

Preparation and application of Fe/biochar (Fe-BC) catalysts in wastewater treatment: A review

Li, X., Qin, Y., Jia, Y. P., Li, Y., Zhao, Y., Pan, Y., & Sun, J. (2021) · Chemosphere · doi:10.1016/j.chemosphere.2021.129766 · Cited by 127

Periodate activated by manganese oxide/biochar composites for antibiotic degradation in aqueous system: Combined effects of active manganese species and biochar

Fang, G., Li, J., Zhang, C., Qin, F., Luo, H., Huang, C., Qin, D., & Ouyang, Z. (2022) · Environmental Pollution · doi:10.1016/j.envpol.2022.118939 · Cited by 124

Biomass Schiff base polymer-derived N-doped porous carbon embedded with CoO nanodots for adsorption and catalytic degradation of chlorophenol by peroxymonosulfate

Xie, M., Tang, J., Fang, G., Zhang, M., Kong, L., Zhu, F., Ma, L., Zhou, D., & Zhan, J. (2019) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2019.121345 · Cited by 118

Combined CdS nanoparticles-assisted photocatalysis and periphytic biological processes for nitrate removal

Zhu, N., Tang, J., Tang, C., Duan, P., Yao, L., Wu, Y., & Dionysiou, D. D. (2018) · Chemical Engineering Journal · doi:10.1016/j.cej.2018.07.121 · Cited by 117

Calcination temperature regulates non-radical pathways of peroxymonosulfate activation via carbon catalysts doped by iron and nitrogen

Wang, Y., Lin, Y., Yang, C., Wu, S., Fu, X., & Li, X. (2022) · Chemical Engineering Journal · doi:10.1016/j.cej.2022.138468 · Cited by 111

TiO2 supported on Salvinia molesta biochar for heterogeneous photocatalytic degradation of Acid Orange 7 dye

Silvestri, S., Gonçalves, M. G., Veiga, P. A. D. S., Matos, T. T. D. S., Peralta-Zamora, P., & Mangrich, A. S. (2019) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2019.102879 · Cited by 113

Lotus-Leaf-Derived Activated-Carbon-Supported Nano-CdS as Energy-Efficient Photocatalysts under Visible Irradiation

Huang, H., Wang, Y., Jiao, W.-B., Cai, F., Shen, M., Zhou, S., Cao, H., Lü, J., & Cao, R. (2018) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.8b01021 · Cited by 107

Non-radical oxidation in environmental catalysis: Recognition, identification, and perspectives

Yu, J., Tang, L., Pang, Y., Liang, X., Lu, Y., Feng, H., Wang, J., Deng, L., Zou, J., Zhu, X., et al. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.134385 · Cited by 107

Bismuth impregnated biochar for efficient estrone degradation: The synergistic effect between biochar and Bi/Bi2O3 for a high photocatalytic performance

Zhu, N., Li, C., Bu, L., Tang, C., Wang, S., Duan, P., Yao, L., Tang, J., Dionysiou, D. D., & Wu, Y. (2019) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2019.121258 · Cited by 107

Biochar derived from different crop straws as persulfate activator for the degradation of sulfadiazine: Influence of biomass types and systemic cause analysis

Feng, Z., Zhou, B., Yuan, R., Li, H., He, P., Wang, F., Chen, Z., & Chen, H. (2022) · Chemical Engineering Journal · doi:10.1016/j.cej.2022.135669 · Cited by 105

A Mechanistic Understanding of Hydrogen Peroxide Decomposition by Vanadium Minerals for Diethyl Phthalate Degradation

Fang, G., Deng, Y., Huang, M., Dionysiou, D. D., Liu, C., & Zhou, D. (2018) · Environmental Science & Technology · doi:10.1021/acs.est.7b05303 · Cited by 102

Significant contribution of metastable particulate organic matter to natural formation of silver nanoparticles in soils

Huang, Y., Qian, T., Dang, F., Yin, Y., Li, M., & Zhou, D. (2019) · Nature Communications · doi:10.1038/s41467-019-11643-6 · Cited by 101

Sustainable remediation of hazardous environmental pollutants using biochar-based nanohybrid materials

Zhao, Y., Qamar, S. A., Qamar, M., Bilal, M., & Iqbal, H. M. N. (2021) · Journal of Environmental Management · doi:10.1016/j.jenvman.2021.113762 · Cited by 100

The generation and transformation mechanisms of reactive oxygen species in the environment and their implications for pollution control processes: A review

Bi, Z., Wang, W., Zhao, L., Wang, X., Xing, D., Zhou, Y., Lee, D., Ren, N., & Chen, C. (2024) · Environmental Research · doi:10.1016/j.envres.2024.119592 · Cited by 102

Accelerating effects of biochar for pyrite-catalyzed Fenton-like oxidation of herbicide 2,4-D

Zhu, X., Li, J., Xie, B., Feng, D., & Li, Y. (2019) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.123605 · Cited by 96

Transformation of functional groups and environmentally persistent free radicals in hydrothermal carbonisation of lignin

Ruan, X., Liu, Y., Wang, G., Frost, R. L., Qian, G., & Tsang, D. C. W. (2018) · Bioresource Technology · doi:10.1016/j.biortech.2018.09.027 · Cited by 96

Efficient oxidation and adsorption of As(III) and As(V) in water using a Fenton-like reagent, (ferrihydrite)-loaded biochar

Huang, Y., Gao, M., Deng, Y., Khan, Z. H., Liu, X., Song, Z., & Qiu, W. (2020) · The Science of The Total Environment · doi:10.1016/j.scitotenv.2020.136957 · Cited by 96

Environmental photochemistry in hematite-oxalate system: Fe(III)-Oxalate complex photolysis and ROS generation

Xu, T., Fang, Y., Tong, T., Xia, Y., Liu, X., & Zhang, L. (2020) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2020.119645 · Cited by 93

A critical review on biochar-based catalysts for the abatement of toxic pollutants from water via advanced oxidation processes (AOPs)

Gupta, A. D., Singh, H., Varjani, S., Awasthi, M. K., Giri, B. S., & Pandey, A. (2022) · The Science of The Total Environment · doi:10.1016/j.scitotenv.2022.157831 · Cited by 93

Enhanced phototransformation of atorvastatin by polystyrene microplastics: Critical role of aging

Wang, H., Liu, P., Wang, M., Wu, X., Shi, Y., Huang, H., & Gao, S. (2020) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2020.124756 · Cited by 88

Solid-phase fabrication of TiO2/Chitosan-biochar composites with superior UV–vis light driven photocatalytic degradation performance

Feng, X., Li, X., Su, B., & Ma, J. (2022) · Colloids and Surfaces A Physicochemical and Engineering Aspects · doi:10.1016/j.colsurfa.2022.129114 · Cited by 91

The adverse effect of biochar to aquatic algae- the role of free radicals

Zhang, Y., Yang, R., Si, X., Duan, X., & Quan, X. (2019) · Environmental Pollution · doi:10.1016/j.envpol.2019.02.055 · Cited by 92

Algal biochar reinforced trimetallic nanocomposite as adsorptional/photocatalyst for remediation of malachite green from aqueous medium

Sharma, G., Bhogal, S., Gupta, V. K., Agarwal, S., Kumar, A., Pathania, D., Mola, G. T., & Stadler, F. J. (2018) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2018.11.070 · Cited by 92

Research progress on removal of phthalates pollutants from environment

Zhu, Z., Rao, R., Zhao, Z., Chen, J., Jiang, W., Bi, F., Yang, Y., & Zhang, X. (2022) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2022.118930 · Cited by 89

The critical role of minerals in persulfate-based advanced oxidation process: Catalytic properties, mechanism, and prospects

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