The DOI matches its Crossref record; 49 of the 49 references it cites were found in a registry or an index.
Monodispersed CuFe2O4 nanoparticles anchored on natural kaolinite as highly efficient peroxymonosulfate catalyst for bisphenol A degradation
Abstract
Abstract In this study, CuFe 2 O 4 /kaolinite catalysts were fabricated through a facile citrate combustion method and were evaluated for their efficiency to activate peroxymonosulfate (PMS) towards the destruction of bisphenol A (BPA). The prepared catalysts were systematically characterized to explore the relationship between their characteristics and catalytic activities. In general, higher specific surface area, larger pore volume, more hydroxyl groups, and more accessible reactive sites of 40%-CuFe 2 O 4 /kaolinite contributed to the greater catalytic activity in peroxymonosulfate activation for BPA degradation compared to bare CuFe 2 O 4 . Monodispersed CuFe 2 O 4 nanoparticles were uniformly anchored on the surface of kaolinite with Fe O Al bond, which prevented leaching of metal ions and contributed to the excellent reusability. The sulfate radicals produced in the CuFe 2 O 4 /kaolinite/PMS system were proved as the predominant radical species through electron spin resonance (ESR) and radical quenching experiments. Based on the results of X-ray photoelectron spectroscopy (XPS) and attenuated total reflectance – Fourier transform infrared spectra (ATR-FTIR), two main possible pathways of sulfate radicals generation were proposed: the generation and decomposition of Cu(II)-(HO)OSO 3 − (Cu(II)/Cu(III) and Cu(III)/Cu(II) redox reaction) and the oxidation of Fe(II). Moreover, the BPA degradation pathway was proposed through the identification of transformation products. This work provides an interesting insight for PMS activation by the high-efficient natural mineral-based catalysts for wastewater reclamation.
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Wang, L., Lan, X., Peng, W., & Wang, Z. (2021) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2020.124436 · Cited by 689
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Ce(Ⅲ) activates peroxymonosulfate for the degradation of substituted PAHs
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Metadata
- Authors
- Dong, X., Ren, B., Sun, Z., Li, C., Zhang, X., Kong, M., Zheng, S., & Dionysiou, D. D.
- Venue
- Applied Catalysis B: Environmental
- Publisher
- Elsevier BV
- Published
- 2019-09
- Volume
- 253
- Pages
- 206-217
- ISSN
- 0926-3373 (ISSN-L)
- OpenAlex
- W2939032959
- Cited by
- 554
- References
- 49
- FWCI
- 25.80
- Type
- journal article
- Language
- en
- Open access
- closed
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- Dong, X., Ren, B., Sun, Z., Li, C., Zhang, X., Kong, M., Zheng, S., & Dionysiou, D. D. (2019). Monodispersed CuFe2O4 nanoparticles anchored on natural kaolinite as highly efficient peroxymonosulfate catalyst for bisphenol A degradation. Applied Catalysis B: Environmental. https://doi.org/10.1016/j.apcatb.2019.04.052
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