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Cited by 554

The DOI matches its Crossref record; 49 of the 49 references it cites were found in a registry or an index.

Monodispersed CuFe2O4 nanoparticles anchored on natural kaolinite as highly efficient peroxymonosulfate catalyst for bisphenol A degradation

Dong, Xiongbo, Ren, Bangxing, Sun, Zhiming, Li, Chunquan, Zhang, Xiangwei, Kong, Minghao, Zheng, Shuilin, Dionysiou, Dionysios D.·2019·Applied Catalysis B: Environmental

Abstract

Abstract In this study, CuFe 2 O 4 /kaolinite catalysts were fabricated through a facile citrate combustion method and were evaluated for their efficiency to activate peroxymonosulfate (PMS) towards the destruction of bisphenol A (BPA). The prepared catalysts were systematically characterized to explore the relationship between their characteristics and catalytic activities. In general, higher specific surface area, larger pore volume, more hydroxyl groups, and more accessible reactive sites of 40%-CuFe 2 O 4 /kaolinite contributed to the greater catalytic activity in peroxymonosulfate activation for BPA degradation compared to bare CuFe 2 O 4 . Monodispersed CuFe 2 O 4 nanoparticles were uniformly anchored on the surface of kaolinite with Fe O Al bond, which prevented leaching of metal ions and contributed to the excellent reusability. The sulfate radicals produced in the CuFe 2 O 4 /kaolinite/PMS system were proved as the predominant radical species through electron spin resonance (ESR) and radical quenching experiments. Based on the results of X-ray photoelectron spectroscopy (XPS) and attenuated total reflectance – Fourier transform infrared spectra (ATR-FTIR), two main possible pathways of sulfate radicals generation were proposed: the generation and decomposition of Cu(II)-(HO)OSO 3 − (Cu(II)/Cu(III) and Cu(III)/Cu(II) redox reaction) and the oxidation of Fe(II). Moreover, the BPA degradation pathway was proposed through the identification of transformation products. This work provides an interesting insight for PMS activation by the high-efficient natural mineral-based catalysts for wastewater reclamation.

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Metadata

Authors
Dong, X., Ren, B., Sun, Z., Li, C., Zhang, X., Kong, M., Zheng, S., & Dionysiou, D. D.
Venue
Applied Catalysis B: Environmental
Publisher
Elsevier BV
Published
2019-09
Volume
253
Pages
206-217
ISSN
0926-3373 (ISSN-L)
OpenAlex
W2939032959
Cited by
554
References
49
FWCI
25.80
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Monodispersed CuFe2O4 nanoparticles anchored on natural kaolinite as highly efficient peroxymonosulfate catalyst for bisphenol A degradation. https://app.cochat.ai/papers/10.1016/j.apcatb.2019.04.052
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Dong, X., Ren, B., Sun, Z., Li, C., Zhang, X., Kong, M., Zheng, S., & Dionysiou, D. D. (2019). Monodispersed CuFe2O4 nanoparticles anchored on natural kaolinite as highly efficient peroxymonosulfate catalyst for bisphenol A degradation. Applied Catalysis B: Environmental. https://doi.org/10.1016/j.apcatb.2019.04.052

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