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Cited by 567

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High efficiency heterogeneous Fenton-like catalyst biochar modified CuFeO2 for the degradation of tetracycline: Economical synthesis, catalytic performance and mechanism

Xin, Shuaishuai, Liu, Guocheng, Ma, Xiaohan, Gong, Jiaxin, Ma, Bingrui, Yan, Qinghua, Chen, Qinghua, Ma, Dong, Zhang, Guangshan, Gao, Mengchun, Xin, Yanjun·2021·Applied Catalysis B: Environmental

Abstract

Abstract The heterogeneous Fenton-like catalysts biochar modified CuFeO2 (CuFeO2/BC) were fabricated by hydrothermal method without additional chemical reducing agent. The systematic characterization demonstrated that higher CuFeO2 particles dispersion and larger BET surface area of CuFeO2/BC catalyst contributed to higher catalytic activity towards the tetracycline (TC) degradation compared to pure-phase CuFeO2. The optimum conditions for TC removal were 598.63 mg L-1 of CuFeO2/BC-1.0, 57.63 mM of H2O2 and pH = 6.27 according to the result of a response surface methodology based on the central composite design. The CuFeO2/BC-1.0 exhibited an excellent reusability and good stability by recycling degradation. The OH was evidenced to the main active radical by scavenging experiments and electron spin resonance. The XPS revealed that the high catalytic efficiency was attributed to the synergistic effect of Fe3+/Fe2+ and Cu2+/Cu+ redox cycles, and the degradation intermediates of TC and toxicity analysis were evaluated.

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Metadata

Authors
Xin, S., Liu, G., Ma, X., Gong, J., Ma, B., Yan, Q., Chen, Q., Ma, D., Zhang, G., Gao, M., & Xin, Y.
Venue
Applied Catalysis B: Environmental
Publisher
Elsevier BV
Published
2021-01
Volume
280
Pages
119386
ISSN
0926-3373 (ISSN-L)
OpenAlex
W3048288578
Cited by
567
References
48
FWCI
22.48
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: High efficiency heterogeneous Fenton-like catalyst biochar modified CuFeO2 for the degradation of tetracycline: Economical synthesis, catalytic performance and mechanism. https://app.cochat.ai/papers/10.1016/j.apcatb.2020.119386
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Xin, S., Liu, G., Ma, X., Gong, J., Ma, B., Yan, Q., Chen, Q., Ma, D., Zhang, G., Gao, M., & Xin, Y. (2021). High efficiency heterogeneous Fenton-like catalyst biochar modified CuFeO2 for the degradation of tetracycline: Economical synthesis, catalytic performance and mechanism. Applied Catalysis B: Environmental. https://doi.org/10.1016/j.apcatb.2020.119386

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